Modeling of first shell substitution effects and preferred cyclization in sol-gel polymerization

Macromolecules

Volumn 30, Issue 13, 1997, Pages 3921-3929

  Kasehagen, Leo J ^a   Rankin, Stephen E ^a   McCormick, Alon V ^a   Macosko, Christopher W ^a  

^a University of Minnesota   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSIS; GELATION; MATHEMATICAL MODELS; MONTE CARLO METHODS; OLIGOMERS; ORGANIC POLYMERS; REACTION KINETICS; SOL-GELS; SUBSTITUTION REACTIONS;

KINETIC RECURSIVE MODEL; POLYDISPERSITY INDEX; SHELL SUBSTITUTION EFFECTS;

POLYMERIZATION;

EID: 0031167301     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma9619142     Document Type: Article

References (45)

1. Flory, P. J. J. Am. Chem. Soc. 1941, 63, 3083; Principles of Polymer Chemistry, 1st ed.; Cornell University Press: Ithaca, NY, 1953.
2. Flory, P. J. J. Am. Chem. Soc. 1941, 63, 3083; Principles of Polymer Chemistry, 1st ed.; Cornell University Press: Ithaca, NY, 1953.
3. Stockmayer, W. H. J. Chem. Phys. 1943, 11, 45; 1944, 12, 125.
4. Stockmayer, W. H. J. Chem. Phys. 1943, 11, 45; 1944, 12, 125.
5. Brinker. C. J.; Assink, R. A. J. Non-Cryst. Solids 1989, 111, 48.
6. Pouxviel, J. C.; Boilot, J. P. J. Non-Cryst. Solids 1987, 94, 374.
7. Ling, D. A. Ph.D. thesis, Georgia Institute of Technology, 1992.
8. Assink, R. A.; Kay, B. D. J. Non-Cryst. Solids 1988, 107, 35.
9. Doughty, D. A.; Assink, R. A.; Kay, B. D. Adv. Chem. 1990, 224, 241.
10. Ng, L. V.; Thompson, P.; Sanchez, J.; Mascsko, C. W.; McCormick, A. V. Macromolecules 1995, 28, 6471.
11. Devreux, F.; Boilot, J. P.; Chaput, F. Phys. Rev. A 1999, 41, 6901.
12. Malier, L.; Boilot, J. P.; Chaput, F.; Devreux, F. Phys Rev. A 1992, 46, 959
13. Vega, A. J.; Scherer, G. W. J. Non-Cryst. Solids 1989, 111, 153.
14. Klemperer, W. G.; Mainz, V. V.; Ramamurthi, S. D.; Rosenberg, F. S. Mater. Res. Soc. Symp. Proc. 1988, 121, 15.
15. Tallent, D. R; Bunker, B. C.; Brinker, C. J.; Balfe, C. A. Mater. Res. Soc. Symp. Proc. 1989, 73, 261.
16. Kelts, L. W.; Armstrong, N. J. J. Mater. Res. 1989, 4, 423.
17. van Beek, J. J.; Seykens, D.; Jansen, J. B. H. J. Non-Cryst. Solids 1991, 134, 14.
18. van Beek, J. J.; Seykens, D.; Jansen, J. B. H. J. Non-Cryst. Solids 1992, 146, 111.
19. Capozzi, C. A.; Pye, L. D.; Condrate, R. A. Sr. Mater. Lett. 1992, 4, 423.
20. Brunet, F.; Cabane, B. J. Non-Cryst Solids 1993, 163, 211.
21. Mikeš, J.; Dušek, K. Macromolecules 1982, 15, 93.
22. Sarmoria, C.; Miller, D. R. Macromolecules 1991, 24, 1833.
23. Macosko, C. W.; Miller, D. R. Macromolecules 1976, 9, 199.
24. Galina, H.; Szustalewicz, A Macromolecules 1989, 22, 3124.
25. Kuchanov, S. I.; Povolotskaya, E. S. Vysokomol. Soedin. 1982, A24, 2190.
26. Bailey, J. K.; Macoako, C. W.; Mecartney, M. L. J. Non-Cryst Solids 1990, 125, 208.
27. Kallala, M.; Julien, R.; Cabane, B. J. Phys. II Fr. 1992, 2, 7.
28. Hendrickson, R. C.; Gupta, A. M.; Macosko, C. W. Comput. Polym. Sci. 1994, 4, 563.
29. Sanchez, J. Ph.D. thesis, University of Minnesota, 1994.
30. Sarmoria, C.; Vallés, E.; Miller, D. R. Macromol. Chem., Macromol. Symp. 1986, 2, 69.
31. Gordon, M.; Scantlebury, G. R. J. Polym. Sci, Part C 1968, 16, 3933.
32. Stanford, J. L.; Stepto, R F. T.; Waywell, D. R J. Chem. Soc., Faraday Trans. 1 1975, 71, 1308.
33. Kumar, A.; Wahal, S.; Sastri, S.; Gupta, S. Polymer 1986, 27, 583.
34. Dutton, S.; Rolfes, H.; Stepto, R. F. T. Polymer 1994, 35, 4521.
35. Leung, Y. K.; Eichinger, B. E. J. Chem. Phys. 1984, 80, 3877.
36. Galiatsatos, V.; Eichinger, B. E. J Polym. Sci., Polym. Phys. Ed. 1988, 26, 595.
37. Hendrickson, R.; Gupta, A.; Macosko, C. W. Comput. Polym. Sci. 1995, 5, 135.
38. Matejka, L.; Dušek, K. J. Polym. Sci. Part A 1996, 33, 461.
39. Sanchez, J.; Rankin, S. E.; McCormick, A. V. Ind. Eng. Chem. Res. 1996, 35, 117.
40. Sefcik, J.; McCormick, A. V. Catal. Today 1997, 35, 205.
41. Miller, D. R.; Macoeko, C. W. Macromolecules 1980, 13, 1063.
42. Somvársky, H.; Dušek, K. Polym. Bull. 1994, 33, 369.
43. Shy, L. Y.; Leung, V. K.; Eichinger, B. E. Macromolecules 1985, 18, 983.
44. Ng, L. V.; McCormick, A. V. J. Phys. Chem. 1996, 100, 12517.
45. Rankin, S. E.; Macosko, C. W., McCormick, A. V. Mater. Res. Soc. Symp. Proc. 1996, 435, 113.