Total synthesis of (-)-decarestrictine D through a stereoselective intramolecular Nozaki-Hiyama-Kishi reaction

Tetrahedron Letters

Volumn 39, Issue 25, 1998, Pages 4421-4424

  Pilli, Ronaldo A ^a   Victor, Mauricio M ^a  

^a UNIVERSITY OF CAMPINAS   (Brazil)

Author keywords

[No Author keywords available]

Indexed keywords

1,3 PROPANEDIOL; ANTILIPEMIC AGENT; DECARESTRICTINE D; UNCLASSIFIED DRUG;

ANIMAL CELL; ARTICLE; CHOLESTEROL SYNTHESIS; DEPOLYMERIZATION; DRUG SYNTHESIS; HUMAN; HUMAN CELL; MOLECULAR INTERACTION; NONHUMAN; PURIFICATION; RAT; REACTION ANALYSIS; STEREOCHEMISTRY; TREATMENT OUTCOME;

ANIMALIA;

EID: 0032543453     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(98)00837-5     Document Type: Article

References (18)

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11. 7. Column: heptakis(2,6-methyl-3-pentyl)β-cyclodextrine 20% in OV 1701, 25m, 0.25mm id.
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17. 13. When the Nozaki-Hiyama step in the above sequence was carried out in DMSO the formation of a 2:1 mixture of (-)-12 and its C-7 epimer was observed.
18. 3) of (-)-1: δ 175.3, 133.9, 130.1, 73.9, 72.5, 72.2, 68.2, 42.9, 33.0, 21.0.