A surprising adduct of a closo cluster

Angewandte Chemie - International Edition

Volumn 37, Issue 10, 1998, Pages 1412-1415

  Wesemann, Lars ^a   Ramjoie, Yves ^a   Trinkaus, Michael ^a   Ganter, Beate ^a   Müller, Jens ^a  

^a RWTH AACHEN UNIVERSITY   (Germany)

Author keywords

Ab initio calculations; Boron; Clusters; Silicon

Indexed keywords

EID: 0032486343     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3773(19980605)37:10<1412::AID-ANIE1412>3.0.CO;2-4     Document Type: Article

References (28)

1. M. F. Hawthorne, D. C. Young, P. M. Garnett, D. A. Owen, S. G. Schwerin, F. N. Tebbe, P. A. Wegner, J. Am. Chem. Soc. 1968, 90, 862-868.
2. a) D. Seyferth, K. Büchner, W. S. Rees, Jr., W. M. Davis, Angew. Chem. 1990, 102, 911-913; Angew. Chem. Int. Ed. Engl. 1990, 29, 918-920;
3. a) D. Seyferth, K. Büchner, W. S. Rees, Jr., W. M. Davis, Angew. Chem. 1990, 102, 911-913; Angew. Chem. Int. Ed. Engl. 1990, 29, 918-920;
4. b) D. Seyferth, K. D. Büchner, W. S. Rees, L. Wesemann, W. M. Davis, S. S. Bukalov, L. A. Leites, H. Bock, B. Solouki, J. Am. Chem. Soc. 1993, 115, 3586-3594.
5. L. Wesemann, U. Englert, D. Seyferth, Angew. Chem. 1995, 107, 2435-2436; Angew. Chem. Int. Ed. Engl. 1995, 34, 2236-2238.
6. L. Wesemann, U. Englert, D. Seyferth, Angew. Chem. 1995, 107, 2435-2436; Angew. Chem. Int. Ed. Engl. 1995, 34, 2236-2238.
7. L. Wesemann, Y. Ramjoie, B. Ganter, B. Wrackmeyer, Angew. Chem. 1997, 109, 902-904; Angew. Chem. Int. Ed. Engl. 1997, 36, 888-890.
8. L. Wesemann, Y. Ramjoie, B. Ganter, B. Wrackmeyer, Angew. Chem. 1997, 109, 902-904; Angew. Chem. Int. Ed. Engl. 1997, 36, 888-890.
9. L. Wesemann, Y. Ramjoie, M. Trinkaus, B. Ganter, Inorg. Chem. 1997, 36, 5192-5197.
10. 0); hydrogen atoms from the second THF molecule (bonded to C23-C26) were treated as riding atoms, all other hydrogen atoms were refined isotropically. Crystallographic data (excluding structure factors) for the structure reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-100936. Copies of the data can be obtained free of charge on application to CCDC, 12 Union Road, Cambridge CB2 1EZ, UK (fax: (+44) 1223-336-033: e-mail: deposit@ccdc.cam.ac.uk).
11. MolEN, An interactive Structure Solution Procedure, Enraf-Nonius, Delft (Netherlands) 1990.
12. A. L. Spek, Acta Crystallogr. Sect. A 1990, 46, C34.
13. T. M. Klapötke, I. C. Tornieporth-Oetting, Nichtmetallchemie, VCH, Weinheim, 1994, pp 254-255.
14. C. Boisson, J. C. Berthet, M. Ephritikhine, M. Lance, M. Nierlich, J. Organomet. Chem. 1997, 531, 115-119.
15. 12).
16. For application to borane chemistry see: X. Y. Yang, H. Jiao, P. von R. Schleyer, Inorg. Chem. 1997, 36, 4897-4899, and references therein.
17. a) A. D. Becke, Phys. Rev. 1988, A38, 3098-3100;
18. b) A. D. Becke, J. Chem. Phys. 1993, 98, 5648-5652;
19. c) C. Lee, W. Yong, R. G. Parr, Phys. Rev. 1988, B37, 785-789.
20. All calculations were performed with Gaussian 94; M. J. Frisch, G. W. Trucks, H. B. Schlegel, P. M. W. Gill, B. G. Johnson, M. A. Robb, J. R. Cheeseman, T. Keith, G. A. Petersson, J. A. Montgomery, K. Raghavachari, M. A. Al-Laham, V. G. Zakrzewski, J. V. Ortiz, J. B. Foresman, J. Cioslowski, B. B. Stefanov, A. Nanayakkara, M. Challacombe, C. Y. Peng, P. Y. Ayala, W. Chen, M. W. Wong, J. L. Andres, E. S. Replogle, R. Gomperts, R. L. Martin, D. J. Fox, J. S. Binkley, D. J. Defrees, J. Baker, J. P. Stewart, M. Head-Gordon, C. Gonzalez, J. A. Pople, Gaussian, Inc., Pittsburgh, PA, 1995.
21. K. Wade, Adv. Inorg. Chem. Radiochem. 1976, 18, 1-66; R. E. Williams, Advances in Boron Chemistry (Ed.: W. Siebert), The Royal Society of Chemistry, Cambridge, 1997.
22. K. Wade, Adv. Inorg. Chem. Radiochem. 1976, 18, 1-66; R. E. Williams, Advances in Boron Chemistry (Ed.: W. Siebert), The Royal Society of Chemistry, Cambridge, 1997.
23. F. Meyer, J. Müller, P. Paetzold, R. Boese, Angew. Chem. 1992, 104, 1221-1222; Angew. Chem. Int. Ed. Engl. 1992, 31, 1227-1228.
24. F. Meyer, J. Müller, P. Paetzold, R. Boese, Angew. Chem. 1992, 104, 1221-1222; Angew. Chem. Int. Ed. Engl. 1992, 31, 1227-1228.
25. M. E. Jung, H. Xia, Tetrahedron Lett. 1988, 297-300; K. Tamao, T. Hayashi, Y. Ito, J. Am. Chem. Soc. 1990, 112, 2422-2423.
26. M. E. Jung, H. Xia, Tetrahedron Lett. 1988, 297-300; K. Tamao, T. Hayashi, Y. Ito, J. Am. Chem. Soc. 1990, 112, 2422-2423.
27. 29Si of TMS).
28. Correct C,H analyses for 5 and 6 were obtained.