Heterodimetallic complexes from a bis(alkynyl)metallocene and vanadocene - Unexpected structure of [Cp2V(μ-η2:η4-butadiyne)Zr(C5H4SiMe3)2] containing two planar-tetracoordinate carbon atoms

Chemistry - A European Journal

Volumn 4, Issue 6, 1998, Pages 1100-1105

  Danjoy, Christine ^a   Zhao, Jianshe ^a,c   Donnadieu, Bruno ^a   Legros, Jean Pierre ^a   Valade, Lydie ^a   Choukroun, Robert ^a   Zwick, Antoine ^b   Cassoux, Patrick ^a  

^a LCC LABORATOIRE DE CHIMIE DE COORDINATION   (France)

^b France   (France)

^c NORTHWEST UNIVERSITY   (China)

Author keywords

Heterodimetallic complexes; Structure elucidation; Titanium; Vanadium; Zirconium

Indexed keywords

EID: 0031745677     PISSN: 09476539     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3765(19980615)4:6<1100::AID-CHEM1100>3.0.CO;2-6     Document Type: Article

References (79)

1. a) R. A. Fischer, M. Kleine, O. Lehmann, M. Stuke, Chem. Mater. 1995, 7, 1863-1872;
2. b) R. A. Fischer, W. Scherer, M. Kleine, Angew. Chem. 1993, 105, 778-780; Angew. Chem. Int. Ed. Engl. 1993, 32, 748-750;
3. b) R. A. Fischer, W. Scherer, M. Kleine, Angew. Chem. 1993, 105, 778-780; Angew. Chem. Int. Ed. Engl. 1993, 32, 748-750;
4. c) R. A. Fischer in Mater. Res. Soc. Symp. Proc. (Eds.: C R. Abernathy, J. C. W. Bates, D. A. Bohling, W. S. Hobson), Materials Research Society, Pittsburg, 1993, pp. 267-273.
5. C. Danjoy, PhD thesis, Institut National Polytechnique de Toulouse, France, 1996, No 1197.
6. a) D. A. Roberts, G. L. Geoffroy, in Comprehensive Organometallic Chemistry, Vol. 6 (Eds.: G. Wilkinson, F. G. A. Stone, E. W. Abel), Pergamon, Oxford, 1982, chapter 40;
7. b) D. W. Stephan, Coord. Chem. Rev. 1989, 95, 41 - 107;
8. c) R. T. Baker, W. C. Fultz, T. B. Morder, I. D. Williams, Organometallics 1990, 9, 2357-2367 and references therein;
9. d) R. M. Bullock, C. P. Casey, Acc. Chem. Res. 1987, 20, 167-173;
10. e) G. K. Anderson, M. Lin, Organometallics 1988, 7, 2285-2288;
11. f) G. S. Ferguson, P. T. Wolczanski, ibid. 1985, 4, 1601 -1605.
12. a) L. Gelmini, D.W. Stephan, Organometallics 1988, 7, 849-855;
13. b) T. T. Nadashi, D.W. Stephan, ibid. 1992, 77, 116-122 and references therein;
14. c) R. Choukroun, A. Iraqi, D. Gervais, J. C Daran, Y. Jeannin, ibid. 1987, 6, 1197-1201;
15. d) R. Choukroun, A. Iraqi, C. Rifai, D. Gervais, J. Organomet. Chem. 1988, 353, 45-52;
16. e) R. Choukroun, F. Dahan, D. Gervais, C. Rifai, Organometallics 1990, 9, 1982-1987 and references therein;
17. f) A. M. Larsonneur, R. Choukroun, J. C. Daran, C. Cuenca, J. C. Flores, P. Royo, J. Organo-met. Chem. 1993, 444, 83-89;
18. g) A. M. Trzeciak, J. J. Ziolkowski, R. Choukroun. J. Mol. Catal. 1996, 110, 135 -139 and references therein.
19. C. Friebel, K. D. Schergise, W. Willing, U. Mueller, K. Dehnicke, Z. Anorg. Allg. Chem. 1987, 546, 21-32.
20. M. Mazzanti, C. Floriani, A. Chiesi-Villa, C. Guastini, Inorg. Chem. 1986, 25, 4158-4164.
21. C. Elschenbroich, E. Schmidt, B. Metz, K. Harms, Organometallics 1995. 14, 4043-4045.
