Plasma-polymerized polyaniline films: Synthesis and characterization

Journal of Polymer Science, Part A: Polymer Chemistry

Volumn 36, Issue 4, 1998, Pages 633-643

  Gong, Xiaoyi ^a,b   Dai, Liming ^a   Mau, Albert W H ^a   Griesser, Hans J ^a  

^a CSIRO   (Australia)

^b GUANGDONG UNIVERSITY OF TECHNOLOGY   (China)

Author keywords

Free radicals; Plasma polymerization; Polyaniline; Surface characterization

Indexed keywords

AROMATIC POLYMERS; ELECTRON SPIN RESONANCE SPECTROSCOPY; FLUORINE CONTAINING POLYMERS; FOURIER TRANSFORM INFRARED SPECTROSCOPY; MOLECULAR STRUCTURE; NITROGEN COMPOUNDS; PLASMA APPLICATIONS; POLYMERIZATION; SCANNING ELECTRON MICROSCOPY; SURFACE PHENOMENA; ULTRAVIOLET SPECTROSCOPY; X RAY PHOTOELECTRON SPECTROSCOPY;

HYDROPHILICITY; PLASMA POLYMERIZATION; POLYANILINE;

PLASTIC FILMS;

EID: 0032021398     PISSN: 0887624X     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1099-0518(199803)36:4<633::AID-POLA12>3.0.CO;2-N     Document Type: Article

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61. pp ≈ 1 G under vacuum (see, for example: H. H. S. Javadi, R. Laversanne, and A. J. Epstein, Synth. Met., 29, E439 (1989); M. Nechtschein and F. Genoud, Solid State Commun., 91, 471 (1994); M. Iida, T. Asaji, M. B. Inoue, and M. Inoue, Synth. Met., 55, 607 (1993)). However, the peak-to-peak line width could be up to about 10 G in air due to the oxygen-induced line broadening (see, for example: M. Nechtschein and F. Genoud, Solid State Commun., 91, 471 (1994); M. Iida, T. Asaji, M. B. Inoue, and M. Inoue, Synth. Met., 55, 607 (1993); E. Houze and M. Nechtschein, Phys. Rev. B, 53, 14309 (1996)). Since it is almost impossible to prevent even brief exposure of the plasma samples to oxygen, we carried out the ESR measurements on both the plasma-polymerized and chemically-synthesized polyaniline samples under ambient atmosphere.
62. pp ≈ 1 G under vacuum (see, for example: H. H. S. Javadi, R. Laversanne, and A. J. Epstein, Synth. Met., 29, E439 (1989); M. Nechtschein and F. Genoud, Solid State Commun., 91, 471 (1994); M. Iida, T. Asaji, M. B. Inoue, and M. Inoue, Synth. Met., 55, 607 (1993)). However, the peak-to-peak line width could be up to about 10 G in air due to the oxygen-induced line broadening (see, for example: M. Nechtschein and F. Genoud, Solid State Commun., 91, 471 (1994); M. Iida, T. Asaji, M. B. Inoue, and M. Inoue, Synth. Met., 55, 607 (1993); E. Houze and M. Nechtschein, Phys. Rev. B, 53, 14309 (1996)). Since it is almost impossible to prevent even brief exposure of the plasma samples to oxygen, we carried out the ESR measurements on both the plasma-polymerized and chemically-synthesized polyaniline samples under ambient atmosphere.
63. pp ≈ 1 G under vacuum (see, for example: H. H. S. Javadi, R. Laversanne, and A. J. Epstein, Synth. Met., 29, E439 (1989); M. Nechtschein and F. Genoud, Solid State Commun., 91, 471 (1994); M. Iida, T. Asaji, M. B. Inoue, and M. Inoue, Synth. Met., 55, 607 (1993)). However, the peak-to-peak line width could be up to about 10 G in air due to the oxygen-induced line broadening (see, for example: M. Nechtschein and F. Genoud, Solid State Commun., 91, 471 (1994); M. Iida, T. Asaji, M. B. Inoue, and M. Inoue, Synth. Met., 55, 607 (1993); E. Houze and M. Nechtschein, Phys. Rev. B, 53, 14309 (1996)). Since it is almost impossible to prevent even brief exposure of the plasma samples to oxygen, we carried out the ESR measurements on both the plasma-polymerized and chemically-synthesized polyaniline samples under ambient atmosphere.
64. pp ≈ 1 G under vacuum (see, for example: H. H. S. Javadi, R. Laversanne, and A. J. Epstein, Synth. Met., 29, E439 (1989); M. Nechtschein and F. Genoud, Solid State Commun., 91, 471 (1994); M. Iida, T. Asaji, M. B. Inoue, and M. Inoue, Synth. Met., 55, 607 (1993)). However, the peak-to-peak line width could be up to about 10 G in air due to the oxygen-induced line broadening (see, for example: M. Nechtschein and F. Genoud, Solid State Commun., 91, 471 (1994); M. Iida, T. Asaji, M. B. Inoue, and M. Inoue, Synth. Met., 55, 607 (1993); E. Houze and M. Nechtschein, Phys. Rev. B, 53, 14309 (1996)). Since it is almost impossible to prevent even brief exposure of the plasma samples to oxygen, we carried out the ESR measurements on both the plasma-polymerized and chemically-synthesized polyaniline samples under ambient atmosphere.
65. pp ≈ 1 G under vacuum (see, for example: H. H. S. Javadi, R. Laversanne, and A. J. Epstein, Synth. Met., 29, E439 (1989); M. Nechtschein and F. Genoud, Solid State Commun., 91, 471 (1994); M. Iida, T. Asaji, M. B. Inoue, and M. Inoue, Synth. Met., 55, 607 (1993)). However, the peak-to-peak line width could be up to about 10 G in air due to the oxygen-induced line broadening (see, for example: M. Nechtschein and F. Genoud, Solid State Commun., 91, 471 (1994); M. Iida, T. Asaji, M. B. Inoue, and M. Inoue, Synth. Met., 55, 607 (1993); E. Houze and M. Nechtschein, Phys. Rev. B, 53, 14309 (1996)). Since it is almost impossible to prevent even brief exposure of the plasma samples to oxygen, we carried out the ESR measurements on both the plasma-polymerized and chemically-synthesized polyaniline samples under ambient atmosphere.
66. pp ≈ 1 G under vacuum (see, for example: H. H. S. Javadi, R. Laversanne, and A. J. Epstein, Synth. Met., 29, E439 (1989); M. Nechtschein and F. Genoud, Solid State Commun., 91, 471 (1994); M. Iida, T. Asaji, M. B. Inoue, and M. Inoue, Synth. Met., 55, 607 (1993)). However, the peak-to-peak line width could be up to about 10 G in air due to the oxygen-induced line broadening (see, for example: M. Nechtschein and F. Genoud, Solid State Commun., 91, 471 (1994); M. Iida, T. Asaji, M. B. Inoue, and M. Inoue, Synth. Met., 55, 607 (1993); E. Houze and M. Nechtschein, Phys. Rev. B, 53, 14309 (1996)). Since it is almost impossible to prevent even brief exposure of the plasma samples to oxygen, we carried out the ESR measurements on both the plasma-polymerized and chemically-synthesized polyaniline samples under ambient atmosphere.