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See the article by H. Terrones, A. L. Mackay, Carbon 1992, 30, 1251 for a useful and readable introduction Io the topic of "curvature". To appreciate the difference between "Gaussian" and "mean" curvatures, note that "mean curvature" is related to the arithmetic "mean" of the curvatures of the primary arcs while "Gaussian curvature" is related to the geometric mean of the curvatures of the primary arcs.
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Strictly speaking, ideal perfect polyhedra have infinitely sharp corners for which "curvature" seems an inappropriate concept. But matter is quantized into atomic centers, and by visualizing atomic centers as parts of arcs, rather than as vertices of angles, the validity of "curvature" is restored.
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note
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In "organic" clusters/nanoparticles such as fullerenes, it is more useful to view the curvature as being exhibited by groups of atoms, especially five-or seven-membered rings, as in [12].
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By manipulating their curvature, atomic centers that in one case bond together as an infinite level surface can in other cases be encouraged to close into polyhedra. See D. L. Thorn, R. L. Harlow, N. Herron, Inorg. Chem. 1995, 34, 2629.
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2 fragments" (tetrahedral or planar) can, like carboxylates, provide the mean curvature for forming small rings. See, for example, P. J. Stang, D. H. Cao, J. Am. Chem. Soc. 1994, 116, 4981. P. J. Stang, B. Olenyuk, A. M. Arif, Organometallics 1996, 15, 904 Coupled with cleverly devised organic components, nanosized objects can result: P. J. Stang, B. Olenyuk, D. C. Muddiman, R. D. Smith, Organometallics 1997, 16, 3094.
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