Reactivity of perfluoro-n-alkyl radicals with reluctant substrates. Rates of addition to R(F)CH2CH=CH2 and R(F)CH=CH2

Tetrahedron

Volumn 54, Issue 32, 1998, Pages 9273-9280

  Delest, Bruno ^a   Shtarev, Alexander B ^a   Dolbier Jr , William R ^a  

^a University of Florida ^*  (United States)

Author keywords

[No Author keywords available]

Indexed keywords

DECANE; PERFLUORO COMPOUND; RADICAL;

ARTICLE; CHEMICAL REACTION; COMPETITIVE INHIBITION; HYDROGEN BOND; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PHOTOLYSIS; PRIORITY JOURNAL; PROTON NUCLEAR MAGNETIC RESONANCE; REACTION ANALYSIS;

EID: 0032490923     PISSN: 00404020     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4020(98)00568-7     Document Type: Article

References (20)

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2. (b) Dolbier, W. R., Jr.; Rong, X. X.; Pan, H.-Q.; Smart, B. E. J. Am. Chem. Soc. 1994, 116, 4521-4522;
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4. (d) Avila, D. V.; Ingold, K. U.; Lusztyk, J.; Dolbier, W. R., Jr.; Pan, H.-Q. Tetrahedron 1996, 52, 12351-12356;
5. (e) Dolbier, W. R., Jr.; Li, A. R. J. Chem. Soc., Perkin Trans. 2 1998, 79-82;
6. (f) Dolbier, W. R., Jr.; Rong, X. X.; Bartberger, M. D.; Koroniak, H.; Smart, B. E.; Yang, Z.-Y. J. Chem. Soc., Perkin Trans. 2 1998, 219-232.
7. 2. Dolbier, W. R., Jr. Chem. Rev. 1996, 96, 1557-1595;
8. (b) Dolbier, W. R., Jr. Topics in Current Chem. 1997, 192, 97-163.
9. -1.
10. 4. Bravo, A.; Bjørsvik, H. R.; Fontana, F.; Liquori, L.; Mele, A.; Minisci, F. J. Org. Chem. 1997, 62, 7128-7136.
11. 7
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14. 9
15. 9. Shtarev, A.; Dolbier, W. R., Jr.; Smart, B. E.; Yang, Z. Y. unpublished results.
16. 11
17. 11. Curran, D. P.; Haddida, S. J. Am. Chem. Soc. 1996, 118, 2531-2532.
18. 12. We thank a referee of an earlier paper in this series for causing us to examine more closely the problem of non-zero intercepts.
19. 13. Brace, N. O. J. Org. Chem. 1963, 28, 3093-3102.
20. 14. Dolbier, W. R., Jr.; Bartberger, M. D.; Lusztyk, J.; Ingold, K. U. Tetrahedron 1997, 53, 9857-9880.