Synthesis of cationic group 4 metal compounds by protonolysis of amide precursors: Crystal structure of [Ti(NMe2)3(NC5H5)2][BPh4]

Journal of Organometallic Chemistry

Volumn 531, Issue 1-2, 1997, Pages 115-119

  Boisson, Christophe ^a   Berthet, Jean Claude ^a   Ephritikhine, Michel ^a   Lance, Monique ^a   Nierlich, Martine ^a  

^a CEA SACLAY   (France)

Author keywords

Amide; Cationic; Group 4

Indexed keywords

EID: 0031569155     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0022-328X(96)06701-0     Document Type: Article

References (33)

1. [1] J.C. Berthet, C. Boisson, M. Lance, J. Vigner, M. Nierlich and M. Ephritikhine, J. Chem. Soc., Dalton Trans., (1995) 3019.
2. [2] J.C. Berthet, C. Boisson, M. Lance, J. Vigner, M. Nierlich and M. Ephritikhine, J. Chem. Soc., Dalton Trans., (1995) 3027.
3. [3] C. Airoldi, D.C. Bradley, H. Chudzynska, M.B. Hursthouse, K.M.A. Malik and P.R. Raithby, J. Chem. Soc., Dalton Trans., (1980) 2010.
4. [4] A.L. Casalnuovo, J.C. Calabrese and D. Milstein, J. Am. Chem. Soc., 110 (1988) 110; G.C. Martin, G.J. Palenik and J.M. Boncella, Inorg. Chem., 29 (1990) 2027; J. Feldman and J.C. Calabrese, J. Chem. Soc., Chem. Commun., (1991) 134.
5. [4] A.L. Casalnuovo, J.C. Calabrese and D. Milstein, J. Am. Chem. Soc., 110 (1988) 110; G.C. Martin, G.J. Palenik and J.M. Boncella, Inorg. Chem., 29 (1990) 2027; J. Feldman and J.C. Calabrese, J. Chem. Soc., Chem. Commun., (1991) 134.
6. [4] A.L. Casalnuovo, J.C. Calabrese and D. Milstein, J. Am. Chem. Soc., 110 (1988) 110; G.C. Martin, G.J. Palenik and J.M. Boncella, Inorg. Chem., 29 (1990) 2027; J. Feldman and J.C. Calabrese, J. Chem. Soc., Chem. Commun., (1991) 134.
7. [5] G. Chandra, T.A. George and M.F. Lappert, J. Chem. Soc., Chem. Commun., (1967) 116; M.G. Clerici and F. Maspero, Synthesis, (1980) 305; P.J. Walsh, A.M. Baranger and R.G. Bergman, J. Am. Chem. Soc., 114 (1992) 1708.
8. [5] G. Chandra, T.A. George and M.F. Lappert, J. Chem. Soc., Chem. Commun., (1967) 116; M.G. Clerici and F. Maspero, Synthesis, (1980) 305; P.J. Walsh, A.M. Baranger and R.G. Bergman, J. Am. Chem. Soc., 114 (1992) 1708.
9. [5] G. Chandra, T.A. George and M.F. Lappert, J. Chem. Soc., Chem. Commun., (1967) 116; M.G. Clerici and F. Maspero, Synthesis, (1980) 305; P.J. Walsh, A.M. Baranger and R.G. Bergman, J. Am. Chem. Soc., 114 (1992) 1708.
10. [6] S. Collins, B.E. Koene, R. Ramachandran and N.J. Taylor, Organometallics, 10 (1991) 2092; Y. Hong, B.A. Kuntz and S. Collins, Organometallics, 12 (1993) 964; D. Röttger, G. Erker, M. Grehl and R. Fröhlich, Organometallics, 13 (1994) 3897.
11. [6] S. Collins, B.E. Koene, R. Ramachandran and N.J. Taylor, Organometallics, 10 (1991) 2092; Y. Hong, B.A. Kuntz and S. Collins, Organometallics, 12 (1993) 964; D. Röttger, G. Erker, M. Grehl and R. Fröhlich, Organometallics, 13 (1994) 3897.
12. [6] S. Collins, B.E. Koene, R. Ramachandran and N.J. Taylor, Organometallics, 10 (1991) 2092; Y. Hong, B.A. Kuntz and S. Collins, Organometallics, 12 (1993) 964; D. Röttger, G. Erker, M. Grehl and R. Fröhlich, Organometallics, 13 (1994) 3897.
13. [7] C. Boisson, J.C. Berthet, M. Lance, J. Vigner, M. Nierlich and M. Ephritikhine, J. Chem. Soc., Dalton Trans., (1996) 947; C. Boisson, J.C. Berthet, M. Ephritikhine, M. Lance and M. Nierlich, J. Organomet. Chem., 522 (1996) 249.
14. [7] C. Boisson, J.C. Berthet, M. Lance, J. Vigner, M. Nierlich and M. Ephritikhine, J. Chem. Soc., Dalton Trans., (1996) 947; C. Boisson, J.C. Berthet, M. Ephritikhine, M. Lance and M. Nierlich, J. Organomet. Chem., 522 (1996) 249.
15. [8] M.F. Lappert, P.P. Power, A.R. Sanger and R.C. Srivastava, Metal and Metalloid Amides: Syntheses, Structures, and Physical and Chemical Properties, Ellis Horwood, Chichester, UK/Wiley, New York, 1980.
