Dirhodium(II) tetracarboxylate carbenoids as catalytic intermediates

Tetrahedron Letters

Volumn 39, Issue 9, 1998, Pages 949-952

  Sheehan, Scott M ^a   Padwa, Albert ^a   Snyder, James P ^a  

^a EMORY UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CARBOXYLIC ACID DERIVATIVE; RHODIUM COMPLEX; SOLVENT;

ARTICLE; CATALYSIS; CHEMICAL BOND; COMPLEX FORMATION; QUANTUM CHEMISTRY;

EID: 0032568062     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(97)10667-0     Document Type: Article

References (22)

1. 1 (a) Ye, T.; McKervey, M. A. Chem. Rev. 1994, 94, 1091.
2. (b) Doyle, M. P. In Comprehensive Organometallic Chemistry II; Hegedus, L. S. Ed.; Pergamon Press, New York, 1995; Vol 12, Chapter 5.2.
3. (c) Padwa, A.; Weingarten, M. D. Chem. Rev. 1996, 96, 223.
4. 2 (a) Doyle, M. P. Acc. Chem. Res. 1986, 19, 348. Doyle, M. P. Chem. Rev. 1986, 86, 919
5. 2 (a) Doyle, M. P. Acc. Chem. Res. 1986, 19, 348. Doyle, M. P. Chem. Rev. 1986, 86, 919
6. (b) Alonso, M. E.; Fernandez, R. Tetrahedron, 1989, 45, 3313.
7. (c) Doyle, M. P. Rec. Trav. Chim. Pays-Bas, 1991, 110, 305.
8. 3 Weingarten, M. D.; Prein, M.; Price, A. T.; Snyder, J. P.; Padwa, A J. Org. Chem. 1997, 62, 2001.
9. 4 GAUSSIAN 94/DFT: (Revision A.1), Gaussian, Inc., Pittsburgh, PA, 1995; http: //www.Gaussian.com/ For references to details of the underlying theory, cf. Snyder, J. P., J. Am. Chem. Soc. 1995, 117, 11025.
10. 4 GAUSSIAN 94/DFT: (Revision A.1), Gaussian, Inc., Pittsburgh, PA, 1995; http: //www.Gaussian.com/ For references to details of the underlying theory, cf. Snyder, J. P., J. Am. Chem. Soc. 1995, 117, 11025.
11. 6 Bauschlicher, C. W. Jr.; Partridge, H.; Sheehy, J. A.; Langhoff, S. R.; Rosi, M. J. Phys. Chem. 1992, 96, 6969.
12. 7 Musaev, D. G.; Morokuma, K. J. Phys. Chem. 1993, 99, 7859.
13. 8 Cotton, F. A.; DeBoer, B. G.; LaPrade, M. D.; Pipal, J. R.; Ucko, D. A. Acta Cryst., 1971, B27, 1664.
14. 9 Reed, A. E.; Weinstock, R. B.; Weinhold, F. J. Chem. Phys. 1985, 83, 735. Reed, A. E.; Curtis, L. A.; Weinhold, F. Chem. Rev., 1988, 88, 899.
15. 9 Reed, A. E.; Weinstock, R. B.; Weinhold, F. J. Chem. Phys. 1985, 83, 735. Reed, A. E.; Curtis, L. A.; Weinhold, F. Chem. Rev., 1988, 88, 899.
16. 10 (a) Norman, J. G.; Kolari, H. J. J. Am. Chem. Soc. 1978, 100, 791.
17. (b) Nakatsuji, H.; Ushio, J; Kanda, K.; Onishi, Y.; Kawamura, T.; Yonezawa, T. Chem. Phys. Lett. 1981, 79, 299.; Nakatsuji, H.; Onishi, Y.; Ushio, J.; Yonezawa, T. Inorg. Chem. 1983, 22, 1623.
18. (b) Nakatsuji, H.; Ushio, J; Kanda, K.; Onishi, Y.; Kawamura, T.; Yonezawa, T. Chem. Phys. Lett. 1981, 79, 299.; Nakatsuji, H.; Onishi, Y.; Ushio, J.; Yonezawa, T. Inorg. Chem. 1983, 22, 1623.
19. 11 Felthouse, T. R. Prog. Inorg. Chem. 1982, 29, 143.
20. 12 Cotton, F. A.; Walton, R. A. Multiple Bonds between Metal Atoms, 1993, Clarenden Press, Oxford, pp 435-443.
21. y, C, H) 6-31G*/6-31+G* +0.93/+0.95, +0.69/+0.72, -0.19/-0.17, +0.19/+0.19, MK +13/+1.5, +0.73/+0.85, -0.13/-0.15, +0.12/+0.12, CHelpG +1.1/+1.3, +0.82/+0.91, +0.05/+0.04, +0.07/+0.06.
22. 14 Allinger, N. L.; Zhou, K.; Bergsma, J. J. Molec. Struct. (Theochem) 1994, 312, 69.