Pyrolysis of cyclopentadiene: Rates for initial C-H bond fission and the decomposition of c-C5H5

Symposium (International) on Combustion

Volumn 27, Issue 1, 1998, Pages 143-150

  Kern, R D ^a   Zhang, Q ^a   Yao, J ^a   Jursic, B S ^a   Tranter, R S ^b   Greybill, M A ^b   Kiefer, J H ^b  

^a UNIVERSITY OF NEW ORLEANS   (United States)

^b 1120 Science and Engineering Offices   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL BONDS; DENSITY MEASUREMENT (SPECIFIC GRAVITY); MASS SPECTROMETRY; MOLECULAR DYNAMICS; OLEFINS; PYROLYSIS; RATE CONSTANTS; SHOCK WAVES;

CYCLOPENTADIENE; LASER-SCHLIEREN (LS) DENSITOMETRY; TIME-OF-FLIGHT MASS SPECTROMETRY (TOFMS);

COMBUSTION;

EID: 0032286621     PISSN: 00820784     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0082-0784(98)80399-8     Document Type: Conference Paper

References (22)

1. Brezinsky, K., Prog. Energy Combust. Sci. 3:1-24 (1986).
2. Emdee, J. L., Brezinsky, K., and Glassman, I., J. Phys. Chem. 96:2151-2161 (1992).
3. Colket, M. B., "The Pyrolysis of Cyclopentadiene," Eastern States Section Meeting of the Combustion Institute, Orlando, FL, 1990.
4. Burcat, A. and Dvinyaninov, M., Int. J. Chem. Kinet. 29:505-514 (1997).
5. Roy, K., Frank, P., and Just, T., Isr. J. Chem. 36:275-278 (1996).
6. Roy, K. and Frank, P., "High Temperature Pyrolysis and Oxidation of Cyclopentadiene," Twenty-First International Symposium on Shock Waves, Great Keppel Island, Australia, 1997.
7. Puttemans, J. P., Smith, J. P., and Golden, D. M., J. Phys. Chem. 94:3226-3227 (1990).
8. Burcat, A. and McBride, B., "1977 Ideal Gas Thermodynamic Data for Combustion and Air-Pollution Use," Technion Aerospace Engineering Report TAE 804, June 1997.
9. Karni, M., Oref, I., and Burat, A., J. Phys. Chem. Ref. Data 20:665-683 (1991).
10. DeFrees, D. J., McIveer, R. T., and Hehre, W. J., J. Am. Chem. Soc. 102:3334-3338 (1980).
11. Melius, C. F., Colvin, M. E., Marinov, N. M., Pitz, W. J., and Senkan, S. M., in Twenty-Sixth Symposium (International) on Combustion, The Combustion Institute, Pittsburgh, 1997, pp. 685-692.
12. Bishof, P., J. Am. Chem. Soc. 99:8145-8149 (1977).
13. Wang, H. and Brezinsky, K., J. Phys. Chem. A 102:1530-1541 (1998).
14. Kiefer, J. H., Zhang, Q., Kern, R. D., Yao, J., and Jursic, B. S., J. Phys. Chem. A 101:7061-7073 (1997).
15. Kiefer, J. H., Mudipalli, P. S., Sidhu, S. S., Kern, R. D., Jursic, B. S., and Chen, H., J. Phys. Chem. A 101:4057-4071 (1997).
16. CRC Handbook of Chemistry and Physics, 49th ed., Chemical Rubber Company, Cleveland, 1969.
17. Castaldi, M. J., Marinov, N. M., Melius, C. F., Huang, J., Senkan, S. M., Pitz, W. J., and Westbrook, C. K., in Twenty-Sixth Symposium (International) on Combustion, The Combustion Institute, Pittsburgh, 1997, pp. 693-702.
18. Wagner, A. F., Kiefer, J. H., Ikeda, E., and Tranter, R. S., unpublished work.
19. Kee, R. J., Rupley, F. M., and Miller, J. A., The CHEMKIN Thermodynamic Base, Sandia report SAND87-8215B.UC4.
20. JANAF Thermochemical Tables; National Standard Reference Data Service, National Bureau of Standards, Washington, D.C., 1985, No. 14.
21. Tsang, W. and Walker, J. A., J. Phys. Chem. 96:8378-8384 (1992).
22. Westley, F., Frizzell, D. H., Herron, J. T., Hampson, R. F., and Mallard, W. J., NIST Chemical Kinetics Database, NIST Standard Reference Data, Gaithersburg, MD, 1993.