Block copolymers by transformation of living ring-opening metathesis polymerization into controlled/"living" atom transfer radical polymerization

Macromolecules

Volumn 30, Issue 21, 1997, Pages 6513-6516

  Coca, Simion ^a   Paik, Hyun Jong ^a   Matyjaszewski, Krzysztof ^a  

^a CARNEGIE MELLON UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALDEHYDES; FREE RADICAL POLYMERIZATION; INITIATORS (CHEMICAL); POLYACRYLATES; POLYSTYRENES; RING OPENING POLYMERIZATION;

DICYCLOPENTADIENE; LIVING ATOM TRANSFER RADICAL POLYMERIZATION; LIVING RING OPENING METATHESIS POLYMERIZATION; NORBORNENE; POLYMETHYL ACRYLATES; WITTIG REACTIONS;

BLOCK COPOLYMERS;

EID: 0031248065     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma970637b     Document Type: Article

References (52)

1. (a) Living and controlled/"living" polymerizations should be distinguished. The living polymerization can be defined as a chain growth process in which no irreversible chain transfer or termination exists. The controlled/"living" polymerization is the polymerization system which provides well-defined polymers but allows tolerable amounts of chain transfer or termination.
2. (b) Matyjaszewski, K.; Muller, A. H. E. Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 1997, 38 (1), 6.
3. Matyjaszewski, K. In Cationic Polymerizations: Mechanisms, Synthesis, and Applications; Marcel Dekker, Inc.: New York, 1996.
4. (a) Szwarc, M. Nature 1956, 178, 1168.
5. (b) Hsieh, H. L.; Quirk, R. P. In Anionic Polymerization: Principles and Practical Applications; Marcel Dekker, Inc.: New York, 1996.
6. (a) Miyamoto, M.; Sawamoto, M.; Higashimura, T. Macromolecules 1984, 17, 265.
7. (b) Faust, R.; Kennedy, J. P. Polym. Bull. 1986, 15, 317.
8. Webster, O. W.; Hertler, W. R.; Sogah, D. Y.; Farnham, W. B.; Rajan-Babu, T. V. J. Am. Chem. Soc. 1983, 705, 5706.
9. (a) Grubbs, R. H.; Tumas, W. Science 1989, 243, 907.
10. (b) Schrock, R. R. Acc. Chem. Res. 1990, 23, 158.
11. (a) Killian, C. M.; Tempel, D. J.; Johnson, L. K.; Brookhart, M. K. J. Am. Chem. Soc. 1996, 118, 11664.
12. (b) Scollard, J. D.; McConville, D. M. J. Am. Chem. Soc. 1996, 118, 10008.
13. (c) Baumann, R.; Davis, W. M.; Schrock, R. R. J. Am. Chem. Soc. 1997, 119, 3830.
14. (a) Otsu, T.; Yoshida, M. Makromol. Chem., Rapid Commun. 1982, 3, 127.
15. (b) Solomon, D. H.; Rizzardo, E.; Cacioli, P. U.S. Patent 4,581,429,1986.
16. (c) Georges, M. K.; Veregin, R. P. N.; Kazmaier, P. M.; Hamer, G. K. Macromolecules 1993, 26, 2987.
17. (d) Wang, J. S.; Matyjaszewski, K. J. Am. Chem. Soc. 1995, 117, 5614.
18. (e) Kato, M.; Kamigaito, M.; Sawamoto, M.; Higashimura, T. Macromolecules 1995, 28, 1721.
19. (f) Percec, V.; Barboiu, B. Macromolecules 1995, 28, 7970.
20. Noshay, A.; McGrath, J. E. In Block Copolymers: Overview and Critical Survey; Academic Press: New York, 1977.
