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0000633297
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Trost, B.M., Fleming, I., Ed.; Pergamon Press: Oxford, U.K.; and references cited theirein
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0000234509
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Doyle, M.P.; Westrum, L.J.; Wendelmoed, N.E.W.; See, M.M.; Boone, W.P.; Bagheri, V.; Pearson, M.M. J. Am. Chem. Soc., 1993, 115, 958-964.
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Pearson, M.M.7
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17
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0343302438
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2SiD and found that 5b was obtained in 90% yield, with complete incorporation of deuterium
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2SiD and found that 5b was obtained in 90% yield, with complete incorporation of deuterium.
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18
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0343302437
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2O which gave KIE values of 2.57 and 1.7 respectively
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2O which gave KIE values of 2.57 and 1.7 respectively.
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19
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4243664295
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Hansch, C.; Leo, A.; Taft, R.W. Chem. Rev., 1991, 91, 165-195.
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20
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0343737962
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+
-
+.
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22
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0000185886
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and references cited theirein
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Mayr, H.; Basso, N.; Hagen, G. J. Am. Chem. Soc., 1992,114, 3060-3066 and references cited therein.
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Mayr, H.1
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23
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0342432877
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note
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3d,f again supporting the occurrence of an early transition state.
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24
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1942474160
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(a) Wolf, J.R.; Hamaker, C.G.; Djukic, J.-P.; Kodadek, T.; Woo, L.K. J. Am. Chem. Soc., 1995, 117, 9194-9199;
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Wolf, J.R.1
Hamaker, C.G.2
Djukic, J.-P.3
Kodadek, T.4
Woo, L.K.5
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26
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0343737961
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note
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14 A polar mechanism with rate determining formation of silicenium ion was proposed (p=2.46). Such a polar mechanism would imply more charge development at the transition state than that suggested by the LFER studies (Fig.-l) and therefore can be ruled out.
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27
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0342432874
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Submitted
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Bulugahapitiya, P.; Landais, Y.; Parra-Rapado, L.; Planchenault, D.; Weber, V. J. Org. Chem.(Submitted).
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J. Org. Chem.
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Bulugahapitiya, P.1
Landais, Y.2
Parra-Rapado, L.3
Planchenault, D.4
Weber, V.5
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28
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0343302430
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note
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3d The hydrosilylation product observed in this case might be formed through an ionic pathway and not via oxidative addition, as suggested by some recent investigations carried out in our laboratories which will be reported in a forthcoming article.
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