Thermal ring contraction of 1,2-digermacyclohexadienes coordinated with iron tricarbonyl fragment

Chemistry Letters

Volumn , Issue 10, 1998, Pages 991-992

  Mochida, Kunio ^a   Hatanaka, Wakako ^a   Wada, Tohru ^a   Sekine, Akiko ^b   Ohashi, Yuji ^b   Yamamoto, Akio ^c  

^a GAKUSHUIN UNIVERSITY   (Japan)

^b TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

^c WASEDA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0032278193     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.1998.991     Document Type: Article

References (31)

1. R. West, in "Comprehensive Organometallic Chemistry," ed by G. F. Wilkinson, F. G. A. Stone, and E. W. Abel, Pergamon Press, New York (1982), Vol. 2, p376.
2. I. Ojima, in "The Chemistry of Organic Silicon Compounds," ed by S. Patai and S. Rappoport, Wiley, New York (1989).
3. T. D. Tilley, in "The Silicon-Heteroatom Bond," ed by S. Patai and Z. Rappoport, John Wiley & Sons, Chichester (1991), Chap. 9.
4. S. Murai and N. Chatani, J. Synth. Org. Chem. Jpn., 51, 421 (1993).
5. Y. Tanaka, H. Yamashita, and M. Tanaka, Organometallics, 14, 530 (1995) and references cited therein.
6. M. Suginome, H. Oike, S. Park, and Y. Ito, Bull. Chem. Soc. Jpn., 69, 289 (1996) and references cited therein.
7. F. Ozawa and T. Hikida, Organometallics; 15, 4501 (1996) and references cited therein.
8. A. M. LaPointe, F. C. Rix, and M. Brookhart, J. Am. Chem. Soc., 119, 906 (1997) and references cited therein.
9. T. Tsumuraya and W. Ando, Organometallics, 8, 2286 (1989).
10. T. Hayashi, H. Yamashita, T. Sakakura, Y. Uchimaru, and M. Tanaka, Chem. Lett., 1991, 245.
11. K. Mochida, C. Hodota, H. Yamashita, and M. Tanaka, Chem. Lett., 1992, 1635.
12. T. N. Michel, A. Amamria, H. Killing, and D. Rutschow, J. Organomet. Chem., 241, C45 (1983).
13. E. Piers and R. T. Skerlji, J. Chem. Soc., Chem. Commun., 1986, 626.
14. Y. Tsuji and Y. Obora, J. Am. Chem. Soc., 113, 9368 (1991); Y. Tsuji and T. Kakehi, J. Chem. Soc., Chem. Commun., 1992, 1000; Y. Ohora, Y. Tsuji, T. Kakehi, M. Kobayashi, Y. Shinkai, M. Ebihara, and T. Kawamura, J. Chem. Soc., Perkin Trans. 1, 1995, 599; Y. Obora, Y. Tsuji, K. Nishiyama, M. Ebihara, and T. Kawamura, J. Am. Chem. Soc., 118, 10922 (1996) and references cited therein.
15. Y. Tsuji and Y. Obora, J. Am. Chem. Soc., 113, 9368 (1991); Y. Tsuji and T. Kakehi, J. Chem. Soc., Chem. Commun., 1992, 1000; Y. Ohora, Y. Tsuji, T. Kakehi, M. Kobayashi, Y. Shinkai, M. Ebihara, and T. Kawamura, J. Chem. Soc., Perkin Trans. 1, 1995, 599; Y. Obora, Y. Tsuji, K. Nishiyama, M. Ebihara, and T. Kawamura, J. Am. Chem. Soc., 118, 10922 (1996) and references cited therein.
16. Y. Tsuji and Y. Obora, J. Am. Chem. Soc., 113, 9368 (1991); Y. Tsuji and T. Kakehi, J. Chem. Soc., Chem. Commun., 1992, 1000; Y. Ohora, Y. Tsuji, T. Kakehi, M. Kobayashi, Y. Shinkai, M. Ebihara, and T. Kawamura, J. Chem. Soc., Perkin Trans. 1, 1995, 599; Y. Obora, Y. Tsuji, K. Nishiyama, M. Ebihara, and T. Kawamura, J. Am. Chem. Soc., 118, 10922 (1996) and references cited therein.
17. Y. Tsuji and Y. Obora, J. Am. Chem. Soc., 113, 9368 (1991); Y. Tsuji and T. Kakehi, J. Chem. Soc., Chem. Commun., 1992, 1000; Y. Ohora, Y. Tsuji, T. Kakehi, M. Kobayashi, Y. Shinkai, M. Ebihara, and T. Kawamura, J. Chem. Soc., Perkin Trans. 1, 1995, 599; Y. Obora, Y. Tsuji, K. Nishiyama, M. Ebihara, and T. Kawamura, J. Am. Chem. Soc., 118, 10922 (1996) and references cited therein.
18. T. Wada, MS dissertation, Gakushuin University (1997).
19. H. Sakurai, Y. Nakadaira, and H. Tobita, Chem. Lett., 1982, 1855.
20. 2: C, 61.90: H, 6.93%. Found: C, 62.15; H, 7.15%.
21. H. Tobita, Dr. dissertation, Tohoku University, 1982.
22. 6) 0.57-1.52 (m 20H), 5.61 (s, 2H), 6.93-7.35 (m, 10H).
23. K. Mochida, M. Akazawa, M. Goto, A. Sekine, Y. Ohashi, and Y. Nakadaira, Organometallics, 17, 1782 (1998).
24. 6) 1.76, 5.84, 69.0, 85.8, 126.4, 127.5, 129.1, 141.8, 212.2.
25. T. J. Barton, A. J. Nelson, and J. Clardy, J. Org. Chem., 37, 895 (1972).
26. 5 at 130°C for 9 h, 1a (12%), 3a (16%), and4a (10%) were formed.
27. K. Mochida, I. Yoneda, and M. Wakasa, J. Organomet. Chem., 399, 53 (1990).
28. Y. Nakadaira, T. Kobayashi, and H. Sakurai, J. Organomet. Chem., 165, 399 (1979).
29. Pannell and Sharma, and Ogino and co-workers have reported that UV photolysis of digermanyliron complexes afford highly unstable germyl(germylene)iron complexes which undergo extrusion of germylenes to give germyliron complexes.
30. K. H. Pannell and S. Sharma, Organometallics, 10, 1655 (1991).
31. J. R. Koe, H. Tobita, T. Suzuki, and H. Ogino, Organometallics, 11, 150 (1992).