High-yield synthesis of alkoxyamine initiators carrying a functional group by reaction of ethylbenzenes with di-tert-butyl diperoxalate in the presence of nitroxides

Macromolecules

Volumn 31, Issue 14, 1998, Pages 4659-4661

  Miura, Yozo ^a   Hirota, Kenichi ^a   Moto, Hiroaki ^a   Yamada, Bunichiro ^a  

^a Osaka Prefecture University   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

AROMATIC HYDROCARBONS; COLUMN CHROMATOGRAPHY; FREE RADICAL POLYMERIZATION; INFRARED SPECTROSCOPY; INITIATORS (CHEMICAL); MOLECULAR STRUCTURE; MONOMERS; NITROGEN OXIDES; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; POLYMERS; STYRENE;

ALKOXYAMINE; ETHYLBENZENE; POLYMER CHAIN;

SYNTHESIS (CHEMICAL);

EID: 0032120930     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma9803685     Document Type: Article

References (27)

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16. 3, 1 H), 7.21-7.33 (m, aromatic, 5 H).
17. 3, 1 H), 7.22-7.35 (m, aromatic, 5 H).
18. 3, 1 H), 7.21-7.33 (m, aromatic, 5H).
19. Boiling points are 204 (4-bromoethylbenzene), 213 (4-(ethoxycarbonyl)ethylbenzene), and 195 °C (4-methoxyethylbenzene).
20. 26BrNO: C, 60.00; H, 7.70; N, 4.12. Found: C, 59.93; H, 7.68; N, 3.82.
21. 3: C, 71.82; H, 9.34; N, 4.19. Found: C, 72.03; H, 9.22; N, 3.87.
22. 2: C, 74.18; H, 10.03; N, 4.81. Found: C, 74.32; H, 9.77; N, 4.52.
23. Kobatake, S.; Harwood: H. J.; Quirk, R. P.; Priddy, D. B. Macromolecules 1997, 30, 4238.
24. 2: C, 74.70; H, 9.40; N, 4.84. Found: C, 74.59; H, 9.37; N, 4.60.
25. 3, 1 H), 7.32 (s, aromatic, 4 H).
26. 3, 2 H), 7.29 (d, J = 8.3 Hz, aromatic, 2 H), 8.00 (d, J = 8.3 Hz, aromatic, 2 H).
27. Ingold, K. U. In Free Radicals; Kochi, J. K, Ed.; Wiley-Interscience: New York, 1972; Vol. 1, p 78.