22. F. Laurent, PhD thesis, Université Paul Sabatier de Toulouse, France, 1996, No 1211.
23. J. H. Teuben, H. J. De Liefde Meijer, J. Organometal. Chem. 1969, 17, 87-93.
24. a) G. Erker, W. Frömberg, R. Mynott, B. Gabor, C. Krüger, Angew. Chem. 1986, 98, 456-457; Angew. Chem. Int. Ed. Engl. 1986, 25, 463-465;
25. a) G. Erker, W. Frömberg, R. Mynott, B. Gabor, C. Krüger, Angew. Chem. 1986, 98, 456-457; Angew. Chem. Int. Ed. Engl. 1986, 25, 463-465;
26. b) G. Erker, W. Frömberg, R. Benn, R. Mynott, K. Angermund, C. Krüger, Organometallics 1989, 8, 911-920.
27. a) A.D. Jenkins, M. F. Lappert, R. C. Srivastava, J. Organometal. Chem. 1970, 23, 165-172;
28. b) R. Jimenez, M. C. Barral, V. Moreno, A. Santos, ibid. 1979, 182, 353-359.
29. a) H. Lang, D. Seyfert, Z. Naturforsch. B 1990, 45, 212-220;
30. b) H. Lang, W. Frosch, I. Y. Wu, S. Blau, B. Nuber, Inorg. Chem. 1996, 35, 6266-6272;
31. c) H. Lang, K. Köhler, L. Zsolnai, J. Chem. Soc. Chem. Commun. 1996, 2043-2044;
32. d) M. Janssen, M. Herres, L. Zsolnai, D. M. Grove, A. L. Spek, H. Lang, G. van Koten, Organometallics 1995, 14. 1098-1100.
33. a) B. P. Warner, W. M. Davis, S. L. Buchwald, J. Am. Chem. Soc. 1994, 116, 5471-5472;
34. b) U. Rosenthal, A. Ohff, W. Baumann, R. Kempe, A. Tillack, V. V. Burlakov. Organometallics 1994, 13, 2903-2906;
35. c) C. Lebefer, W. Baumann, A. Tiliack, R. Kempe, H. Gorls, U. Rosenthal, ibid. 1996, 75, 3486-3490;
36. d) V. Varga, J. Hiller, M. Polasek, U Thewalt, K. Mach, J. Organomet. Chem. 1996, 515, 57 -64;
37. e) A. Ohff, S. Pulst, C. Lebefer, N. Peulecke, P. Arndt, V. V. Burlakov, U Rosenthal, Synlett. 1996, 2, 111-118;
38. f) U Rosenthal. A. Ohff, W. Baumann, R. Kempe, A. Tillack, V. V. Burlakov. Angew. Chem. 1994, 106, 1678- 1680; Angew. Chem. Int. Ed. Engl. 1994.33, 1605-1607:
39. f) U Rosenthal. A. Ohff, W. Baumann, R. Kempe, A. Tillack, V. V. Burlakov. Angew. Chem. 1994, 106, 1678- 1680; Angew. Chem. Int. Ed. Engl. 1994.33, 1605-1607:
40. g) S. Pulst, P. Arndt, B. Heller, W. Baumann, R. Kempe, U. Rosenthal, ibid. 1996, 108, 1175-1178 and 1996, 35, 1112-1114.
41. g) S. Pulst, P. Arndt, B. Heller, W. Baumann, R. Kempe, U. Rosenthal, ibid. 1996, 108, 1175-1178 and 1996, 35, 1112-1114.
42. a) H. Lang, M. Herres, L. Zsolnai, Organometallics 1993, 12, 5008-5011;
43. b) M. D. Janssen, M. Herres, L. Zsolnai, A. L. Spek, D.M. Grove, H. Lang, G. van Koten, Inorg. Chem. 1996, 35, 2476-2483;
44. c) M. D. Janssen, K. Köhler, M. Herres. A. Dedieu, W. J. J. Smeets, A. L. Spek, D. M. Grove, H. Lang, G. van Koten, J. Am. Chem. Soc. 1996, 118. 4817-4829.
45. a) D. Sekutowski, G. D. Stucky, J. Am. Chem. Soc. 1976, 98, 1376- 1382;
46. b) D. F. Fousts, M. D. Rausch, W. E. Hunter, J. L. Atwood. E. Samuel, J. Organomet. Chem. 1980. 797, 217-224;
47. c) G. Fachinetti, C. Floriani, A. Chiesi-Villa, C. Guastini, Inorg. Chem. 1979, 18, 2282-2287;
48. d) J. L. Petersen, L. Griffith, ibid. 1980, 19, 1852-1858.
