Complexation of fullerenes with bis-calix[n]arenes synthesized by tandem Claisen rearrangement

Journal of the American Chemical Society

Volumn 120, Issue 47, 1998, Pages 12226-12231

  Wang, Jianshe ^a   Gutsche, C David ^a  

^a TEXAS CHRISTIAN UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALKYLATION; CHEMICAL BONDS; COMPLEXATION; ETHERS; MOLECULAR STRUCTURE; OLEFINS; SYNTHESIS (CHEMICAL);

ALKYLATING AGENTS; BISCALIXARENES; ETHERIFICATION; PHASE TRANSFER AGENTS; TANDEM CLAISEN REARRANGEMENT;

FULLERENES;

CALIXARENE; FULLERENE DERIVATIVE;

ARTICLE; CHEMICAL STRUCTURE; COMPLEX FORMATION; MOLECULAR DYNAMICS; SYNTHESIS;

EID: 0032477314     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja981530m     Document Type: Article

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53. 13C NMR spectra were recorded on a Varian XL-300 spectrometer at 300 and 75 MHz, respectively. Analytical samples were dried in a drying pistol under vauum for at least 36 h. Microanalyses were performed by Desert laboratories, Tucson, AZ. Thin-layer chromatography (TLC) was carried out on Analtech silica gel plates (absorbant thickness 250 mm) containing a fluorescent indicator. Column chromatography was carried out with J. T. Baker silica gel no. JT7042-2 (40-64 mm particles) on columns filled to a height of ca. 6 in. Elution rates were 2 in. min. Mass spectral determinations were carried out by the Mass Spectrometry Resource Center of Washington University, St. Louis, MO, partially supported by NIH Grant RR00954.