Molecular characterization of microgram amounts of oceanic colloidal organic matter by direct temperature-resolved ammonia chemical ionization mass spectrometry

Organic Geochemistry

Volumn 29, Issue 5-7 -7 pt 2, 1998, Pages 1051-1061

  Boon, Jaap J ^a   Klap, Vincent A ^a   Eglinton, Timothy I ^b  

^a FOM INSTITUTE AMOLF   (Netherlands)

^b WOODS HOLE OCEANOGRAPHIC INSTITUTION   (United States)

Author keywords

Chemical ionization; Colloidal organic matter; Direct temperature resolved mass spectrometry (DT MS); Dissolved organic carbon (DOC); Polysaccharides; Ultrafiltration

Indexed keywords

DIRECT TEMPERATURE TIME-RESOLVED MASS SPECTROMETRY (DT-MS);

AMMONIA; BACTERIA; BIOMARKERS; COLLOIDS; IONIZATION; MASS SPECTROMETRY; NITROGEN COMPOUNDS; POLYSACCHARIDES; SUGARS; THERMODYNAMIC STABILITY; ULTRAFILTRATION;

ANALYTICAL GEOCHEMISTRY;

COASTAL WATERS; MASS SPECTROMETRY; ORGANIC MATTER;

ATLANTIC OCEAN;

EID: 0032215149     PISSN: 01466380     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0146-6380(98)00121-1     Document Type: Conference Paper

References (32)

