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Volumn 32, Issue 20, 1998, Pages 3200-3206

Carbon atom-initiated degradation of carbon tetrachloride in the presence of molecular oxygen: A product and mechanistic study

Author keywords

[No Author keywords available]

Indexed keywords

ATOMS; CARBON DIOXIDE; CARBON TETRACHLORIDE; CHEMICAL BONDS; FLUORESCENCE; FOURIER TRANSFORM INFRARED SPECTROSCOPY; GAS CHROMATOGRAPHY; LASER APPLICATIONS; MASS SPECTROMETRY; MOLECULES; OXYGEN;

EID: 0032532733     PISSN: 0013936X     EISSN: None     Source Type: Journal    
DOI: 10.1021/es980475e     Document Type: Article
Times cited : (5)

References (31)
  • 1
    • 0003223828 scopus 로고
    • Report on Concentrations, Lifetimes, and Trends of CFCs, Halons, and Related Species
    • January
    • Kaye, J. A.; Penkett, S. A.; Ormond, F. M. Report on Concentrations, Lifetimes, and Trends of CFCs, Halons, and Related Species. NASA Reference Publication 1339, January 1994.
    • (1994) ASA Reference Publication , vol.1339
    • Kaye, J.A.1    Penkett, S.A.2    Ormond, F.M.3
  • 25
    • 3543106827 scopus 로고    scopus 로고
    • note
    • Rotating the graphite rod so that the laser beam did not strike the same spot each time, as in ref 15, could easily increase these numbers. With a static experiment, the laser tended to gouge a hole in the graphite rod, so that the plume of carbon atoms did not have ready access to the entire cell volume's worth of reactants. Therefore, the reaction area also was not directly in the path of the FT-IR beam. Studies in which the 308-nm laser beam was moved once in the middle of the experiment confirmed that significantly higher degradation yields, on the order of 40%, could be obtained via this method.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.