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Volumn 9, Issue 4, 1998, Pages 647-651

Kinetic resolution of vic-diols by Bacillus stearothermophilus diacetyl reductase

Author keywords

[No Author keywords available]

Indexed keywords

OXIDOREDUCTASE;

EID: 0032570486     PISSN: 09574166     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0957-4166(98)00032-9     Document Type: Article
Times cited : (31)

References (23)
  • 1
    • 0002874969 scopus 로고
    • Morrison, J. W.; Scott, J. W., Eds; Academic Press: New York
    • Scott, J. W. In Asymmetric Synthesis; Morrison, J. W.; Scott, J. W., Eds; Academic Press: New York, 1984, Vol. 4, pp. 1-226.
    • (1984) In Asymmetric Synthesis , vol.4 , pp. 1-226
    • Scott, J.W.1
  • 7
    • 0030789621 scopus 로고    scopus 로고
    • The combined yields of the recovered alcohol and the α-hydroxy ketone are always higher than 50%. For a recent report on the coupled use of resolution and recovery of the substrate see for example:
    • The combined yields of the recovered alcohol and the α-hydroxy ketone are always higher than 50%. For a recent report on the coupled use of resolution and recovery of the substrate see for example: Larsson, A. L. E.; Persson, B. A.; Backvall, J. E. Angew. Chem. Int. Ed. Engl. 1997, 36, 1211.
    • (1997) Angew. Chem. Int. Ed. Engl. , vol.36 , pp. 1211
    • Larsson, A.L.E.1    Persson, B.A.2    Backvall, J.E.3
  • 8
    • 84920311191 scopus 로고    scopus 로고
    • Acyclic syn compounds are formed by the (R,R) and (S,S) pair, anti compounds by the (R,S) and (S,R) pair. With cyclic compounds the nomenclature is inverted: syn is the meso compound and anti is the (R,R) and (S,S) pair
    • Acyclic syn compounds are formed by the (R,R) and (S,S) pair, anti compounds by the (R,S) and (S,R) pair. With cyclic compounds the nomenclature is inverted: syn is the meso compound and anti is the (R,R) and (S,S) pair.
  • 9
    • 0029092875 scopus 로고
    • For selectivity as a function of steric bulkiness see
    • For selectivity as a function of steric bulkiness see Kim, M. J.; Choi, G. B.; Kim, J. Y.; Kim, H. J. Tetrahedron Lett. 1995, 36, 6253.
    • (1995) Tetrahedron Lett. , vol.36 , pp. 6253
    • Kim, M.J.1    Choi, G.B.2    Kim, J.Y.3    Kim, H.J.4
  • 10
    • 84920311190 scopus 로고    scopus 로고
    • The catalytic system is equally effective as a single enzyme, where BSDR catalyzes the desired reaction while simultaneously regenerating the cofactor. In this case, the BSDR natural substrate diacetyl i.e. (2,3-butandione) has been used as a cosubstrate, see Ref. 13. For an easy work-up of the reaction mixture, however, the double-enzyme system is recommended
    • The catalytic system is equally effective as a single enzyme, where BSDR catalyzes the desired reaction while simultaneously regenerating the cofactor. In this case, the BSDR natural substrate diacetyl i.e. (2,3-butandione) has been used as a cosubstrate, see Ref. 13. For an easy work-up of the reaction mixture, however, the double-enzyme system is recommended.
  • 17
    • 84920311189 scopus 로고    scopus 로고
    • For the optical rotation of the (S,S)-enantiomer see Ref. 4
    • For the optical rotation of the (S,S)-enantiomer see Ref. 4.
  • 21
    • 84920311188 scopus 로고    scopus 로고
    • Commercially available product
    • Commercially available product.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.