Unusual formation of cyclometallated C,H-trans-hydridoruthenium(II) complexes and their isomerization into C,H-cis-types

Chemistry Letters

Volumn , Issue 1, 1998, Pages 47-48

  Hiraki, Katsuma ^a   Koizumi, Makoto ^a   Kira, Shu Ichi ^a   Kawano, Hiroyuki ^a  

^a NAGASAKI UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0032363772     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.1998.47     Document Type: Article

References (12)

1. a) S. Murai, F. Kakiuchi, S. Sekine, Y. Tanaka, A. Kamatani, M. Sonoda, and N. Chatani, Nature, 366, 529 (1993).
2. b) F. Kakiuchi, ,S. Sekine, Y. Tanaka, A. Kamatani, M. Sonoda, N. Chatani, and S. Murai, Bull. Chem. Soc. Jpn., 68, 62 (1995).
3. K. Hiraki, S. Kira, and H. Kawano, Bull. Chem. Soc. Jpn., 70, 1583 (1997).
4. a) Yield: 2a 44%, 2b 48% 3a 55%, 3b 45%.
5. -1 (C=N).
6. 1H} δ 53.0 (s).
7. w = 0.054.
8. w = 0.041.
9. Z. Dauter, R. J. Mawby, C. D. Reynolds, and D. R. Saunders, J. Chem. Soc., Dalton Trans., 1985, 1235.
10. D. J. Cole-Hamilton and G. Wilkinson, Nouv. J. Chim., 1, 141 (1977).
11. F. Kakiuchi, M. Yamauchi, N. Chatani, and S. Murai, Chem. Lett., 1996, 111.
12. Y.-G. Lim, Y. H. Kim, and J.-B. Kang, J. Chem. Soc., Chem. Commun., 1994, 2267.