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Volumn 53, Issue 23, 1997, Pages 7795-7804

Asymmetric hydroformylation of conjugated dienes catalyzed by chiral phosphine-phosphite-Rh(I) complex

Author keywords

[No Author keywords available]

Indexed keywords

ALDEHYDE; ALKENE DERIVATIVE;

EID: 0031011797     PISSN: 00404020     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4020(97)00471-7     Document Type: Article
Times cited : (91)

References (41)
  • 4
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    • (a) Kummer, R.; Weiss, F. J. Symp. Rhodium Homogeneous Catal. 1978, 87-93; Chem Abstr. 1979, 90, 38503n.
    • (1979) Chem Abstr. , vol.90
  • 5
    • 0342353996 scopus 로고    scopus 로고
    • Eur. Pat. Appl. EP 577,042
    • (b) Packett, D. L. Eur. Pat. Appl. EP 577,042; Chem. Abstr. 1994, 120, 298075j.
    • Packett, D.L.1
  • 6
    • 22944463460 scopus 로고
    • (b) Packett, D. L. Eur. Pat. Appl. EP 577,042; Chem. Abstr. 1994, 120, 298075j.
    • (1994) Chem. Abstr. , vol.120
  • 7
    • 0342353994 scopus 로고    scopus 로고
    • U.S. US 5,312,996
    • (c) Packett, D. L. U.S. US 5,312,996; Chem. Abstr. 1995, 123, 82828w.
    • Packett, D.L.1
  • 8
    • 4243538797 scopus 로고
    • (c) Packett, D. L. U.S. US 5,312,996; Chem. Abstr. 1995, 123, 82828w.
    • (1995) Chem. Abstr. , vol.123
  • 10
    • 0002086347 scopus 로고
    • Recently, Bertozzi et al. reported the selective formation of β,γ-unsaturated aldehydes by hydroformylation of conjugated dienes such as 1,3-butadiene, isoprene, and 1,3-pentadiene using rhodium vapor-mesitylene cocondensates as a catalytic precursor: Bertozzi, S.; Campigli, N.; Vitulli, G.; Lazzaroni, R.; Salvadori, P. J. Organomet. Chem. 1995, 487, 41-45.
    • (1995) J. Organomet. Chem. , vol.487 , pp. 41-45
    • Bertozzi, S.1    Campigli, N.2    Vitulli, G.3    Lazzaroni, R.4    Salvadori, P.5
  • 22
    • 0343659184 scopus 로고    scopus 로고
    • Efficient stirring of the reaction mixture is indispensable for obtaining high regio- and enantioselectivities. Otherwise, variable amounts of 4a were formed via isomerization of 3a, and the ee of 3a has dropped to some extent (80-90% ee)
    • Efficient stirring of the reaction mixture is indispensable for obtaining high regio- and enantioselectivities. Otherwise, variable amounts of 4a were formed via isomerization of 3a, and the ee of 3a has dropped to some extent (80-90% ee).
  • 25
    • 0342353988 scopus 로고
    • Wilkinson, G., Ed.; Pergamon Press Ltd.: Oxford
    • Hughes, R. P. Comprehensive Organometallic Chemistry; Wilkinson, G., Ed.; Pergamon Press Ltd.: Oxford, 1982; Vol. 5, pp. 493-506.
    • (1982) Comprehensive Organometallic Chemistry , vol.5 , pp. 493-506
    • Hughes, R.P.1
  • 26
    • 0342353989 scopus 로고    scopus 로고
    • This value corresponds to 10% ee. The deviation from the observed ee can be explained by assuming that the selectivity of the formation of (R)-or (5)-16 may slightly depend on the enantioface discrimination during the formation of 15
    • This value corresponds to 10% ee. The deviation from the observed ee can be explained by assuming that the selectivity of the formation of (R)-or (5)-16 may slightly depend on the enantioface discrimination during the formation of 15.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.