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Volumn 38, Issue 2, 1997, Pages 229-232

Mechanism of metal-carbenoid insertion into the Si-H bond

Author keywords

[No Author keywords available]

Indexed keywords

ORGANOSILICON DERIVATIVE;

EID: 0031029518     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(96)02285-X     Document Type: Article
Times cited : (43)

References (28)
  • 13
    • 0000633297 scopus 로고
    • Trost, B.M., Fleming, I., Ed.; Pergamon Press: Oxford, U.K.; and references cited theirein
    • Taber, D.F. in Comprehensive Organic Synthesis; Trost, B.M., Fleming, I., Ed.; Pergamon Press: Oxford, U.K. 1991; Vol. 4, pp 1045-1062 and references cited therein.
    • (1991) Comprehensive Organic Synthesis , vol.4 , pp. 1045-1062
    • Taber, D.F.1
  • 17
    • 0343302438 scopus 로고    scopus 로고
    • 2SiD and found that 5b was obtained in 90% yield, with complete incorporation of deuterium
    • 2SiD and found that 5b was obtained in 90% yield, with complete incorporation of deuterium.
  • 18
    • 0343302437 scopus 로고    scopus 로고
    • 2O which gave KIE values of 2.57 and 1.7 respectively
    • 2O which gave KIE values of 2.57 and 1.7 respectively.
  • 20
    • 0343737962 scopus 로고    scopus 로고
    • +
    • +.
  • 22
    • 0000185886 scopus 로고
    • and references cited theirein
    • Mayr, H.; Basso, N.; Hagen, G. J. Am. Chem. Soc., 1992,114, 3060-3066 and references cited therein.
    • (1992) J. Am. Chem. Soc. , vol.114 , pp. 3060-3066
    • Mayr, H.1    Basso, N.2    Hagen, G.3
  • 23
    • 0342432877 scopus 로고    scopus 로고
    • note
    • 3d,f again supporting the occurrence of an early transition state.
  • 26
    • 0343737961 scopus 로고    scopus 로고
    • note
    • 14 A polar mechanism with rate determining formation of silicenium ion was proposed (p=2.46). Such a polar mechanism would imply more charge development at the transition state than that suggested by the LFER studies (Fig.-l) and therefore can be ruled out.
  • 28
    • 0343302430 scopus 로고    scopus 로고
    • note
    • 3d The hydrosilylation product observed in this case might be formed through an ionic pathway and not via oxidative addition, as suggested by some recent investigations carried out in our laboratories which will be reported in a forthcoming article.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.