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0040681372
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1a-d on the reductive desorption of SAMs suggest that the charge transferred per molecule is approximately equal to unity, i.e., n ∼1 in eq 4 of the text.
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0000506304
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0038903390
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note
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The initial report of this chemistry (ref 1a) concerned the electrochemical deposition of n-alkanethiolates on Au(111) from 0.5 M KOH ethanolic solutions. The methodology is readily extended to Ag(111) and NaOH aqueous solutions.
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24
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49249147047
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25
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0040681370
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unpublished results, University of Utah
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Ex-situ STM results of the S adlayer on Ag(111) confirm the existance of a (√7 × √7)R10.9° structure (Q = 0.46). Stevenson, K.J.; White, H.S.; unpublished results, University of Utah, 1996.
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Stevenson, K.J.1
White, H.S.2
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0038903389
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Submitted
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Hatchett, D.W.; Vibel, R.H.; Stevenson, J.K.; Harris, J.M.; White, H.S. Submitted to J. Am. Chem. Soc.
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J. Am. Chem. Soc.
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Hatchett, D.W.1
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37
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0040681369
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note
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- adsorption are ca. 0.2 V more negative for the (100) and (110) orientations of Ag than reported here for the (111)-oriented electrodes (see ref 5).
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