Gemini surfactants at solid-liquid interfaces: Control of interfacial aggregate geometry

Langmuir

Volumn 13, Issue 24, 1997, Pages 6382-6387

  Manne, S ^a,c   Schaffet T E ^b   Huo, Q ^b   Hansma, P K ^b   Morse, D E ^b   Stucky, G D ^b   Aksayt, I A ^a  

^a Princeton University   (United States)

^b UNIVERSITY OF CALIFORNIA   (United States)

^c University of Arizona   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AGGLOMERATION; ELECTROSTATICS; GRAPHITE; MICA; MORPHOLOGY; NUCLEATION; PHASE INTERFACES; SURFACE TREATMENT;

INTERFACIAL AGGREGATE GEOMETRY;

SURFACE ACTIVE AGENTS;

EID: 0031275459     PISSN: 07437463     EISSN: None     Source Type: Journal    
DOI: 10.1021/la970070s     Document Type: Article

References (40)

1. Manne, S.; Cleveland, J. P.; Gaub, H. E.; Stucky, G. D.; Hansma, P. K. Langmuir 1994, 10, 4409-4413.
2. Manne, S.; Gaub, H. E. Science 1995, 270, 1480-1482.
3. Beck, J. S.; et al. J. Am. Chem. Soc. 1992, 114, 10834-10843.
4. Monnier, A.; et al. Science 1993, 261, 1299-1303.
5. Huo, Q.; et al. Chem. Mater. 1994, 6, 1176-1191.
6. Firouzi, A.; et al. Science 1995, 267, 1138-1143.
7. Huo, Q.; Leon, R.; Petroff, P. M.; Stucky, G. D. Science 1995,268, 1324-1327.
8. Yang, H.; Kuperman, A.; Coombs, N.; Mamiche-Afara, S.; Ozin, G. A. Nature 1996, 379, 703-705.
9. Mann, S.; Ozin, G. A. Nature 1996, 382, 313-319.
10. Aksay, I. A. et al. Science 1996, 273, 892-898.
11. Kumar, A.; Biebuyck, H. A.; Whitesides, G. M. Langmuir 1994, 10, 1498-1516.
12. Ulman, A. An Introduction to Ultrathin Organic Films: From Langmuir-Blodgett to Self-Assembly; Academic Press: Boston,MA, 1991.
13. For reviews see: (a) Zana, R. Curr. Opin. Colloid Interface Sci. 1996, 1, 566-571. (b) Rosen, M. J. CHEMTECH 1993, 30-33.
14. For reviews see: (a) Zana, R. Curr. Opin. Colloid Interface Sci. 1996, 1, 566-571. (b) Rosen, M. J. CHEMTECH 1993, 30-33.
15. This parameter reflects the effective molecular geometry of a given surfactant molecule in a micelle and is defined as g = v/(al), where v is the hydrocarbon chain volume, a is the optimum headgroup area per molecule, and l is the hydrocarbon chain length. Spherical micelles are favored when g < 1/3, cylinders are favored when 1/3 < g < 1/2, and bilayers and vesicles are favored when l/2 < g < 1. See: Israelachvili, J. N. ; Mitchell, D. J.; Ninham, B. W. J. Chem. Soc., Faraday Trans, 1 1976, 72, 1525-1568.
16. Zana, R.; Benrraou, M.; Rueff, R. Langmuir 1991, 7, 1072-1075.
17. Alami, E.; Levy, H.; Zana, R.; Skoulios, A. Langmuir 1993, 9, 940-944.
18. Hagslätt, H.; Söderman, O.; Jönsson, B. Langmuir 1994, 10, 2177-2187.
19. Danino, D.; Talmon, Y.; Zana, R. Langmuir 1995, 11, 1448-1456.
20. Karaborni, S.; et al. Science 1994, 266, 254-256.
21. Alami, E.; Beinert, G.; Marie, P.; Zana, R. Langmuir 1993, 9, 1465-1467.
22. Wanless, E. J.; Ducker, W. A. J. Phys. Chem. 1996, 100, 3207-3214.
23. Binnig, G.; Quate, C. F.; Gerber, Ch. Phys. Rev. Lett. 1986, 56, 930-933.
24. Pashley, R. M.; Israelachvili, J. N. Colloids Surf. 1981, 2, 169-187.
25. Kekicheff, P.; Christenson, H. K.; Ninham, B. W. Colloids Surf. 1989, 40, 31-41.
26. McDermott, D. C.; McCarney, J.; Thomas, R. K.; Rennie, A. R. J. Colloid Interface Sci. 1994, 162, 304-310.
27. Fragneto, G.; Thomas, R. K.; Rennie, A. R.; Penfold, J. Langmuir 1996, 12, 6036-6043.
28. Esumi, K.; Goino, M.; Koide, Y. Colloids Surf. 1996, 118, 161-166.
29. See for example Quirion, F.; Magid, L. J. J. Phys. Chem. 1986, 90, 5435-5441.
30. Tanford, C. The Hydrophobic Effect; John Wiley & Sons: New York, 1973.
31. Ducker, W. A.; Wanless, E. J. Langmuir 1996, 12, 5915-5920.
32. Salicylate and other phenyl derivatives are known to induce sphere-to-rod transitions in free solutions of quaternary ammonium surfactants, by reducing the headgroup area due to strong binding and charge neutralization. This high binding strength arises from the partially hydrophobic character of these counterions, which results in a combination of electrostatic interactions with headgroups and hydrophobic interactions with the adjacent carbon atoms in the tailgroup. See Cassidy, M. A.; Warr, G. G. J. Phys. Chem. 1996, 100, 3237-3240 and references therein.
33. Saleeb, F. Z.; Kitchener, J. A. J. Chem. Soc. 1965, 911-917.
34. See: Zettlemoyer, A. C. J. Colloid Interface Sci. 1968, 28, 343-369 and the discussion in ref. 1.
35. (a) Groszek, A. J. Proc. R. Soc. London, Sect. A 1970, 374, 473-498.
36. (b) Rabe, J. P.; Buchholz, S. Science 1991, 253, 424-427.
37. (c) Yeo, Y. H.; Yackoboski, K.; McGonigal, G. C.; Thompson, D. J. J. Vac. Sci. Technol., A 1992, 10, 600-602.
38. Tolbert, S. H.; Schäffer, T. E.; Feng, J.; Hansma, P. K.; Stucky, G. D. Chem. Mater., in press.
39. Danino, D.; Talmon, Y.; Levy, H.; Beinert, G.; Zana, R. Science 1995, 269, 1420-1421.
40. Warr, G. G.; Sen, R.; Evans, D. F.; Trend, J. E. J. Phys. Chem. 1988, 92, 774-783.