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3, we did not encounter a problem of delamination of the polymer structures when the PDMS mold was removed. There are possible sources of this adhesion: (1) although the adhesion of the polymer on the surface of PDMS may be favored thermodynamically, the local deformation of the PDMS surface during the removal of the PDMS may have caused the polymer to remain on the SAM; (2) the polymer structures adhered strongly to the surface at the defect sites in the SAM, and these microscopic attachments translated into the macroscopic adhesion of the polymer.
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