Synthesis of acrylate and methacrylate block copolymers using atom transfer radical polymerization

Macromolecules

Volumn 31, Issue 23, 1998, Pages 8005-8008

  Shipp, Devon A ^a   Wang, Jen Lung ^a   Matyjaszewski, Krzysztof ^a  

^a CARNEGIE MELLON UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACRYLIC MONOMERS; FREE RADICAL POLYMERIZATION; INITIATORS (CHEMICAL); MACROMOLECULES; MOLECULAR STRUCTURE; POLYACRYLATES; POLYMETHYL METHACRYLATES; SYNTHESIS (CHEMICAL);

ATOM TRANSFER RADICAL POLYMERIZATION; MACROINITIATORS;

BLOCK COPOLYMERS;

EID: 0032204429     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma981033q     Document Type: Article

References (20)

1. Moad, G.; Solomon, D. H. The Chemistry of Free-Radical Polymerization; Pergamon: Oxford, U.K., 1995.
2. Matyjaszewski, K., Ed. Controlled Radical Polymerization; ACS Symposium Series Vol. 685; American Chemical Society: Washington, DC, 1998.
3. Kato, M.; Kamigaito, M.; Sawamoto, M.; Higashimura, T. Macromolecules 1995, 28, 1721.
4. Kotani, Y.; Kato, M.; Kamigaito, M.; Sawamoto, M. Macromolecules 1996, 29, 6979.
5. Matyjaszewski, K.; Patten, T. E.; Xia, J. J. Am. Chem. Soc. 1997, 119, 674.
6. Wang, J. S.; Matyjaszewski, K. Macromolecules 1995, 28, 7901.
7. Patten, T. E.; Xia, J.; Abernathy, T.; Matyjaszewski, K. Science 1996, 272, 866.
8. Matyjaszewski, K.; Jo, S. M.; Paik, H.-J.; Gaynor, S. G. Macromolecules 1997, 30, 6398.
9. Coca, S.; Jasieczek, C. B.; Beers, K. L.; Matyjaszewski, K. J. Polym. Sci., Part A: Polym. Chem. 1998, 36, 1417.
10. Percec, V.; Kim, H.-J.; Barboiu, B. Macromolecules 1997, 30, 6702.
11. Percec, V.; Barboiu, B.; Kim, H.-J. J. Am. Chem. Soc. 1998, 120, 305.
12. Matyjaszewski, K.; Wang, J.-L.; Grimaud, T.; Shipp, D. A. Macromolecules 1998, 31, 1527.
13. Percec, V.; Kim, H.-J.; Barboiu, B. Macromolecules 1997, 30, 8526.
14. Matyjaszewski, K.; Shipp, D. A.; Wang, J.-L.; Grimaud, T.; Patten, T. E. Macromolecules 1998, 31, 6836.
15. Matyjaszewski, K. J. Phys. Org. Chem. 1995, 8, 197.
16. Matyjaszewski, K.; Grimaud, T. Macromolecules 1997, 30, 2216.
17. Wang, J.-L.; Grimaud, T.; Matyjaszewski, K. Macromolecules 1997, 30, 6507.
18. The different solvents used in expts 8 and 11 may slightly affect the kinetics of the polymerizations (e.g., EC in acrylate ATRP see: Matyjaszewski, K.; Nakagawa, Y.; Jasieczek, C. B. Macromolecules 1998, 31, 1535), but should not affect the functionality of the block copolymers.
19. Coca, S.; Davis, K.; Miller, P.; Matyjaszewski, K. Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 1997, 38, 689.
20. Keller, R. N.; Wycoff, H. D. Inorg. Synth. 1946, 2, 1.