49. Supporting information is available on the WWW under http:// www.wiley-vch.de/home/chemistry/ or from the author.
50. a) M. D. Janssen, M. Herres, L. Zsolnai, D. M. Grove, A. L. Spek, H. Lang, G. van Koten, Organometallics 1995, 14, 1098-1100;
51. b) K. Yasufuku, H. Yamazaki, Short Communication, 1972, 45, 2664-2664.
52. R. Choukroun, B. Donnadieu, I. Malfant, S. Haubrich, R. Frantz, C. Guerin, B. Henner, J. Chem. Soc. Chem. Commun. 1997, 2315-2316.
53. T. Takahaski, Y. Nishihara, W.-H. Sun, R. Fischer, K. Nakajima, Organometallics 1997, 76, 2216-2219.
54. a) G. Erker, J. Wicher, K. Engel, F. Rosenfeld, W. Dietrich, C. Krüger, J. Am. Chem. Soc. 1980, 102, 6344-6346;
55. b) Y. Kai, N. Kanehisa, K. Miki, N. Kasai, K. Mashima, K. Nagasuna, H. Yasuda. A. Nakamura J. Chem. Soc. Chem. Commun. 1982, 191-192.
56. U. Rosenthal, A. Ohff, M. Michalik, H. Görls, V. V. Burlakov, V. B. Shur, Angew. Chem. 1993, 105, 1228-1230; Angew. Chem. Int. Ed. Engl. 1993, 32, 1193-1195.
57. U. Rosenthal, A. Ohff, M. Michalik, H. Görls, V. V. Burlakov, V. B. Shur, Angew. Chem. 1993, 105, 1228-1230; Angew. Chem. Int. Ed. Engl. 1993, 32, 1193-1195.
58. G. Erker, K. Kropp, J. L. Atwood, W. E. Hunter, Organometallics 1983, 2, 1555-1561.
59. a) D. Röttger, G. Erker, R. Fröhlich, M. Grehl, S. J. Silverio, I. HylaKryspin, R. Gleiter, J. Am. Chem. Soc. 1995, 117, 10503- 10512;
60. b) G. Erker, Comments Inorg. Chem. 1992, 13, 111-131;
61. c) M. Alhrecht, G. Erker, C. Krüger, Synlett. 1993. 441-448.
62. a) M. Bochmann, in Comprehensive Organometallic Chemistry II, Vol. 4 (Eds.: E. W. Abel, E G. Stone, G. Wilkinson), Pergamon Press, Fort Collins, 1995, pp. 274-431;
63. b) P. Binger, S. Podubrin, ibid., pp. 439-463;
64. c) R. D. Broene, ibid., Vol. 12, pp. 323-347;
65. d) S. L. Buchwald, R. D. Broene, ibid., pp. 771-784;
66. e) S. L. Buchwald, B. T. Watson, J. C Huffman, J. Am. Chem. Soc. 1986, 108, 7411-7413;
67. f) S. L. Buchwald, B. T. Watson, J. C Huffman, ibid. 1987,109, 2544-2546;
68. g) K. Takagi, C. J. Rousset, E.-I. Negishi, ibid. 1991, 113, 1440-1044;
69. h) W. Ando, T. Ohtaki, T. Suzuki, T. Kabe, ibid. 1991, 113, 7782-7784;
70. i) T. Takahashi, M. Hasegawa, N. Suzuki, M. Saburi, C. J. Rousset, P. E. Fanwick, E. Negishi, ibid. 1991, 113, 8564-8566;
71. j) M. R. Kesti, R. M. Waymouth, Organometallics 1992, 11, 1095-1103;
72. k) N. Suzuki, D. Y. Kondakov, T. Takahashi, J. Am. Chem. Soc. 1993, 115, 8485-8486;
73. l) H. Ito, Y. Ikeuchi, T. Taguchi, Y. Hanzawa, M. Shiro, ibid. 1994, 116, 5469-5470;
74. h) T. Takahashi, Z. Xi, Y. Ohora, N. Susuki, ibid. 1995, 117, 2665-2666.
75. J. J. Eisch, R. B. King, Organometal. Synth. Trans. Met. Compounds. Academic Press, New York, 1965, pp. 64-66.
76. C. H. Winter, X. X. Zhou, D. A. Dobbs, M. J. Heeg, Organometallics 1991, 70, 210-214.
77. 1.
78. A. Altomare, G. Cascarano, C. Giacovazzo, A. Guagliardi, M. C. Burla, G. Polidori, M. Camalli, SIR92, User's Manual, 1992.
79. D. J. Watkin, J. R. Carruthers, P. W. Betteridge, CRYSTAES, User's Guide. University of Oxford, UK. 1988.