21. (a) Ivin, K. J.; Mol, J. C. In Olefin Metathesis and Metathesis Polymerization; Academic Press: San Diego, 1997.
22. (b) Breslow, D. S. Prog. Polym. Sci. 1991, 18, 1141.
23. Grubbs, R. H.; Gilliom, L. R. J. Am. Chem. Soc. 1986, 108, 733.
24. (a) Bazan, G. C.; Schrock, R. R.; Cho, H.-N.; Gibson, V. C. Macromolecules 1991, 24, 4495.
25. (b) Murdzek, J. S.; Schrock, R. R. Macromolecules 1987, 20, 2460.
26. (a) Schrock, R. R.; Feldman, J.; Cannizzo, L. F.; Grubbs, R. H. Macromolecules 1987, 20, 1169.
27. (b) Kress, J.; Osborn, J. A.; Greene, R. M. E.; Ivin, K. J.; Rooney, J. J. J. Am. Chem. Soc. 1987, 109, 899.
28. (c) Coca, S.; Dimonie, M.; Dragutan, V.; Ion, R.; Popescu, L.; Teodorescu, M.; Moise, F. J. Mol. Catal. 1994, 90, 101.
29. Wallace, K. C.; Liu, A. H.; Dewan, J. C.; Schrock, R. R. J. Am. Chem. Soc. 1988, 110, 4964.
30. Toreki, R.; Schrock, R. R. J. Am. Chem. Soc. 1990, 112, 2448.
31. Nguen, S. T.; Johnson, L. K.; Grubbs, R. H. J. Am. Chem. Soc. 1992, 114, 3974.
32. Novak, B. M.; Risse, W.; Grubbs, R. H. Adv. Polym. Sci. 1992, 102, 47.
33. Schue, F. Synthesis of Block Copolymers by Transformatiom Reactions. In Comprehensive Polymer Science, 2nd ed.; Allen, G., Bevington, J. C., Eds.; Pergamon Press: Oxford 1989; Vol. 6, Chapter 10.
34. Risse, W.; Grubbs, R. H. J. Mol. Catal. 1991, 65, 211.
35. Tritto, I.; Sacchi, M. C.; Grubbs, R. H. Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 1994, 35, 696.
36. Wayland, B. B.; Poszmik, G.; Mukerjee, S. L.; Fryd, M. J. Am. Chem. Soc. 1994, 116, 7943.
37. Gaynor, S. G.; Wang, J. S.; Matyjaszewski, K. Macromolecules 1995, 28, 8051.
38. (a) Bellus, D. Pure Appl. Chem. 1985, 57, 1827.
39. (b) Curran, C. P.; Newcomb, M. Acc. Chem. Res. 1988, 21, 206.
40. (a) Wang, J.-S.; Gaynor, S. G.; Matyjaszewski, K. Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 1995, 36, 465.
41. (b) Matyjaszewski, K. Curr. Opin. Solid State Mater. Sci. 1996, 7, 769.
42. (c) Wang, J. S.; Matyjaszewski, K. Macromolecules 1995, 28, 7901.
43. (d) Greszta, D.; Matyjaszewski, K. Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 1996, 37 (1), 569.
44. (e) Jo, S. M.; Gaynor, S. G.; Matyjaszewski, K. Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 1996, 37, 272.
45. (f) Coca, S.; Matyjaszewski, K. Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 1996, 37 (1), 573.
46. Patten, T. E.; Xia, J.; Abernathy, T.; Matyjaszewski, K. Science 1996, 272, 866.
47. (a) Coca, S.; Matyjaszewski, K. Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 1997, 38 (1), 693.
48. (b) Coca, S.; Matyjaszewski, K. Macromolecules 1997, 30, 2808.
49. Schrock's carbene is available from Strem Chemicals, Inc.
50. Risse, W.; Grubbs, R. H. Makromol. Chem., Rapid Commun. 1989, 10, 73.
51. Lavallee, D. K.; Xu, Z.; Pina, R. J. Org. Chem. 1993, 58, 6000.
52. Katz, T. J.; Lee, S. J.; Acton, N. Tetrahedron Lett. 1976, 4247.