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Volumn 56, Issue 6, 1997, Pages 6569-6580

Critique of primitive model electrolyte theories

Author keywords

[No Author keywords available]

Indexed keywords

APPROXIMATION THEORY; FREE ENERGY; IONS; MATHEMATICAL MODELS; PHASE TRANSITIONS; THERMODYNAMIC STABILITY;

EID: 0031337568     PISSN: 1063651X     EISSN: None     Source Type: Journal    
DOI: 10.1103/PhysRevE.56.6569     Document Type: Article
Times cited : (47)

References (62)
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    • (b) 56, 3086 (1972);
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    • (c) 56, 3093 (1972).
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    • Europhys. Lett. 39, 611 (1997).EULEEJ
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    • (a) A. B. Pippard, Elements of Classical Thermodynamics for Advanced Students of Physics (Cambridge University Press, Cambridge, England, 1957), Chap. 7; (b) H. B. Callen, Thermodynamics and an Introduction to Thermostatistics, 2nd ed. (Wiley, New York, 1985), Chap. 8
    • (a) A. B. Pippard, Elements of Classical Thermodynamics for Advanced Students of Physics (Cambridge University Press, Cambridge, England, 1957), Chap. 7;(b) H. B. Callen, Thermodynamics and an Introduction to Thermostatistics, 2nd ed. (Wiley, New York, 1985), Chap. 8.
  • 35
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    • An association constant with fixed upper cutoff was considered by R. M. Fuoss, Trans. Faraday Soc. 30, 967 (1934), who also recognized the low-temperature insensitivity of (Formula presented) of the form (4.23) to the upper cutoff.TFSOA4
    • (1934) Trans. Faraday Soc. , vol.30 , pp. 967
    • Fuoss, R.M.1
  • 39
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    • 14, 465 (1976);
    • (1976) , vol.14 , pp. 465
  • 45
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    • H.-L. Vörtler and J. Heybey, Mol. Phys. 51, 73 (1984).MOPHAM
    • (1984) Mol. Phys. , vol.51 , pp. 73
    • Heybey, J.1
  • 48
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    • JPCHAX see also, D. Levesque and J. J. Weis, in The Monte Carlo Method in Condensed Matter Physics, 2nd ed., edited by K. Binder (Springer, Berlin, 1995)
    • D. Frenkel, J. Phys. Chem. 91, 4912 (1987); JPCHAXsee also, D. Levesque and J. J. Weis, in The Monte Carlo Method in Condensed Matter Physics, 2nd ed., edited by K. Binder (Springer, Berlin, 1995).
    • (1987) J. Phys. Chem. , vol.91 , pp. 4912
    • Frenkel, D.1
  • 50
    • 36849106010 scopus 로고
    • for mixtures, see G. A. Mansoori et al., 54, 1523 (1971);
    • (1971) , vol.54 , pp. 1523
    • Mansoori, G.A.1
  • 51
    • 0001608002 scopus 로고
    • In the strong coupling limit, (Formula presented) it has been shown by H. Gould, R. G. Palmer, and G. A. Estévez
    • (1991) Mol. Phys. , vol.72 , pp. 1365
    • Jackson, G.1
  • 52
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    • In the strong coupling limit, (Formula presented) it has been shown by H. Gould, R. G. Palmer, and G. A. Estévez, J. Stat. Phys. 21, 55 (1979), that the OCP energy computed via the MSA approaches this bound asymptotically; JSTPBS
    • (1979) J. Stat. Phys. , vol.21 , pp. 55
    • Gould, H.1    Palmer, R.G.2    Estévez, G.A.3
  • 53
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    • the same seems true for the HNC approximation, see K.-C. Ng, J. Chem. Phys. 61, 2680 (1974). However, the relevance of these observations to the reliability or accuracy of the HNC and MSA for the OCP model again seems obscure.JCPSA6
    • (1974) J. Chem. Phys. , vol.61 , pp. 2680
  • 54
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    • but note the following corrections: (a) In Eq. (9.8) the coefficient (Formula presented) in the correction factor should be (Formula presented) (b) in Eq. (9.9) the right-hand side should read (Formula presented)
    • but note the following corrections: (a) In Eq. (9.8) the coefficient (Formula presented) in the correction factor should be (Formula presented) (b) in Eq. (9.9) the right-hand side should read (Formula presented)
  • 59
    • 85037180617 scopus 로고
    • 96, 1507 (1992).
    • (1992) , vol.96 , pp. 1507


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