Reaction dynamics of C(3P) with chloroform

Journal of Physical Chemistry A

Volumn 101, Issue 33, 1997, Pages 5846-5851

  Choi, J H ^a,b   Scholefield, M R ^a   Kolosov, D ^a   Reisler, H ^a  

^a UNIVERSITY OF SOUTHERN CALIFORNIA   (United States)

^b Korea University   (South Korea)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL REACTIONS; CHLORINE COMPOUNDS; ELECTRON TRANSITIONS; FLUORESCENCE; MOLECULAR VIBRATIONS; ORGANIC COMPOUNDS; REACTION KINETICS;

CHLOROFORM;

MOLECULAR DYNAMICS;

EID: 0031207468     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp970999l     Document Type: Article

References (55)

1. For reviews, see: (a) Mackay, C. in Carbenes; Moss, R. A., Jones, M., Eds.; Wiley and Sons: New York, 1975; Vol. II. (b) Shevlin, P. B. In Reactive Intermediates; Abramovich, R. A., Ed.; Plenum: New York, 1980; Vol. I.
2. For reviews, see: (a) Mackay, C. in Carbenes; Moss, R. A., Jones, M., Eds.; Wiley and Sons: New York, 1975; Vol. II. (b) Shevlin, P. B. In Reactive Intermediates; Abramovich, R. A., Ed.; Plenum: New York, 1980; Vol. I.
3. Gaydon, A. G. The Spectroscopy of Flames, 2nd ed.; Chapman and Hall: London, 1974.
4. (a) Anderson, D. J.; Rosenfeld, R. N. J. Chem. Phys. 1990, 94, 7857.
5. (b) Strauss, C. E. M.; Kable S. H.; Chawla, G. K.; Houston, P. L. J. Chem. Phys. 1990, 94, 1837.
6. Reid, S. A.; Winterbottom, F.; Scott, D. C.; de Juan, J.; Reisler, H. Chem. Phys. Lett. 1992, 189, 430.
7. Scott, D. C.; Winterbottom, F.; Scholefield, M. R.; Goyal, S.; Reisler, H. Chem. Phys. Lett. 1994, 222, 471.
8. Scholefield, M. R.; Goyal, S.; Choi, J.-H.; Reisler, H. J. Phys. Chem. 1995, 99, 14605.
9. Costes, M.; Naulin, C.; Dorthe, G.; Daleau, G.; Joussot-Dubien, J.; Lalaude, C.; Vinckert, M.; Destor, A.; Vaucamps, C.; Nouchi, G. J. Phys. E 1989, 22, 1017.
10. Kaiser, R. I.; Suits, A. G Rev. Sci. Instrum. 1995, 66, 5405.
11. (a) Harding, L. B. J. Phys. Chem. 1983, 87, 441.
12. (b) Harding, L. B.; Guadagnini, R.; Schatz, G. C. J. Phys. Chem. 1993, 97, 5472.
13. Guadagnini, R.; Schatz, G. C. J. Phys. Chem. 1996, 100, 18944.
14. (a) Luntz, A. C. J. Chem. Phys. 1980, 73, 1143.
15. (b) Andresen, P.; Luntz, A. C. J. Chem. Phys. 1980, 72, 5842.
16. (c) Howard, R. E.; McLean, A. D.; Lester, W. A. J. Chem. Phys. 1979, 71, 2412.
17. (a) Skell, P. S.; Havel, J. S.; McGlinchey M. J. Acc. Chem. Res. 1973, 6, 97.
18. (b) Skell, P. S.; Engel, R. R. J. Am. Chem. Soc. 1965, 87, 4663; 1966, 88, 3749, 4883; 1967, 89, 2912.
19. (b) Skell, P. S.; Engel, R. R. J. Am. Chem. Soc. 1965, 87, 4663; 1966, 88, 3749, 4883; 1967, 89, 2912.
20. (b) Skell, P. S.; Engel, R. R. J. Am. Chem. Soc. 1965, 87, 4663; 1966, 88, 3749, 4883; 1967, 89, 2912.
21. (c) Skell, P. S.; Harris, R. F. J. Am. Chem. Soc. 1965, 87, 5807; 1969, 91, 4440.
22. (c) Skell, P. S.; Harris, R. F. J. Am. Chem. Soc. 1965, 87, 5807; 1969, 91, 4440.
