메뉴 건너뛰기




Volumn 101, Issue 9, 1997, Pages 1535-1542

Solid state electron-hopping transport and frozen concentration gradients in a mixed valent viologen-tetraethylene oxide copolymer

Author keywords

[No Author keywords available]

Indexed keywords

CHARGE TRANSFER; CONDUCTIVE FILMS; ELECTRIC CONDUCTIVITY; ELECTROCHEMICAL ELECTRODES; ELECTROCHEMISTRY; ELECTRON TRANSPORT PROPERTIES; INTERFACES (MATERIALS); ORGANIC COMPOUNDS; REDOX REACTIONS;

EID: 0031079367     PISSN: 15206106     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp962614p     Document Type: Article
Times cited : (38)

References (76)
  • 27
    • 0003748396 scopus 로고
    • Wiley Interscience John Wiley and Sons: New York
    • Bard, A. J. Integrated Chemical Systems; Wiley Interscience John Wiley and Sons: New York, 1994.
    • (1994) Integrated Chemical Systems
    • Bard, A.J.1
  • 29
    • 5844265026 scopus 로고
    • American Institute of Physics: Woodbury, NY
    • (b) Aviram A. AIP Conference Proceedings 262; American Institute of Physics: Woodbury, NY, 1992.
    • (1992) AIP Conference Proceedings , vol.262
    • Aviram, A.1
  • 49
    • 85087582371 scopus 로고    scopus 로고
    • 8b-d
    • 8b-d
  • 54
    • 5844287192 scopus 로고    scopus 로고
    • note
    • Loss in signal was observed when the film was electrolyzed repeatedly over the 1+/0 couple, suggesting that the 0-valent form is unstable or soluble.
  • 55
    • 85087580379 scopus 로고    scopus 로고
    • note
    • 4, the films thinned over several minutes until only ca. 30 nm persistently remained.
  • 60
    • 85087580952 scopus 로고    scopus 로고
    • note
    • PEAK values of reduction and oxidation peaks.
  • 68
    • 85087582472 scopus 로고    scopus 로고
    • note
    • 2,APP)C/d.
  • 72
    • 5844241696 scopus 로고    scopus 로고
    • note
    • Determination of the mixed valent film composition by coulometry or spectrophotometry is in principle possible, but both approaches face substantial technical difficulties.
  • 74
    • 5844336399 scopus 로고    scopus 로고
    • note
    • Electrical gradients shown in Figure 6, bottom, are calculated assuming uniform current density within the gradient film. The actual electrical gradients for steady state currents under a ΔE=+600 mV forward bias may differ those shown because the simple calculation ignores the built-in Nernstian potential gradient as well as bulk and interfacial space-charges.
  • 75
    • 5844291345 scopus 로고    scopus 로고
    • note
    • Electrolyzed bipotentiostatically, opposing electrodes ±150 mV relative to E○′
  • 76
    • 85087581231 scopus 로고    scopus 로고
    • note
    • 2 and using the total IDA finger surface area.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.