Molecular composite films from polybenzoxazole and crosslinked polymer matrixes

Journal of Polymer Science, Part A: Polymer Chemistry

Volumn 35, Issue 11, 1997, Pages 2157-2165

  Mcgee, Robert L ^a   So, Ying Hung ^a   Martin, Steve J ^a   Broomall, Charles F ^a   Jeor, Var St ^a   Curphy, James J ^a   Swedberg, Eric J ^a   Wetters, Derrick G ^a  

^a DOW CHEMICAL COMPANY   (United States)

Author keywords

Benzocyclobutene; Delamination resistance; Film; Film density; Interlayer integrity; Molecular composite; Phase separation; Poly(p phenylenebenzobis(oxazole)); Poly(p phenylenebenzobis(thiazole)); Tensile modulus; Tensile strength

Indexed keywords

DELAMINATION; HEAT TREATMENT; NONMETALLIC MATRIX COMPOSITES; PHASE SEPARATION; POLYMERS; TENSILE PROPERTIES; THERMODYNAMIC STABILITY; THERMOSETS; TRANSMISSION ELECTRON MICROSCOPY;

DELAMINATION RESISTANCE; METHANESULFONIC ACID; MOLECULAR COMPOSITE; PHASE SEGREGATION; POLYBENZOXAZOLE; POLYPHOSPHORIC ACID;

PLASTIC FILMS;

EID: 0031210802     PISSN: 0887624X     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1099-0518(199708)35:11<2157::AID-POLA6>3.0.CO;2-V     Document Type: Article

References (25)

