Structure and fluxional behavior of cis-bis(stannyl)bis(phosphine)platinum: Oxidative addition of organodistannane to platinum(0) complex

Journal of the American Chemical Society

Volumn 118, Issue 44, 1996, Pages 10922-10923

  Obora, Yasushi ^a   Tsuji, Yasushi ^a   Nishiyama, Kayo ^a   Ebihara, Masahiro ^a   Kawamura, Takashi ^a  

^a GIFU UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

PLATINUM COMPLEX;

ARTICLE; COMPLEX FORMATION; DRUG STRUCTURE; NUCLEAR MAGNETIC RESONANCE; REACTION ANALYSIS;

EID: 0029798419     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja9626392     Document Type: Article

References (12)

1. (a) Obora, Y.; Tsuji, Y.; Kakehi, T.; Kobayashi, M.; Shinkai, Y.; Ebihara, M.; Kawamura, T. J. Chem. Soc., Perkin Trans. 1 1995, 599.
2. (b) Tsuji, Y.; Kakehi, T. J. Chem. Soc., Chem. Commun. 1992, 1000.
3. (c) Piers, E.; Skerlj, R. T. J. Org. Chem. 1987, 52, 4421.
4. (d) Mitchell, T. N.; Schneider, U. J. Organomet. Chem. 1991, 407, 319.
5. (a) Akhtar, M.; Clark, H. C. J. Organomet. Chem. 1970, 22, 233.
6. (b) Weichmann, H. J. Organomet. Chem. 1982, 238, C49.
7. w = 0.027, GOF = 1.730.
8. 119Sn, viz., 0.956. (a) Brevard, C.; Granger, P. Handbook of High Resolution Multinuclear NMR; John Wiley & Sons: New York, 1981; p 168.
9. P-Sn(cisoid) should be opposite.
10. Clark et al. proposed that 3b has the trans-structure. However, 3b should have the same structure as 3a, the cis-structure, since the both complexes show essentially the same NMR spectral data.
11. 7a (a) La Mar, G. N.; Sherman, E. O. J. Chem. Soc., Chem. Commun. 1969, 809, and references cited therein.
12. Gausian 94 package. For details, see Supporting Information.