C-S bond cleavage of allyl thioethers by zerovalent Ru complexes

Chemistry Letters

Volumn , Issue 2, 1998, Pages 123-124

  Planas, Jose Giner ^a   Hirano, Masafumi ^a   Komiya, Sanshiro ^a  

^a TOKYO UNIVERSITY OF AGRICULTURE AND TECHNOLOGY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0032398080     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.1998.123     Document Type: Article

References (25)

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18. 6) for 2 and 3 shows an ABMX pattern: δ 46.28 (ddd, J = 243, 30, 16 Hz, 1 ap-P), 50.35 (ddd, J = 30, 16, 10 Hz, 1 eq-P), 54.72 (ddd, J = 243, 30, 23 Hz, 1 ap-P), 55.02 (ddd, J = 30, 23, 10 Hz, 1 eq-P), and 46.53 (ddd, J = 243, 30, 16Hz, 1 ap-P), 50.35 (ddd, J = 30, 16, 11 Hz, 1 eq-P), 54.72 (ddd, J = 243, 30, 23 Hz, 1ap-P), 55.02 (ddd, J = 30, 23, 11 Hz, 1 eq-P), respectively.
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21. -1.
22. w) = 0.048(0.065) for 4543 reflections.
23. 6: δ 48.48 (t, J = 23 Hz), 60.98 (t, J = 23 Hz). J. Chatt and G. Hayter, J. Chem. Soc., 1961, 896.
24. 10(5) has been reported by the reaction of Ru(cod)(cot) with dmpe and depe, respectively.
25. B. Chaudret, G. Commenges, and R. Poilblanc, J. Chem. Soc., Dalton Trans., 1984, 1635.