Lithium arsanylalanates as arsenide sources: A simple route to the zintl anion As73- and the synthesis of a tetraarsatetrasilacubane

Angewandte Chemie (International Edition in English)

Volumn 35, Issue 21, 1996, Pages 2507-2510

  Driess, Matthias ^a   Merz, Klaus ^a   Pritzkow, Hans ^a   Janoschek, Rudolf ^b  

^a UNIVERSITY OF HEIDELBERG   (Germany)

^b UNIVERSITY OF GRAZ   (Austria)

Author keywords

Aluminum compounds; Arsenic compounds; Heterocubanes; Lithium compounds; Silanes; Zintl anions

Indexed keywords

EID: 0030477271     PISSN: 05700833     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.199625071     Document Type: Article

References (30)

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11. Solutions of 1 a in diglyme have already been used in the synthesis of primary monosilyl- and monogermylarsanes. However, neither the preparation and characterization nor the characteristic thermal lability of la were described: J. W. Anderson, J. E. Drake, J. Chem. Soc. A 1970, 3131, and references therein.
12. max = 48°), all non-hydrogen atoms refined anisotropieally, R1 = 0.065 (4203 observed reflections), wR2 = 0.236 (all reflections) [15]. The cell also contains other atoms (6-8 in the asymmetric unit) that probably belong to disordered solvent molecules (hexane), but which cannot be unequivocally assigned. Crystallographic data (excluding structure factors) for the structures reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-179-96. Copies of the data can be obtained free of charge on application to The Director, CCDC, 12 Union Road, Cambridge CB2 1EZ, UK (fax: Int. code +(1223) 336-033; e-mail: teched@chemcrys. cam.ac.uk).
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