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The diastereomeric ratio was determined by NMR or by GC analysis (β-permethylated, 25 m, 90 kPa, 40°C) of (1-methoxyethyl)benzene after cleavage of the selenium moiety. For the radical cleavage, see: Clive, D. L. J.; Chittattu, G. J.; Farina, V.; Kiel, W. A.; Menchen, S. M.; Russell, C. G.; Singh, A.; Wong, C. K., Curtis, N. J. J. Am. Chem. Soc. 1980, 102, 4438-4447.
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39
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2642660924
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After addition of each alkene, the reaction mixture was stirred at -100 °C for 90 min
-
After addition of each alkene, the reaction mixture was stirred at -100 °C for 90 min.
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2642626111
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N2-displacement does not occur at temperatures below -25 °C
-
N2-displacement does not occur at temperatures below -25 °C.
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45
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0011954260
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Spectroscopic data: Krief, A.; Dumont, W.; Clarembeau, M.; Bernard, G.; Badaoui, E. Tetrahedron 1989, 45, 2005-2022. Preparation: Sakakibara, M.; Katsumata, K.; Watanabe, Y.; Toru, T.; Ueno, Y. Synthesis 1992, 377-379.
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