Fast oxidation of organic sulfides by hydrogen peroxide by in situ generated peroxynitrous acid

Angewandte Chemie - International Edition

Volumn 37, Issue 15, 1998, Pages 2088-2090

  Vayssié, Stéphane ^b   Elias, Horst ^a  

^a DARMSTADT UNIVERSITY OF TECHNOLOGY   (Germany)

^b NONE

Author keywords

Homogeneous catalysis; O O activation; Oxidations; Peroxides; Synthetic methods

Indexed keywords

EID: 0032541273     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3773(19980817)37:15<2088::AID-ANIE2088>3.0.CO;2-1     Document Type: Article

References (23)

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7. See, for example, a) R. Radi, J. S. Beckman, K. S. Bush, B. A. Freeman, J. Biol. Chem. 1991, 266, 4244-4250; b) W. A. Pryor, X. Jin, G. L. Squadrito, Proc. Natl. Acad. Sci. USA 1994, 91, 11 173-11 177; c) A. Al-Ajlouni, E. S. Gould, Inorg. Chem. 1996, 35, 7892-7896; d) S. Goldstein, G. Czapski, Inorg. Chem. 1995, 34, 4041-4048.
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9. 2 as a reagent necessarily introduces some water into the system. The solvent acetonitrile with a constant admixture of water (5M) was therefore taken as the standard reaction medium.
10. ∞ (5)
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15. 2O).[13]
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20. -1.
21. 2S) and 170°C (PhSMe). The samples were neutralized with NaOH before injection.
22. 1H NMR and IR spectroscopy as well as C,H,N analysis proved the identity of the product as dibenzyl sulfoxide.
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