Kinetic study of gas phase olefin polymerization with a TiCl4/MgCl2 catalyst I. Effect of polymerization conditions

Journal of Polymer Science, Part A: Polymer Chemistry

Volumn 35, Issue 10, 1997, Pages 2063-2074

  Han Adebekun, C C ^a,b   Hamba, M ^a,c   Ray, W H ^a  

^a University of Wisconsin ^*  (United States)

^b EASTMAN KODAK COMPANY   (United States)

^c SUMITOMO CHEMICAL CO LTD   (Japan)

Author keywords

Ethylene propylene copolymerization; Gas phase; High temperature; Kinetic study; Supported titanium catalyst

Indexed keywords

CATALYSTS; CHEMICAL REACTORS; CHEMICAL VARIABLES CONTROL; COMPOSITION; COMPOSITION EFFECTS; ETHYLENE; MELTING; MONOMERS; ONLINE SYSTEMS; POLYMERIZATION; PROPYLENE; THERMAL EFFECTS;

DIFFUSION LIMITATION; ETHYLENE PROPYLENE COPOLYMERIZATION; GAS PHASE OLEFIN POLYMERIZATION; GAS PHASE REACTOR; HYDROGEN CONCENTRATION; INSTANTANEOUS REACTION RATE; ON LINE COMPOSITION CONTROL SCHEME; SUPPORTED TITANIUM CATALYST;

REACTION KINETICS;

EID: 0031189181     PISSN: 0887624X     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1099-0518(19970730)35:10<2063::AID-POLA22>3.0.CO;2-D     Document Type: Article

References (37)

1. G. C. Han-Adebekun, J. A. Debling, and W. H. Ray, J. Appl. Polym. Sci., submitted.
2. R. A. Hutchinson and W. H. Ray, J. Appl. Polym. Sci., 41, 51-81 (1990).
3. G. C. Han-Adebekun, Ph.D. thesis, Department of Chemical Engineering, University of Wisconsin, Madison, WI, 1996.
4. C. Cozewith, Macromolecules, 20, 1237-1244 (1987).
5. M. Hamba, G. C. Han-Adebekun, and W. H. Ray, J. Polym. Sci. Part A: Polym. Chem., 35, XXX (1997).
6. K. Soga, H. Yanagihara, and D. Lee, Makromol. Chem., 190, 995-1006 (1989).
7. D. C. Calabro and F. Y. Lo, "A Comparison of the Reaction Kinetics for the Homo- and Copolymerization of Ethylene and Hexene with a Heterogeneous Ziegler Catalysts," in Transition Metal Catalyzed Polymerization: Ziegler-Natta and Metathesis Polymerization, R. P. Quirk, Ed., Cambridge University Press, New York, 1988, pp. 729-739.
8. F. J. Karol, S.-C. Kao, and K. J. Cann, J. Polym. Sci. Part A: Polym. Chem., 31, 2541-2553 (1993).
9. P. J. T. Tait, G. W. Downs, and A. A. Akinbami, "Copolymerization of Ethylene and α-Olefins: A kinetic Considerations," in Transition Metal Catalyzed Polymerization: Ziegler-Natta and Metathesis Polymerization, R. P. Quirk, Ed., Cambridge University Press, New York, 1988, p. 834.
10. R. Spitz, L. Duranel, P. Masson, and M. F. Darricades-Llauro, "Difference in Reactivity between Ethylene and Propene with Supported Ziegler-Natta Catalysts," in Transition Metal Catalyzed Polymerization: Ziegler-Natta and Metathesis Polymerization, R. P. Quirk, Ed., Cambridge University Press, New York, 1988, pp. 719-728.
11. C. M. Chen and W. H. Ray, J. Appl. Polym. Sci., 49, 1573-1588 (1993).
12. 0 Seminário Brasileiro de Catálise, 1991, pp. 540-556.
13. Y. V. Kissin, J. Mol. Catal., 56, 220-236 (1989).
14. S. Floyd, K. Y. Choi, T. W. Taylor, and W. H. Ray, J. Appl. Polym. Sci., 32, 2231 (1986).
15. A. S. Michaels and H. J. Bixler, J. Polym. Sci., 50, 413-439 (1961).
16. R. A. Hutchinson, C. M. Chen, and W. H. Ray, J. Appl. Polym. Sci., 44, 1389-1414 (1992).
17. R. J. L. Graff, G. Kortleve, and C. G. Vonk, Polym. Lett., 8, 735-739 (1970).
18. L. Noristi, E. Marchetti, G. Baruzzi, and P. Sgarzi, J. Polym. Sci. Part A: Polym. Chem., 32, 3047-3059 (1994).
19. D. B. Ludlum, A. W. Anderson, and C. E. Ashby, J. Am. Chem. Soc., 80, 1380-1384 (1958).
20. A. Malatesta, Can. J. Chem., 37, 1176-1186 (1959).
21. M. L. Cooper and J. B. Rose, J. Chem. Soc., 795 (1959).
22. R. J. Kern and H. G. Hurst, J. Polym. Sci., 44, 272 (1960).
23. Y. Doi, M. Murata, K. Yano, and T. Keii, Ind. Eng. Chem. Prod. Res. Dev., 21, 580-585 (1982).
24. C. Dumas and C. C. Hsu, J. Appl. Polym. Sci., 37, 1605-1623 (1989).
25. C. Dumas and C. C. Hsu, J. Appl. Polym. Sci., 37, 1625-1644 (1989).
26. J. Boor, Jr., Ziegler-Natta Catalysts and Polymerization. Academic, New York, 1979.
27. K. Soga, S. Chen, and R. Ohnishi, Polym. Bull., 8, 473-478 (1982).
28. N. Kashiwa and J. Yoshitake, Makromol. Chem., 185, 1133-1138 (1984).
29. T. Keii, E. Suzuki, M. Tamura, M. Murata, and Y. Doi, Makromol. Chem., 183, 2285-2304 (1982).
30. P. Galli, P. C. Barbé, and L. Noristi, Die Angew. Macromol. Chem., 120, 73-90 (1984).
31. J. J. A. Dusseault and C. C. Hsu, J. Appl. Polym. Sci., 50, 431-447 (1993).
32. U. Zucchini, G. A. Saggese, I. Cuffiani, and G. Foschini, "Progress in Tailor-Made Ziegler-Natta Catalysts for Ethylene Polymerization," in Transition Metal Catalyzed Polymerization: Ziegler-Natta and Metathesis Polymerization, R. P. Quirk, Ed., Cambridge University Press, New York, 1988, p. 450.
33. M. Kioka and N. Kashiwa, J. Macromol. Sci. Chem., A28, 865 (1991).
34. V. Busico, R. Cipullo, and Corradini, Makromol. Chem. Rapid Commun., 13, 15 (1992).
35. V. Busico, R. Cipullo, and Corradini, Makromol. Chem. Rapid Commun., 13, 21 (1992).
36. J. C. W. Chien and T. Nozaki, J. Polym. Sci. Part A: Polym. Chem., 29, 505-514 (1991).
37. T. Keii, in Studies in Surface Science & Catalysis, Vol. 25, Catalytic Polymerization of Olefins, T. Keii and K. Soga, Ed., Elsevier, New York, 1986, p. 1.