The formation of HCS and HCSH molecules and their role in the collision of comet Shoemaker-Levy 9 with Jupiter

Science

Volumn 279, Issue 5354, 1998, Pages 1181-1184

  Kaiser, R I ^a,b,c   Ochsenfeld, C ^a   Head Gordon, M ^a   Lee, Y T ^a,b  

^a UNIVERSITY OF CALIFORNIA   (United States)

^b ACADEMIA SINICA   (Taiwan)

^c CHEMNITZ UNIVERSITY OF TECHNOLOGY   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

CARBON; HYDROGEN; HYDROGEN SULFIDE; RADICAL; THIOL DERIVATIVE;

CARBON; COMET SHOEMAKER-LEVY 9; HYDROGEN SULPHIDE; IMPACT; JUPITER;

ARTICLE; ASTRONOMY; ATOM; PRIORITY JOURNAL; REACTION ANALYSIS;

ATMOSPHERE; CARBON; CARBON COMPOUNDS, INORGANIC; CARBON DISULFIDE; EXTRATERRESTRIAL ENVIRONMENT; FREE RADICALS; HYDROGEN SULFIDE; JUPITER; METEOROIDS; SULFIDES; SULFUR OXIDES;

EID: 0032549093     PISSN: 00368075     EISSN: None     Source Type: Journal    
DOI: 10.1126/science.279.5354.1181     Document Type: Article

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24. -1.
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29. -1 singlettriplet gap of {1} and {2} could induce intersystem crossing (ISC) followed by H migration to {4}/{5}. Alternatively, {2} could undergo H migration to {3} and ISC to {4}/{5}.
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34. R.I.K. and C.O. thank the Deutsche Forschungsgemeinschaft (DFG) for Habilitation and postdoctoral fellowships, respectively. R.I.K. further thanks D. Gerlich and Y.T.L for support. M.H.G. acknowledges a Packard fellowship. We acknowledge useful comments from S. K. Atreya, J. F. Stanton, and P. Casavecchia and discussions with M. F. A'Hearn and K. S. Noll. This work was supported by the U.S. Department of Energy.