Monomeric Bis(η2-alkyne)copper (I) and -silver (I) Halides, Pseudohalides, and Arenethiolates

Inorganic Chemistry

Volumn 35, Issue 9, 1996, Pages 2476-2483

  Janssen, Maurits D ^a   Herres, Mathias ^b   Zsolnai, Laszló ^b   Spek, Anthony L ^c   Grove, David M ^a   Lang, Heinrich ^b   Van Koten, Gerard ^a  

^a UTRECHT UNIVERSITY   (Netherlands)

^b UNIVERSITY OF HEIDELBERG   (Germany)

^c UTRECHT UNIVERSITY   (Netherlands)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000765428     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic950710j     Document Type: Article

References (76)

1. Little structural information is available on these species: for all copper halides phase transitions between the low-temperature cubic zinc blende (γ) structure into the hexagonal wurzite (β) structure have been reported. Cubic (a) structures have also been reported at higher temperatures, (a) Lorenz, M. R.; Prener, J. S. Acta Crystallogr. 1956, 9, 538-539. (b) Bhalla, A. S.; White, E. W. Acta Crystallogr. 1971, B27, 852-853.
2. Little structural information is available on these species: for all copper halides phase transitions between the low-temperature cubic zinc blende (γ) structure into the hexagonal wurzite (β) structure have been reported. Cubic (a) structures have also been reported at higher temperatures, (a) Lorenz, M. R.; Prener, J. S. Acta Crystallogr. 1956, 9, 538-539. (b) Bhalla, A. S.; White, E. W. Acta Crystallogr. 1971, B27, 852-853.
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63. The alkyne ligands each donate two electrons. For examples of four-electron-donating alkynes in alkyne-copper complexes see: (a) Villacorta, G. M.; Gibson, D.; Williams, I. D.; Whang, E.; Lippard, S. J. Organometallics 1987, 6, 2426-2431. (b) Villacorta, G. M.; Gibson, D.; Williams, I. D.; Lippard, S. J. J. Am. Chem. Soc. 1985, 107, 6732-6734. (c) Aalten, H. L.; van Koten, G.; Riethorst, E.; Stam, C. H Inorg. Chem. 1989, 28, 4140-4146. (d) Reger, D. L.; Huff, M. F. Organometallics 1990, 9, 2807-2810.
64. The alkyne ligands each donate two electrons. For examples of four-electron-donating alkynes in alkyne-copper complexes see: (a) Villacorta, G. M.; Gibson, D.; Williams, I. D.; Whang, E.; Lippard, S. J. Organometallics 1987, 6, 2426-2431. (b) Villacorta, G. M.; Gibson, D.; Williams, I. D.; Lippard, S. J. J. Am. Chem. Soc. 1985, 107, 6732-6734. (c) Aalten, H. L.; van Koten, G.; Riethorst, E.; Stam, C. H Inorg. Chem. 1989, 28, 4140-4146. (d) Reger, D. L.; Huff, M. F. Organometallics 1990, 9, 2807-2810.
65. The alkyne ligands each donate two electrons. For examples of four-electron-donating alkynes in alkyne-copper complexes see: (a) Villacorta, G. M.; Gibson, D.; Williams, I. D.; Whang, E.; Lippard, S. J. Organometallics 1987, 6, 2426-2431. (b) Villacorta, G. M.; Gibson, D.; Williams, I. D.; Lippard, S. J. J. Am. Chem. Soc. 1985, 107, 6732-6734. (c) Aalten, H. L.; van Koten, G.; Riethorst, E.; Stam, C. H Inorg. Chem. 1989, 28, 4140-4146. (d) Reger, D. L.; Huff, M. F. Organometallics 1990, 9, 2807-2810.
66. The alkyne ligands each donate two electrons. For examples of four-electron-donating alkynes in alkyne-copper complexes see: (a) Villacorta, G. M.; Gibson, D.; Williams, I. D.; Whang, E.; Lippard, S. J. Organometallics 1987, 6, 2426-2431. (b) Villacorta, G. M.; Gibson, D.; Williams, I. D.; Lippard, S. J. J. Am. Chem. Soc. 1985, 107, 6732-6734. (c) Aalten, H. L.; van Koten, G.; Riethorst, E.; Stam, C. H Inorg. Chem. 1989, 28, 4140-4146. (d) Reger, D. L.; Huff, M. F. Organometallics 1990, 9, 2807-2810.
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70. 2] is also able to bind the metal-containing entities Co(CO) and Ni(CO): (a) Lang, H.; Imhof, W. Chem. Ber. 1992, 125, 1307-1311. (b) Lang, H.; Zsolnai, L. J. Organomet. Chem. 1991, 406, C5-C8.
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73. n species are isolated.
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76. c = coalescence temperature (K), and Δν = chemical shift difference (Hz): the other symbols have their usual meaning.