1. Aluwihare L. I., Repeta D. J., Chen R. F. A major biopolymeric component to dissolved organic carbon in surface seawater. Nature. 387:1997;166-169.
2. Aries R. E., Gutteridge C. S., Laurie W. A., Boon J. J., Eijkel G. B. A pyrolysis mass spectrometry investigation of pectin methylation. Analytical Chemistry. 60:1988;1498-1502.
3. Arisz P. W. F., Boon J. J. Pyrolysis chemical ionization mass spectrometry of cellulose ethers. Journal of Polymer Science. 33:1995;2855-2864.
4. Benner R., Pakulski J. D., McCarthy M., Hedges J. I., Hatcher P. G. Bulk chemical characteristics of dissolved organic matter in the ocean. Science. 255:1992;1561-1564.
5. Boon J. J. Analytical pyrolysis mass spectrometry: new vistas opened by temperature-resolved in-source Py-MS. International Journal of Mass Spectrometry and Ion Processes. 118-119:1992;755-787.
6. Boon J. J., De Boer W. R., Kruyssen F. J., Wouters J. T. M. Pyrolysis mass spectrometry of whole cells, cell walls and isolated cell wall polymers of Bacillus subtilis var Iniger WM. Journal of General Microbiology. 122:1981;119-127.
7. Boon, J. J., Nip, M., Brandt-de Boer, B. and Van Amsterdam, M. (1988) Characterisation of citrus and apple pectins by pyrolysis mass spectrometry in Py-EI-MS, DCIMS and PYGCMS modes. In 11th International Mass Spectrometry Conference, ed. P. Longevialle, Vol. 11: Advances in Mass Spectrometry. Heyden and Son, Bordeaux, pp. 1100-1101.
8. Chapman, J. R. (Ed.) (1996) Protein and Peptide Analysis by Mass Spectrometry. Humana Press, Totowa, 350 pp.
9. Chen R. F., Fry B., Hopkinson C. S., Repeta D. J., Peltzer E. T. Dissolved organic carbon on Georges Bank. Continental Shelf Research. 16:1996;409-420.
10. Chin W.-C., Orellana M. V., Verdugo P. Spontaneous assembly of marine dissolved organic matter into polymer gels. Nature. 391:1998;568-572.
11. Eglinton T. I., Boon J. J., Minor E. C., Olson R. J. Microscale characterization of algal and related particulate organic matter by direct temperature-resolved mass spectrometry. Marine Chemistry. 52:1996;27-54.
12. Guo L., Santschi P. H. Composition and cycling of colloids in marine environments. Reviews of Geophysics. 35:1997;17-40.
13. Guo L., Santschi P. H. Isoptopic and elemental characterization of colloidal organic matter from Chesapeake Bay and Galveston Bay. Marine Chemistry. 59:1997;1-15.
14. Hedges J. I., Cowie G. L., Richey J. E., Quay P. D., Benner R., Strom M., Forsberg B. Origins and processing of organic matter in the Amazon river as indicated by carbohydrates and amino acids. Limnology and Oceanography. 39:1994;743-761.
15. Heeren R. M. A., Boon J. J. Rapid microscale analyses with an external ion source Fourier transform ion cyclotron resonance mass spectrometer. International Journal of Mass Spectrometry and Ion Processes. 157-158:1996;391-403.
16. Johnstone, R. A. W. and Rose, M. E. (1996) Mass Spectrometry for Chemists and Biochemists. Cambridge University Press, Cambridge, pp. 256-259.
17. Kenne, L. and Lindberg, B. (1982) Bacterial polysaccharides. In The Polysaccharides, ed. G. O. Aspinall, Vol. 2: Molecular Biology. Academic Press, New York, pp. 287-364.
18. Klap, V. A. (1997) Biogeochemical Aspects of Salt Marsh Exchange Processes in the SW Netherlands 171. University of Amsterdam.
19. Klap V. A., Boon J. J., Hemminga M. A., Van Soelen J. Assessment of the molecular composition of particulate organic matter exchanged between the Saeftinghe salt marsh (southwestern Netherlands) and adjacent water system. Marine Chemistry. 54:1996;221-243.
20. Lomax J. A., Boon J. J., Hoffman R. A. Characterisation of polysaccharides by in-source pyrolysis positive- and negative-ion direct chemical ionisation-mass spectrometry. Carbohydrate Research. 221:1991;219-233.
21. Lomax J. A., Commandeur J. M., Arisz P. W. F., Boon J. J. Characterisation of oligomers and sugar ring-cleavage products in the pyrolysate of cellulose. Journal of Analytical and Applied Pyrolysis. 19:1991;65-79.
22. Lomax J. A., Commandeur J. M., Boon J. J. Pyrolysis mass spectrometry of polysaccharides. Biological Mass Spectrometry. 19:1991;65-79.
23. McCarthy M., Hedges J., Benner R. Major biochemical composition of dissolved high molecular weight organic matter in seawater. Marine Chemistry. 55:1996;281-297.
24. McCarthy M., Pratum T., Hedges J. Chemical composition of dissolved organic nitrogen in the ocean. Nature. 390:1997;150-154.
25. McCarthy M. D., Hedges J. I., Benner R. The chemical composition of dissolved organic matter in seawater. Chemical Geology. 107:1993;503-507.
26. Minor, E. C., Eglinton, T. I., Olson, R. J. and Boon, J. J. (submitted) Spatial and temporal variations in the composition of particulate organic matter from the surface ocean: an investigation using flow-cytometry and DT-MS. In Advances in Organic Geochemistry 1997, eds. B. Horsfeld, M. Radke, R. G. Schaefer and H. Wilkes.
27. Moers, M. E. C. (1989) Occurrence and Fate of Carbohydrates in Recent and Ancient Sediments from Different Environments of Deposition 195. Technical University, Delft.
28. Scheijen M. A., Boon J. J. Loss of oligomer information in pyrolysis-desorption/chemical-ionization mass spectrometry of amylose, due to the influence of potassium hydroxide. Rapid Communications in Mass Spectrometry. 3:1989;238-240.
29. Sharp J. Marine dissolved organic carbon: Are the older values correct? Marine Chemistry. 56:1997;265-277.
30. Skoog A., Benner R. Aldoses in various size fractions of marine organic matter: Implications for carbon cycling. Limnology and Oceanography. 42:1997;1803-1813.
31. Van der Kaaden A., Boon J. J., De Leeuw J. W., De Lange F., Schuyl P. J. W., Schulten H.-R., Bahr U. Comparison of analytical pyrolysis techniques in the characterization of chitin. Analytical Chemistry. 56:1984;2160-2164.
32. Williams P. M., Druffel E. R. M. Radiocarbon in dissolved organic matter in the central North Pacific Ocean. Nature. 330:1987;246-248.