Studies on enantiotopic differentiation in the horse liver alcohol dehydrogenase catalysed reduction of chiral tricarbonyl(η6- benzaldehyde)chromium complexes

Tetrahedron Asymmetry

Volumn 9, Issue 9, 1998, Pages 1497-1504

  Baldoli, Clara ^a   Del Buttero, Paola ^a   Maiorana, Stefano ^a   Ottolina, Gianluca ^a   Riva, Sergio ^a  

^a CNR   (Italy)

Author keywords

[No Author keywords available]

Indexed keywords

ALCOHOL DEHYDROGENASE; CHROMIUM DERIVATIVE; METAL COMPLEX;

ARTICLE; CHIRALITY; CONTROLLED STUDY; ENANTIOMER; ENZYME ACTIVE SITE; ENZYME SPECIFICITY; ENZYME SUBSTRATE COMPLEX; HORSE; NONHUMAN; PRIORITY JOURNAL; REDUCTION; STEREOCHEMISTRY; STEREOSPECIFICITY;

EID: 0032496255     PISSN: 09574166     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0957-4166(98)00105-0     Document Type: Article

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27. This was due to the fact that benzaldehyde complexes were retained on the stationary phase of chiral HPLC column.
28. 2 solution, gave a positive Cotton effect for the n-π* transition with an extremum at λ=323 (Δε=+3250) for 1e, λ=324 (Δε=+2371) for 1f, λ=322 (Δε=+1030) for 1g and λ=315(Δε=+210) for 1h.
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