16. [9] E.P. Benzing and W.A. Kornicker, Chem. Ber., 94 (1961) 2263; H. Bürger and H.J. Neese, Z. Anorg. Allg. Chem., 370 (1969) 275; H. Bürger and H.J. Neese, J. Organomet. Chem., 20 (1969) 129; H.J. Neese and H. Bürger, J. Organomet. Chem., 32 (1971) 213; H. Bürger and K.Z. Wiegel, Z. Anorg. Allg. Chem., 398 (1973) 257; H. Bürger and C. Kluess, J. Organomet. Chem., 108 (1976) 69.
17. [9] E.P. Benzing and W.A. Kornicker, Chem. Ber., 94 (1961) 2263; H. Bürger and H.J. Neese, Z. Anorg. Allg. Chem., 370 (1969) 275; H. Bürger and H.J. Neese, J. Organomet. Chem., 20 (1969) 129; H.J. Neese and H. Bürger, J. Organomet. Chem., 32 (1971) 213; H. Bürger and K.Z. Wiegel, Z. Anorg. Allg. Chem., 398 (1973) 257; H. Bürger and C. Kluess, J. Organomet. Chem., 108 (1976) 69.
18. [9] E.P. Benzing and W.A. Kornicker, Chem. Ber., 94 (1961) 2263; H. Bürger and H.J. Neese, Z. Anorg. Allg. Chem., 370 (1969) 275; H. Bürger and H.J. Neese, J. Organomet. Chem., 20 (1969) 129; H.J. Neese and H. Bürger, J. Organomet. Chem., 32 (1971) 213; H. Bürger and K.Z. Wiegel, Z. Anorg. Allg. Chem., 398 (1973) 257; H. Bürger and C. Kluess, J. Organomet. Chem., 108 (1976) 69.
19. [9] E.P. Benzing and W.A. Kornicker, Chem. Ber., 94 (1961) 2263; H. Bürger and H.J. Neese, Z. Anorg. Allg. Chem., 370 (1969) 275; H. Bürger and H.J. Neese, J. Organomet. Chem., 20 (1969) 129; H.J. Neese and H. Bürger, J. Organomet. Chem., 32 (1971) 213; H. Bürger and K.Z. Wiegel, Z. Anorg. Allg. Chem., 398 (1973) 257; H. Bürger and C. Kluess, J. Organomet. Chem., 108 (1976) 69.
20. [9] E.P. Benzing and W.A. Kornicker, Chem. Ber., 94 (1961) 2263; H. Bürger and H.J. Neese, Z. Anorg. Allg. Chem., 370 (1969) 275; H. Bürger and H.J. Neese, J. Organomet. Chem., 20 (1969) 129; H.J. Neese and H. Bürger, J. Organomet. Chem., 32 (1971) 213; H. Bürger and K.Z. Wiegel, Z. Anorg. Allg. Chem., 398 (1973) 257; H. Bürger and C. Kluess, J. Organomet. Chem., 108 (1976) 69.
21. [9] E.P. Benzing and W.A. Kornicker, Chem. Ber., 94 (1961) 2263; H. Bürger and H.J. Neese, Z. Anorg. Allg. Chem., 370 (1969) 275; H. Bürger and H.J. Neese, J. Organomet. Chem., 20 (1969) 129; H.J. Neese and H. Bürger, J. Organomet. Chem., 32 (1971) 213; H. Bürger and K.Z. Wiegel, Z. Anorg. Allg. Chem., 398 (1973) 257; H. Bürger and C. Kluess, J. Organomet. Chem., 108 (1976) 69.
22. [10] L.J. Baye, Synth. React. Inorg. Metal-Org. Chem., 2 (1972) 47; W.J. Sartain, J.C. Huffman, E.G. Lundquist, W.G. Streib and K.G. Caulton, J. Mol. Cat., 56 (1989) 20; F.R. Lemke, D.J. Szalda and R.M. Bullock, J. Am. Chem. Soc., 113 (1991) 8466.
23. [10] L.J. Baye, Synth. React. Inorg. Metal-Org. Chem., 2 (1972) 47; W.J. Sartain, J.C. Huffman, E.G. Lundquist, W.G. Streib and K.G. Caulton, J. Mol. Cat., 56 (1989) 20; F.R. Lemke, D.J. Szalda and R.M. Bullock, J. Am. Chem. Soc., 113 (1991) 8466.
24. [10] L.J. Baye, Synth. React. Inorg. Metal-Org. Chem., 2 (1972) 47; W.J. Sartain, J.C. Huffman, E.G. Lundquist, W.G. Streib and K.G. Caulton, J. Mol. Cat., 56 (1989) 20; F.R. Lemke, D.J. Szalda and R.M. Bullock, J. Am. Chem. Soc., 113 (1991) 8466.
25. [11] C.K. Johnson, ORTEP, Report ORNL-5138, Oak Ridge National Laboratory, Oak Ridge, TN, 1976.
26. [12] V.M. Visciglio, P.E. Fanwick and I.P. Rothwell, Inorg. Chim. Acta, 211 (1993) 203.
27. [13] M. Galakhov, A. Martin, M. Mena, F. Palacios, C. Yélamos and P.R. Raithby, Organometallics, 14 (1995) 131.
28. [14] W.J. Sartain and J.P. Selegue, Organometallics, 8 (1989) 2153 and references cited therein.
29. [15] P.E. Collier, S.C. Dunn, P. Mountford, O.V. Shishkin and D. Swallow, J. Chem. Soc., Dalton Trans., (1995) 3743.
30. [16] D.C. Bradley and I.M. Thomas, J. Chem. Soc., (1960) 3857.
31. [17] G. Chandra and M.F. Lappert, J. Chem. Soc. A, (1968) 1950.
32. [18] MolEN, An Interactive Structure Solution Procedure, Enraf-Nonius, Delft, Netherlands, 1990.
33. [19] International Tables for X-ray Crystallography, Vol. 4, Kynoch Press, Birmingham, UK (present distributor Academic Publishers, Dordrecht, Netherlands), 1974.