Unexpected ligand displacement of Ru(cod)(cot) with trimethylphosphine to give fac-Ru(6-η1:1-3-η3-C8H 10)(PMe3)3

Chemistry Letters

Volumn , Issue 4, 1997, Pages 297-298

  Hirano, Masafumi ^a   Marumo, Tsuyoshi ^a   Miyasaka, Takashi ^a   Fukuoka, Atsushi ^a   Komiya, Sanshiro ^a  

^a TOKYO UNIVERSITY OF AGRICULTURE AND TECHNOLOGY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0012319086     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.1997.297     Document Type: Article

References (29)

1. a) E. O. Fischer and J. Müller, Chem. Ber., 96, 3217 (1963).
2. b) P. Pertici, G. Vitulli, and L. Porri, J. Chem. Soc., Chem. Commun., 1975, 846.
3. c) J. Müller, C. G. Kreiter, B. Mertschenk, and S. Schmitt, Chem. Ber., 108, 273 (1975).
4. d) P. Pertici, G. Simonelli, G. Vitulli, G. Deganello, P. Sandrini, and A. Mantovani, J. Chem. Soc., Chem. Commun., 1977, 132.
5. e) P. Pertici, G. Vitulli, M. Paci, and L. Porri, J. Chem. Soc., Dalton Trans., 1980, 1961.
6. f) K. Itoh, H. Nagashima, T. Ohshima, N. Oshima, and H. Nishiyama, J. Organomet. Chem., 272, 179 (1984).
7. g) K. -M. Frosin and L. Dahlenburg, Inorg. Chim. Acta, 167, 83 (1990).
8. h) P. Pertici and G. Vitulli, Comments Inorg. Chem., 11, 175 (1991) and references cited therein.
9. For examples; a) T. Mitsudo, Y. Nakagawa, K. Watanabe, Y. Hori, H. Misawa, H. Watanabe, and Y. Watanabe, J. Org. Chem., 50, 565 (1985).
10. b) T. Mitsudo, Y. Hori, and Y. Watanabe, J. Organomet. Chem., 334, 157 (1987).
11. c) Y. Wakatsuki, H. Yamazaki, N. Kumegawa, T. Satoh, and J. Y. Satoh, J. Am. Chem. Sec., 113, 9604 (1991).
12. a) P. Pertici, G. Vitulli, R. Lazzaroni, and P. Salvadori, J. Chem. Soc., Dalton Trans., 1982, 1019.
13. b) G. Vitulli, P. Pertici, and P. Salvadori, J. Chem. Soc., Dalton Tarans., 1984, 2255.
14. c) G. Vitulli, P. Pertici, and C. Bigelli, Gazzetta Chim. Ital., 115, 79 (1985).
15. d) P. Pertici, G. Vitulli, S. Bertozzi, and R. Lazzaroni, Inorg. Chim. Acta, 149, 235 (1988).
16. G. Deganello, A. Mantovani, P. L. Sandrini, P. Pertici, and G. Vitulli, J. Organomet. Chem., 135, 215 (1977).
17. a) B. Chaudret, G. Commenges, and R. Poilblanc., J. Chem. Soc., Chem. Commun., 1982, 1388.
18. b) B. Chaudret, G. Commenges, and R. Poilblanc., J. Chem. Soc., Dalton Trans., 1984, 1635.
19. c) P. Pertici, G. Vitulli, W. Porzio, M. Zocchi, P. L. Barili, and G. Deganello, J. Chem. Soc., Dalton Trans., 1983, 1553.
20. 3Ru: C, 46.89; H, 8.56%.
21. w) = 0.038 (0.034) for 3905 unique reflections.
22. A. F. Hill, in Comprehensive Organometallic Chemistry II, ed by D. F. Shriver and M. I. Bruce; Pergamon: Oxford (1995); vol.7, p299.
23. 4: F. Bouachir, B. Chaudret, and I. Tkatchenko, J. Chem. Soc., Chem. Commun., 1986, 94.
24. G. M. Diamond, M. L. H. Green, N. M. Walker, J. A. K. Howard, and S. A. Mason, J. Chem. Soc., Dalton Trans., 1992, 2641.
25. 2-, which tightly bound to the ruthenium center: M. A. Bennett, T. W. Matheson, G. B. Robertson, A. K. Smith, and P. A. Tucker, Inorg. Chem., 19, 1014 (1980).
26. 2-dpe): δ -11.54 (d, J = 19 Hz, 1P), 35.33 (dt, J = 19, 12 Hz, 1P), 69.34 (d, J = 12 Hz, 2P). Formation of the dppm analogue has been reported [Ref. 5].
27. a) S. Komiya, J. Suzuki, K. Miki, and N. Kasai, Chem. Lett., 1987, 1287.
28. b) S. Komiya, T. Kabasawa, K. Yamashita, M Hirano, and A. Fukuoka, J. Organomet. Chem., 471, C6 (1994).
29. 3 is also reported: Y. Maruyama, I. Shimizu, and A. Yamamoto, Chem. Lett., 1994, 1041.