1. (a) T. E. Helminiak, ACS Div. Org. Coatings Plastic Chem. Prepr., 40, 475 (1979);
2. (b) For review articles: The Materials Science and Engineering of Rigid-Rod Polymers; W. W. Adams, R. K. Eby, and D. E. McLemore, Eds., Symposium Proceedings, Vol. 134, Materials Research Society, Pittsburgh, PA, 1989, Part VII.
3. W. F. Hwang, D. R. Wiff, and C. Verschoore, Polym. Eng. Sci., 23, 789-791 (1983).
4. W. F. Hwang, D. R. Wiff, and C. L. Benner, J. Macromol. Sci.-Phys., B22(2), 231-257 (1983).
5. O. A. Nehme, R. J. Farris, C. A. Gabriel, M. F. Malone, and E. T. Thomas, J. Appl. Polym. Sci., 35, 1955-1965 (1988).
6. H. H. Chuah, T. Kyu, and T. E. Helminiak, Polymer, 28, 2130-2132 (1987).
7. J. J. Rafalko, R. T. Chen, J. D. Menczel, M. T. Demeuse, and L. C. Sawyer, Polym. Mater. Sci. Eng., 59, 711-713 (1988).
8. (a) I. L. Klundt, Chem. Rev., 70, 471-487 (1970);
9. (b) M. P. Cava and D. R. Rapier, J. Am. Chem. Soc., 79, 1701-1705 (1957);
10. (c) J. J. McCullough, Acc. Chem. Res., 13, 270-276 (1980).
11. (d) L. A. Errede, J. Am. Chem. Soc., 83, 949-954 (1961).
12. (a) L. S. Tan and F. E. Arnold, Am. Chem. Soc., Polym. Div., Polym. Prepr., 26(2), 176-179 (1985);
13. (b) R. A. Kirchhoff, U.S. Pat. 4,540,763 (Aug 1985); Chem. Abstr., 104, 34502w (1986).
14. For review articles: (c) L. S. Tan, E. J. Soloski, and F. E. Arnold, in Cross-Linked Polymers, R. A. Dickie, S. S. Labana, and R. S. Bauer, Eds., ACS Symposium Series 367, American Chemical Society, Washington, DC, 1988, pp. 349-365. (d) R. A. Kirchhoff, C. J. Carriere, K. J. Bruza, N. G. Rondan, and R. L. Sammler, J. Macromol. Sci. Chem., A28 (11, 12), 1079-1113 (1991). (e) R. A. Kirchhoff and K. J. Bruza, Prog. Polym. Sci., 18, 85-185 (1993).
15. For review articles: (c) L. S. Tan, E. J. Soloski, and F. E. Arnold, in Cross-Linked Polymers, R. A. Dickie, S. S. Labana, and R. S. Bauer, Eds., ACS Symposium Series 367, American Chemical Society, Washington, DC, 1988, pp. 349-365. (d) R. A. Kirchhoff, C. J. Carriere, K. J. Bruza, N. G. Rondan, and R. L. Sammler, J. Macromol. Sci. Chem., A28 (11, 12), 1079-1113 (1991). (e) R. A. Kirchhoff and K. J. Bruza, Prog. Polym. Sci., 18, 85-185 (1993).
16. For review articles: (c) L. S. Tan, E. J. Soloski, and F. E. Arnold, in Cross-Linked Polymers, R. A. Dickie, S. S. Labana, and R. S. Bauer, Eds., ACS Symposium Series 367, American Chemical Society, Washington, DC, 1988, pp. 349-365. (d) R. A. Kirchhoff, C. J. Carriere, K. J. Bruza, N. G. Rondan, and R. L. Sammler, J. Macromol. Sci. Chem., A28 (11, 12), 1079-1113 (1991). (e) R. A. Kirchhoff and K. J. Bruza, Prog. Polym. Sci., 18, 85-185 (1993).
17. H. H. Chauh, L. S. Tan, and F. E. Arnold, Poly. Eng. Sci., 29, 107-112 (1989).
18. Y. H. So, A. Sen, P. Kim, and V. St. Jeor, J. Polym. Sci.: Part A: Polym. Chem., 33, 2893-2899 (1995).
19. Crosslinking polyamides through benzocyclobutenes which were part of the polymer backbone had been reported: (a) L. J. Markoski, K. A. Walker, G. A. Deeter, G. E. Spilman, D. C. Martin, and J. S. Moore, Chem. Mater., 5, 248-250 (1993). (b) G. E. Spilman, J. Tao, J. S. Moore, and D. C. Martin, Am. Chem. Soc., Polym. Div., Polym. Prepr., 35(2), 667-668 (1994). (c) N. Venkatasubramanian and L. S. Tan, Am. Chem. Soc., Polym. Div., Polym. Prepr., 35(2), 623-624 (1994).
20. Crosslinking polyamides through benzocyclobutenes which were part of the polymer backbone had been reported: (a) L. J. Markoski, K. A. Walker, G. A. Deeter, G. E. Spilman, D. C. Martin, and J. S. Moore, Chem. Mater., 5, 248-250 (1993). (b) G. E. Spilman, J. Tao, J. S. Moore, and D. C. Martin, Am. Chem. Soc., Polym. Div., Polym. Prepr., 35(2), 667-668 (1994). (c) N. Venkatasubramanian and L. S. Tan, Am. Chem. Soc., Polym. Div., Polym. Prepr., 35(2), 623-624 (1994).
21. Crosslinking polyamides through benzocyclobutenes which were part of the polymer backbone had been reported: (a) L. J. Markoski, K. A. Walker, G. A. Deeter, G. E. Spilman, D. C. Martin, and J. S. Moore, Chem. Mater., 5, 248-250 (1993). (b) G. E. Spilman, J. Tao, J. S. Moore, and D. C. Martin, Am. Chem. Soc., Polym. Div., Polym. Prepr., 35(2), 667-668 (1994). (c) N. Venkatasubramanian and L. S. Tan, Am. Chem. Soc., Polym. Div., Polym. Prepr., 35(2), 623-624 (1994).
22. Y. H. So, J. M. Zaleski, C. L. Murlick, and A. Ellaboudy, Macromolecules, 29, 2783-2795 (1996).
23. The processing of PBT and PBO films was also pursued at Foster-Miller, Inc.: R. W. Lusignea, in The Materials Science and Engineering of Rigid-Rod Polymers, W. W. Adams, R. K. Eby, and D. E. McLemore, Eds., Symposium Proceedings, Vol. 134, Materials Research Society, Pittsburgh, PA, 1989, pp. 265-276.
24. The morphology of PBT thin films is similar to that of PBO films: E. J. Roche, in The Materials Science and Engineering of Rigid-Rod Polymers, W. W. Adams, R. K. Eby, and D. E. McLemore, Eds., Symposium Proceedings, Vol. 134, Materials Research Society, Pittsburgh, PA, 1989, pp. 457-463.
25. The morphologies of PBO films and PBO/nylon molecular composite films have been reported: D. S. Nelson and D. S. Soane, Poly. Eng. Sci., 34, 965-974 (1994).