Site-specific chemical-bond scission in poly(methyl methacrylate) by inner shell excitation

Japanese Journal of Applied Physics, Part 1: Regular Papers and Short Notes and Review Papers

Volumn 36, Issue 12 SUPPL. B, 1997, Pages 7605-7610

  Ueno, Nobuo ^a,b   Tanaka, Kenichiro ^c  

^a INSTITUTE FOR MOLECULAR SCIENCE   (Japan)

^b CHIBA UNIVERSITY   (Japan)

^c HIROSHIMA UNIVERSITY   (Japan)

Author keywords

Energy dependent photochemical reaction; Inner shell excitation; NEXAFS; Photon stimulated ion desorption; Site specific reaction; Synchrotron radiation

Indexed keywords

CHEMICAL BONDS; DESORPTION; ELECTRON ENERGY LEVELS; MOLECULAR STRUCTURE; PHOTOCHEMICAL REACTIONS; PHOTONS; SYNCHROTRON RADIATION; THIN FILMS;

INNER SHELL EXCITATION; PHOTON STIMULATED ION DESORPTION;

POLYMETHYL METHACRYLATES;

EID: 0031368339     PISSN: 00214922     EISSN: None     Source Type: Journal    
DOI: 10.1143/jjap.36.7605     Document Type: Article

References (20)

1. N. Ueno, K. Kamiya, Y. Harada, M. C. K. Tinone, T. Sekitani and K. Tanaka: Optoelectronics 11 (1996) 91.
2. N. Ueno and K. Tanaka: J. Jpn. Soc. Synchrotron Rad. Res. (Houshakou) 9 (1996) 29 [in Japanese].
3. W. Eberhardt, T. K. Sham, R. Carr, S. Krummacher, M. Strongin, S. L. Weng and D. Wesner: Phys. Rev. Lett. 50 (1983) 1038.
4. D. Menzel and R. Gomer: J. Chem. Phys. 41 (1964) 3311.
5. P. Antononiewicz: Phys. Rev. B 21 (1980) 3811.
6. K. L. Knotek: Rep. Prog. Phys. 47 (1984) 1499, and references therein.
7. N. Ueno, M. Komada, Y. Morimoto, M. C. K. Tinone, M. Kushida, K. Sugita and K. Tanaka: Proc. 3rd Int. Conf. High Technology, Chiba, Japan, September 1992, p. 245.
8. N. Ueno, M. Komada, Y. Morimoto, M. C. K. Tinone, M. Kushida, K. Sugita, K. Honma and K. Tanaka: Jpn. J. Appl. Phys. 32 (1993) 229.
9. M. C. K. Tinone, T. Sekitani and K. Tanaka, J. Maruyama and N. Ueno: Appl. Surf. Sci. 79/80 (1994) 89.
10. M. C. K. Tinone, K. Tanaka, J. Maruyama, N. Ueno, M. Imamura and N. Matsubayashi: J. Chem. Phys. 100 (1994) 5988.
11. M. C. K. Tinone, N. Ueno, J. Maruyama, K. Kamiya, Y. Harada, T. Sekitani and K. Tanaka: J. Electron Spectr. Relat. Phenom. 80 (1996) 117.
12. Photoionization dominates the photoexcitation of core electrons to the continuum state, and electrons excited to the bound states decay effectively through Auger transitions. These phenomena give a good correspondence between the absorption and TEY spectra. See for example, J. Stöhr: NEX-AFS Spectroscopy (Springer, Berlin, 1992) Chap. 5 and references therein.
13. R. Haensel, G. Keitel, G. Peters, P. Schreiber, B. Sonntag and C. Kuntz: Phys. Rev. Lett. 23 (1969) 530.
14. K. Tanaka, M. C. K. Tinone, H. Ikeura, T. Sekiguchi and T. Sekitani: Rev. Sci. Instrum. 66 (1995) 1474.
15. C. T. Chen and F. Sette: Rev. Sci. Instrum. 60 (1989) 2533.
16. I. Ishii and A. P. Hitchcock: J. Electron Spectrosc. Rel. Phenom. 46 (1988) 55.
17. D. A. Outka, J. Stöhr, R. J. Madix, H. H. Rotermund, B. Hermsmeier and J. Solomon: Surf. Sci. 185 (1987) 53.
18. H. I. Sekiguchi, T. Sekiguchi and K. Tanaka: Phys. Rev. B 53 (1996) 12655.
19. K. Mase, M. Nagasono, T. Urisu and Y. Murata: Bull. Chem. Soc. Jpn. 69 (1996) 1829.
20. M. Nagasono, K. Mase and T. Urisu: Surf. Sci. 363 (1996) 342.