Reaction of dihydrosilanes with ethyl diazoacetate: Synthesis of 3,3-disubstituted 3-silaglutarates

Journal of Organometallic Chemistry

Volumn 514, Issue 1-2, 1996, Pages 67-71

  Barnier, Jean Pierre ^a   Blanco, Luis ^a  

^a UNIVERSITÉ PARIS SUD   (France)

Author keywords

3 silaglutarates; Ethyl diazoacetate; Rhodium catalysis; Si; Silicon hydrides; Synthesis

Indexed keywords

EID: 0030591516     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/0022-328X(95)06035-U     Document Type: Article

References (49)

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47. [25] To our knowledge such silatriesters are not reported in the literature. We thank one of the referees who suggested that such compounds could be of interest to replace methyltriacetoxysilane in the elaboration of silicone elastomers since vulcanization would produce ethyl acetate instead of acetic acid upon hydrolysis.
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49. [27] The same compound 4 was prepared by rhodium acetate catalyzed reaction of ethyl diazoacetate with the allylsilaglutarate 2c. A careful silica gel column chromatography gave fractions enriched in each isomer, which has allowed us to determine their characteristic spectroscopic signals.