Detailed kinetics of cyclopentadiene decomposition studied in a shock tube

International Journal of Chemical Kinetics

Volumn 29, Issue 7, 1997, Pages 505-514

  Burcat, Alexander ^a   Dvinyaninov, Michael ^a  

^a TECHNION ISRAEL INSTITUTE OF TECHNOLOGY   (Israel)

Author keywords

[No Author keywords available]

Indexed keywords

ACETYLENE; ARGON; BENZENE; DECOMPOSITION; ETHYLENE; FREE RADICALS; GAS CHROMATOGRAPHY; METHANE; SHOCK TUBES;

CYCLOPENTADIENE; RING OPENING REACTIONS;

REACTION KINETICS;

EID: 0031188127     PISSN: 05388066     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1097-4601(1997)29:7<505::AID-KIN4>3.0.CO;2-Y     Document Type: Article

References (24)

1. M. B. Colket, The Pyrolysis of Cyclopentadiene, Eastern States Section of Combustion Institute annual meeting, Orlando, 1990, Paper 1.
2. R. G. Butler, A Flow Reactor Study of the Oxidation of 1,3-Cyclo-Pentadiene, MSc. Thesis, Princeton University, 1992.
3. O. S. L. Bruisma, P. J. J. Tromp, H. J. J. de Sauvage Nolting, and J. A. Moulijn, Fuel, 67, 334 (1988).
4. E. Gey, B. Ondrushka, and G. Zimmermann, J. Prakt. Chem, 329(3), 511 (1987).
5. A. Burcat and B. McBride, 1995 Thermodynamic Database for Combustion and Air Pollution Use, Technion Aerospace Engineering (TAB) Report # 732, January 1995.
6. J. Kee, F. M. Rupley, and J. A. Miller, Chemkin-II A Fortran Chemical Kinetic Package for Analysis of Gas Phase Chemical Kinetics. Sandia Report SAND 89-8009B. U.C-706, 1992.
7. R. V. Serkauskas, M. Frenklach, H. Wang, C. T. Bowman, G. P. Smith, D. M. Golden, W. C. Gardiner, and V. Lissianski, An Optimized Detailed Chemical Mechanism for Methane Combustion, Gas Research Institute Topical Report 1994.
8. C. K. Westbrook, W. J. Pitz, M. M. Thornton, and P. C. Malte, Comb. Flame, 72, 45 (1988); W. J. Pitz, C. K. Westbrook, W. M. Proscia, and F. L. Dryer, A Comprehensive Chemical Kinetic Reaction Mechanism for the Oxidation of N Butane, 20-th Comb. Symp., 1984, pp. 831-843.
9. C. K. Westbrook, W. J. Pitz, M. M. Thornton, and P. C. Malte, Comb. Flame, 72, 45 (1988); W. J. Pitz, C. K. Westbrook, W. M. Proscia, and F. L. Dryer, A Comprehensive Chemical Kinetic Reaction Mechanism for the Oxidation of N Butane, 20-th Comb. Symp., 1984, pp. 831-843.
10. J. L. Emdee, K. Brezinsky, and I. Glassman, J. Phys. Chem., 96, 2151, (1992), F. N. Egolffopoulos, D. X. Du, and C. K. Law, Comb. Sci. Tech., 83, 33 (1992).
11. J. L. Emdee, K. Brezinsky, and I. Glassman, J. Phys. Chem., 96, 2151, (1992), F. N. Egolffopoulos, D. X. Du, and C. K. Law, Comb. Sci. Tech., 83, 33 (1992).
12. J. A. Miller and C. F. Melius, Combust. Flame, 91, 21 (1992).
13. M. Frenklach, D. W. Clary, T. Yuan, W. C. Gardiner, and S. E. Stein, Combust. Sci. Technol., 50, 79 (1986).
14. A.M. Dean, J. Phys. Chem., 94, 1432 (1990).
15. R. D. Kern, K. Xie, H. Chen, and J. H. Kiefer, High Temperature Pyrolysis of Acetylene and Diacetylene behind Reflected Shock Waves, 23 Combust Symp., (1990), pp. 69-75.
16. C. H. Wu, and R. D. Kern, J. Phys. Chem., 91, 6291 (1987).
17. W. Tsang and R. F. Hampson, J. Phys. Chem. Ref. Data, 15, 1087 (1986).
18. J. Warnatz, Chemistry of High Temperature Combustion of Alkanes up to Octane, 20-th Comb. Symp., 1984, pp. 845-855.
19. M. Karni, I. Oref, and A. Burcat, J. Phys. Chem. Ref. Dora, 20, 665 (1991).
20. M. Frenklach, Reduction of Chemical Reaction Models in Numerical Approaches to Combustion Modeling, Chap. 5, E. S. Oran and J. P. Boris, Eds., Progress in Astronautics & Aeronautics, 1991, Vol. 135, pp. 129-154.
21. A. Burcat, M. Dvinyaninov, E. Olchanski, and Ch. Sokolinski, Detailed Combustion Kinetics of Cyclopentadiene. Combust. Flame, submitted.
22. C. F. Melius, BAC/MP4 ab-initio calculation database, Sandia Co.
23. S. E. Stein, NIST Structures and Properties, Computerized Database #25, Gaithersburg, Maryland, 1994.
24. A. Lifshitz, M. Frenklach, and A. Burcat, J. Phys. Chem., 79, 1148 (1975).