Rubber-elasticity of hybrid organic-inorganic composites evaluated using dynamic mechanical spectroscopy and equilibrium swelling

Journal of Applied Polymer Science

Volumn 68, Issue 6, 1998, Pages 947-957

  Miller, Thomas M ^a   Zhao, Licheng ^a   Brennan, Anthony B ^a  

^a J Crayton Pruitt Family Department of Biomedical Engineering   (United States)

Author keywords

Average molar mass between crosslinks; Dynamic mechanical spectroscopy; Hybrid organic inorganic composites; Rubber elasticity theory; Sol gel processing

Indexed keywords

AGING OF MATERIALS; COMPUTATIONAL METHODS; CROSSLINKING; ELASTIC MODULI; INORGANIC POLYMERS; MATHEMATICAL MODELS; ORGANIC POLYMERS; PHASE SEPARATION; SILICATES; SOL-GELS; SPECTROSCOPIC ANALYSIS; SWELLING;

DYNAMIC MECHANICAL SPECTROSCOPY; FLORY-REHNER EQUATION; POLYSILICATE; POLYTETRAMETHYLENE OXIDE; RUBBER ELASTICITY THEORY;

COMPOSITE MATERIALS;

EID: 0032499337     PISSN: 00218995     EISSN: None     Source Type: Journal    
DOI: 10.1002/(sici)1097-4628(19980509)68:6<947::aid-app8>3.3.co;2-6     Document Type: Article

References (42)

1. A. B. Brennan and T. M. Miller, in Kirk-Othmer Encyclopedia of Chemical Technology, Vol. 12, 4th ed., John Wiley and Sons, Inc., New York, 1994, p. 644.
2. J. Wen and G. L. Wilkes, Chem. Mater., 8, 1667 (1996).
3. J. E. Mark, Y. P. Ningand, C. J. Jiang, and M. Y. Tang, Polymer, 26, 2069 (1985).
4. G. B. Sohoni and J. E. Mark, J. Appl. Polym. Sci., 45, 1763 (1992).
5. H. H. Huang, B. Orler, and G. L. Wilkes, Macromolecules, 20, 1322 (1987).
6. F. Surivet, T. M. Lam, J. P. Pascault, and C. Mai, Macromolecules, 25, 5742 (1992).
7. H.-H. Huang, R. H. Glaser, and G. L. Wilkes, in Inorganic and Organometallic Polymers, ACS Symposium Series 360, American Chemical Society, Washington, DC, 1987, p. 355.
8. A. B. Brennan and G. L. Wilkes, Polymer, 32, 733 (1991).
9. D. E. Rodrigues, A. B. Brennan, C. Betrabet, B. W. Wang, and G. L. Wilkes, Chem. Mater., 4, 1437 (1992).
10. J. L. W. Noell, G. L. Wilkes, D. K. Mohanty, and J. E. McGrath, J. Appl. Polym. Sci., 40, 1177 (1990).
11. A. B. Brennan, Ph.D. dissertation, Virginia Polytechnic Institute and State University, Blacksburg, VA, 1990.
12. A. Okada, Polym. Prep., Am. Chem. Soc. Div. Polym. Chem., 28, 447 (1987).
13. D. Tian, Ph. Dubois, and R. Jerome, Polymer, 37, 3983 (1996).
14. C. J. Wung, Y. Pang, P. N. Prasad, and F. E. Karasz, Polymer, 32, 605 (1991).
15. C. J. T. Landry, B. K Coltrain, J. A. Wesson, N. Zumbulyadis, and J. L. Lippert, Polymer, 33, 1496 (1992).
16. C. J. T. Landry, B. K. Coltrain, and B. K. Brady, Polymer, 33, 1486 (1992).
17. M. Toki, T. Y. Chow, T. Ohnaka, H. Samura, and T. Saegusa, Polym. Bull., 29, 653 (1992).
18. B. M. Novak and M. W. Ellsworth, Mater. Sci. Eng., A162, 257 (1993).
19. P. Bosch, F. Del Monte, J. L. Mateo, and D. Levy, J. Polym. Sci.: Poly. Chem., 34, 3289 (1996).
20. C. L. Jackson, B. J. Bauer, A. I. Nakatani, and J. D. Barnes, Chem. Mater., 8, 727 (1996).
21. B. J. Bauer, D.-W. Liu, C. L. Jackson, and J. D. Barnes, Polym. Adv. Tech., 7, 333 (1995).
22. K. A. Mauritz, J. D. Stefanithis, S. V. Davis, R. W. Sheetz, R. K. Pope, G. L. Wilkes, and H.-H. Huang, J. Appl. Polym. Sci., 55, 181 (1995).
23. E. P. Giannelis, Adv. Mater., 8, 29 (1996).
24. K. J. Becker, J. A. Jensen, and A. Lukas III, U.S. Pat. 5,612,414 (1997).
25. T. M. Keller and D. Y. Son, U.S. Pat. 5,563,181 (1996).
26. K. G. Sharp and M. J. Michalczyk, U.S. Pat. 5,548,051 (1996).
27. A. B. Brennan and T. M. Miller, Chem. Mater., 6, 262 (1994).
28. A. B. Brennan, T. M. Miller, and R. V. Vinocur, in Hybrid Organic-Inorganic Composites, J. E. Mark, C. Y.-C. Lee, and P. A. Bianconi, Eds., ACS Symposium Series 585, American Chemical Society, Washington, DC, 1995, p. 142.
29. A. B. Brennan and T. M. Miller, in Better Ceramics Through Chemistry VII: Organic / Inorganic Hybrid Materials, B. K. Coltrain, C. Sanchez, D. W. Schaefer, and G. L. Wilkes, Eds., Mater. Res. Soc. Symp. Proc. Vol. 435, Materials Research Society, Pittsburgh, PA, 1996, p. 155.
30. R. K. Iler, The Chemistry of Silica, John Wiley & Sons, Inc., New York, 1979, p. 40.
31. G. L. Wilkes, Polymer Science and Technology: An Interdisciplinary Approach; Part II Physical Aspects of Polymers, American Chemical Society, Washington, DC, 1978, p. 129.
32. P. J. Flory, Principles of Polymer Chemistry, Cornell University Press, Ithaca, NY, 1953, p. 576.
33. P. J. Flory, J. Chem. Phys., 18, 108 (1950).
34. G. M. Bristow and W. F. Watson, Trans. Farad. Soc., 54, 1731 (1958).
35. R. H. Glaser, G. L. Wilkes, and C. E. Bronniman, J. Non-Cryst. Solids, 113, 73 (1989).
36. R. M. Almeida and C. G. Pantano, J. Appl. Phys., 68, 4225 (1990).
37. D. L. Wood and E. M. Rabinovich, Appl. Spec., 43, 263 (1989).
38. A. Bertoluzza, C. Fagnano, M. A. Morelli, V. Gottardi, and M. Guglielmi, J. Non-Cryst. Solids, 48, 117 (1982).
39. H. Yoshino, K. Kamiya, and H. Nasu, J. Non-Cryst. Solids, 126, 68 (1990).
40. N. J. Harrick, Internal Reflection Spectroscopy, Wiley-Interscience, New York, 1967.
41. K. A. Mauritz, R. F. Storey, and C. K. Jones, in Multiphase Polymer Materials: Blends, Ionomers and Interpenetrating Networks, L. A. Ultracki and R. A. Weiss, Eds., ACS Symposium Series, American Chemical Society, Washington, DC, 1989, p. 401.
42. R. V. Gummaraju, R. B. Moore, and K. A. Mauritz, J. Polym. Sci.: Polym. Phys., 34, 2383 (1996).