23. The energetics of the reactions are calculated for ground-state reactants and products by using heats of formation taken from: (a) Chase, M. W., Jr.; Davies, C. A.; Downey, J. R., Jr.; Frurip, D. J.; McDonald, R. A.; Syverud, A. N. JANAF Thermochemical Tables, 3rd ed., Part I; J. Phys. Chem. Ref. Data 1985, 14 (Suppl. 1). (b) Yang, X.; Felder, P.; Huber, J. R. Chem. Phys. 1994, 189, 127. (c) Rodriquez, C. F.; Hopkinson, A. C. J. Phys. Chem. 1993, 97, 849. (d) Holmes, J. L.; Lossing, F. P. J. Am. Chem. Soc. 1988, 110, 7343. (e) Lias, S. G.; Karpas, Z.; Liebman, J. F. J. Am. Chem. Soc. 1985, 107, 6089.
24. The energetics of the reactions are calculated for ground-state reactants and products by using heats of formation taken from: (a) Chase, M. W., Jr.; Davies, C. A.; Downey, J. R., Jr.; Frurip, D. J.; McDonald, R. A.; Syverud, A. N. JANAF Thermochemical Tables, 3rd ed., Part I; J. Phys. Chem. Ref. Data 1985, 14 (Suppl. 1). (b) Yang, X.; Felder, P.; Huber, J. R. Chem. Phys. 1994, 189, 127. (c) Rodriquez, C. F.; Hopkinson, A. C. J. Phys. Chem. 1993, 97, 849. (d) Holmes, J. L.; Lossing, F. P. J. Am. Chem. Soc. 1988, 110, 7343. (e) Lias, S. G.; Karpas, Z.; Liebman, J. F. J. Am. Chem. Soc. 1985, 107, 6089.
25. The energetics of the reactions are calculated for ground-state reactants and products by using heats of formation taken from: (a) Chase, M. W., Jr.; Davies, C. A.; Downey, J. R., Jr.; Frurip, D. J.; McDonald, R. A.; Syverud, A. N. JANAF Thermochemical Tables, 3rd ed., Part I; J. Phys. Chem. Ref. Data 1985, 14 (Suppl. 1). (b) Yang, X.; Felder, P.; Huber, J. R. Chem. Phys. 1994, 189, 127. (c) Rodriquez, C. F.; Hopkinson, A. C. J. Phys. Chem. 1993, 97, 849. (d) Holmes, J. L.; Lossing, F. P. J. Am. Chem. Soc. 1988, 110, 7343. (e) Lias, S. G.; Karpas, Z.; Liebman, J. F. J. Am. Chem. Soc. 1985, 107, 6089.
26. The energetics of the reactions are calculated for ground-state reactants and products by using heats of formation taken from: (a) Chase, M. W., Jr.; Davies, C. A.; Downey, J. R., Jr.; Frurip, D. J.; McDonald, R. A.; Syverud, A. N. JANAF Thermochemical Tables, 3rd ed., Part I; J. Phys. Chem. Ref. Data 1985, 14 (Suppl. 1). (b) Yang, X.; Felder, P.; Huber, J. R. Chem. Phys. 1994, 189, 127. (c) Rodriquez, C. F.; Hopkinson, A. C. J. Phys. Chem. 1993, 97, 849. (d) Holmes, J. L.; Lossing, F. P. J. Am. Chem. Soc. 1988, 110, 7343. (e) Lias, S. G.; Karpas, Z.; Liebman, J. F. J. Am. Chem. Soc. 1985, 107, 6089.
27. The energetics of the reactions are calculated for ground-state reactants and products by using heats of formation taken from: (a) Chase, M. W., Jr.; Davies, C. A.; Downey, J. R., Jr.; Frurip, D. J.; McDonald, R. A.; Syverud, A. N. JANAF Thermochemical Tables, 3rd ed., Part I; J. Phys. Chem. Ref. Data 1985, 14 (Suppl. 1). (b) Yang, X.; Felder, P.; Huber, J. R. Chem. Phys. 1994, 189, 127. (c) Rodriquez, C. F.; Hopkinson, A. C. J. Phys. Chem. 1993, 97, 849. (d) Holmes, J. L.; Lossing, F. P. J. Am. Chem. Soc. 1988, 110, 7343. (e) Lias, S. G.; Karpas, Z.; Liebman, J. F. J. Am. Chem. Soc. 1985, 107, 6089.
