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85088809741
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note
-
44 and the C(1s):S(2p) and O(1s):C(1s) ratios calculated from the decomposition of thiophene and methanol, respectively, on Mo-(110).
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-
-
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23
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85088810289
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note
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2 evolution (36 amu) was observed when the Co-O overlayer was prepared with oxygen-18.
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-
-
-
24
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85088810112
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note
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3OD.
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-
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26
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11644294445
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note
-
Since molecular and recombinant CO are the only C-containing product formed from methanol reaction on the pure Co overlayer, the integrated CO signal from temperature-programmed reaction is used as a measurement of the total reactivity. Similarly, the yields for formaldehyde and CO were used as a measurement of the total reactivity of the oxidized 1.3 ML Co overlayer. The estimated total reactivity is a lower limit since the methyl radical yield was not included in this calculation. Methanol desorption is not considered to contribute to total reactivity. The relative mass spectrometer sensitivities for formaldehyde and CO were determined by leaking in a fixed pressure of authentic CO and formaldehyde samples, in separate experiments, and comparing the signal intensities.
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-
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27
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85088809982
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note
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2O is not shown because the 18 amu signal could not be reliably integrated, due to the water contribution associated with methanol sublimation.
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-
-
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28
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11644293604
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note
-
Some formaldehyde is produced even on the pure ∼1.0 ML oxygen overlayer on Mo(110). The formaldehyde yield is quite sensitive to the oxygen coverage and preparation conditions.
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-
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30
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0001688965
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0026172477
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0002670585
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0026985292
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0031187199
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45
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85088809719
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note
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2 signal are from scatter due to experimental error.
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