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Volumn 52, Issue 38, 1996, Pages 12351-12356

Perfluoro-tert-butyl, a reactive, neutral, electrophilic carbon-centered radical par excellence

Author keywords

[No Author keywords available]

Indexed keywords

ALKENE DERIVATIVE;

EID: 0030590428     PISSN: 00404020     EISSN: None     Source Type: Journal    
DOI: 10.1016/0040-4020(96)00742-9     Document Type: Article
Times cited : (10)

References (32)
  • 1
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    • Issued as NRCC No. 39116
    • 1. Issued as NRCC No. 39116.
  • 2
    • 85030272173 scopus 로고    scopus 로고
    • NRCC Research Associate 1992-94
    • 2. (a) NRCC Research Associate 1992-94.
  • 3
    • 85030274133 scopus 로고    scopus 로고
    • Steacie Institute
    • (b) Steacie Institute.
  • 4
    • 85030277504 scopus 로고    scopus 로고
    • University of Florida
    • (c) University of Florida.
  • 10
    • 85030274918 scopus 로고    scopus 로고
    • note
    • 9b, 30 and 31, respectively.
  • 14
    • 85030279441 scopus 로고    scopus 로고
    • note
    • 2 are essentially equal.
  • 15
    • 85030270240 scopus 로고    scopus 로고
    • note
    • 5,13 for methyl methacrylate and acrylonitrile which do not yield easily observed product radicals.
  • 17
    • 85030272808 scopus 로고    scopus 로고
    • note
    • -1) = 12.7 - 0.60 IP/eV
  • 19
    • 85030274879 scopus 로고    scopus 로고
    • note
    • 17b correlate well with the overall reaction enthalpies, with only minor polar effects.
  • 22
    • 85030277178 scopus 로고    scopus 로고
    • note
    • m and F values for the perfluoroisopropyl group have been underestimated.
  • 23
    • 85005722068 scopus 로고
    • 19. Wong, M. W.; Pross, A.; Radom, L. Israel J. Chem. 1993, 33, 415-425. Wong, M. W.; Pross, A.; Radom, L. J. Am. Chem. Soc. 1994, 116, 6284-6292. Wong, M. W.; Pross, A.; Radom, L. J. Am. Chem. Soc. 1994, 116, 11938-11943.
    • (1993) Israel J. Chem. , vol.33 , pp. 415-425
    • Wong, M.W.1    Pross, A.2    Radom, L.3
  • 24
    • 0001051921 scopus 로고
    • 19. Wong, M. W.; Pross, A.; Radom, L. Israel J. Chem. 1993, 33, 415-425. Wong, M. W.; Pross, A.; Radom, L. J. Am. Chem. Soc. 1994, 116, 6284-6292. Wong, M. W.; Pross, A.; Radom, L. J. Am. Chem. Soc. 1994, 116, 11938-11943.
    • (1994) J. Am. Chem. Soc. , vol.116 , pp. 6284-6292
    • Wong, M.W.1    Pross, A.2    Radom, L.3
  • 25
    • 0041059705 scopus 로고
    • 19. Wong, M. W.; Pross, A.; Radom, L. Israel J. Chem. 1993, 33, 415-425. Wong, M. W.; Pross, A.; Radom, L. J. Am. Chem. Soc. 1994, 116, 6284-6292. Wong, M. W.; Pross, A.; Radom, L. J. Am. Chem. Soc. 1994, 116, 11938-11943.
    • (1994) J. Am. Chem. Soc. , vol.116 , pp. 11938-11943
    • Wong, M.W.1    Pross, A.2    Radom, L.3
  • 29
    • 85030279220 scopus 로고    scopus 로고
    • note
    • 22 and pyramidalization is relatively facile.
  • 30
    • 0001637204 scopus 로고
    • 22. See, e.g., Griller, D.; Ingold, K. U.; Krusic, P. J.; Fischer, H. J. Am. Chem. Soc. 1978 700, 6750-6752. Schrader, B.; Pacansky, J.; Pfieffer, U. J. Phys. Chem. 1984, 88, 4069-4073. Paddon-Row, M. N.; Houk, K. N. J. Phys. Chem. 1985, 89, 3771-3774.
    • (1978) J. Am. Chem. Soc. , vol.700 , pp. 6750-6752
    • Griller, D.1    Ingold, K.U.2    Krusic, P.J.3    Fischer, H.4
  • 31
    • 0011809225 scopus 로고
    • 22. See, e.g., Griller, D.; Ingold, K. U.; Krusic, P. J.; Fischer, H. J. Am. Chem. Soc. 1978 700, 6750-6752. Schrader, B.; Pacansky, J.; Pfieffer, U. J. Phys. Chem. 1984, 88, 4069-4073. Paddon-Row, M. N.; Houk, K. N. J. Phys. Chem. 1985, 89, 3771-3774.
    • (1984) J. Phys. Chem. , vol.88 , pp. 4069-4073
    • Schrader, B.1    Pacansky, J.2    Pfieffer, U.3
  • 32
    • 0001100889 scopus 로고
    • 22. See, e.g., Griller, D.; Ingold, K. U.; Krusic, P. J.; Fischer, H. J. Am. Chem. Soc. 1978 700, 6750-6752. Schrader, B.; Pacansky, J.; Pfieffer, U. J. Phys. Chem. 1984, 88, 4069-4073. Paddon-Row, M. N.; Houk, K. N. J. Phys. Chem. 1985, 89, 3771-3774.
    • (1985) J. Phys. Chem. , vol.89 , pp. 3771-3774
    • Paddon-Row, M.N.1    Houk, K.N.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.