28. The energetics of the reactions are calculated for ground-state reactants and products by using heats of formation taken from: (a) Chase, M. W., Jr.; Davies, C. A.; Downey, J. R., Jr.; Frurip, D. J.; McDonald, R. A.; Syverud, A. N. JANAF Thermochemical Tables, 3rd ed., Part I; J. Phys. Chem. Ref. Data 1985, 14 (Suppl. 1). (b) Yang, X.; Felder, P.; Huber, J. R. Chem. Phys. 1994, 189, 127. (c) Rodriquez, C. F.; Hopkinson, A. C. J. Phys. Chem. 1993, 97, 849. (d) Holmes, J. L.; Lossing, F. P. J. Am. Chem. Soc. 1988, 110, 7343. (e) Lias, S. G.; Karpas, Z.; Liebman, J. F. J. Am. Chem. Soc. 1985, 107, 6089.
29. (a) Verma, R. D.; Mulliken, R. S. J. Mol. Spectrose. 1961, 6, 419.
30. (b) Gordon, R. D.; King, G. W. Can. J. Phys. 1961, 39, 252.
31. (c) Merer, A. J.; Travis, D. N.; Watson, J. K. G. Can. J. Phys. 1966, 44, 447.
32. (a) Mélen, F.; Houbrechts, Y.; Dubois, I.; Bredohl, H. J. Phys. B: At. Mol. Phys. 1983, 16, 2523.
33. (b) Sharpe, S. W.; Johnson, P. M. J. Mol. Spectrosc. 1986, 116, 247.
34. Robie, D. C.; De Juan, J.; Reisler, H. J. Mol. Spectrosc. 1991, 150, 296.
35. (a) Larsson, M.; Blomberg, M.; Siegbahn, P. Mol. Phys. 1982, 46, 365.
36. (b) Gottscho, R.; Burton, R. H.; Davis, G. P. J. Chem. Phys. 1982, 77, 5298.
37. Gausset, L.; Herzberg, G.; Lagerqvist, A.; Rosen, B. Astrophys. J. 1965, 142, 45.
38. Kolodney, E.; Amirav, A. Chem. Phys. 1983, 82, 269.
39. Kovacs, I. Rotational Structure in the Spectra of Diatomic Molecules; American Elsevier: New York, 1969.
40. Kusakabe, M.; Ito, Y.; Tokue, I. Chem. Phys. 1993, 170, 243.
41. Levine, R. D.; Bernstein, R. B. Molecular Reaction Dynamics and Chemical Reactivity; Oxford University Press; New York, 1987.
42. Zamir, E.; Levine, R. D. Chem. Phys. 1980, 52, 253.
43. 5 are out-of-plane, and the remainder are in the plane. (b) Rodriquez, C. F.; Bohme, D. K.; Hopkinson, A. C. J. Phys. Chem. 1996, 100, 2942.
44. 5 are out-of-plane, and the remainder are in the plane. (b) Rodriquez, C. F.; Bohme, D. K.; Hopkinson, A. C. J. Phys. Chem. 1996, 100, 2942.
45. (a) Irikura, K. K.; Goddard, W. A., III; Beauchamp, J. L. J. Am. Chem. Soc. 1992, 114, 48.
46. (b) Scuseria, G. E.; Durán, M.; Maclagan, G. A. R.; Schaefer, H. F. III. J. Am. Chem. Soc. 1986, 108, 3248.
47. (c) Sakai, S.; Deisz, J.; Gordon, M. S. J. Phys. Chem. 1989, 93, 1888.
48. Nishiyama, N.; Sekiya, H.; Nishimura, Y. J. Chem. Phys. 1986, 84, 5213.
49. (a) Polanyi, J. C. Acc. Chem. Res. 1972, 5, 161.
50. (b) Polanyi, J. C.; Schreiber, J. L. In Physical Chemistry, an Advanced Treatise; Jost, W., Ed.; Academic: New York, 1974; Vol. 6A, p 383.
51. (c) Parr, C. A.; Polanyi, J. C.; Wong, W. H. J. Chem. Phys. 1973, 58, 5.
52. (a) Kaiser, R. I.; Lee, Y. T.; Suits, A. G. J. Chem. Phys. 1995, 103, 10395.
53. (b) Kaiser, R. I.; Lee, Y. T.; Suits, A. G. J. Chem. Phys. 1996, 105, 8721.
54. -1.
55. Scholefield, M. R.; Choi, J.-H.; Reisler, H. Manuscript in preparation.