An efficient method for converting alcohols to azides with 2,4,4,6-tetrabromo-2,5-cyclohexadienone/PPh3/Zn(N3)2·Py

Tetrahedron Letters

Volumn 38, Issue 22, 1997, Pages 3955-3958

  Saito, Akiko ^a   Saito, Kazumi ^a   Tanaka, Akira ^a   Oritani, Takayuki ^a  

^a TOHOKU UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

2,4,4,6 TETRABROMO 2,5 CYCLOHEXADIENONE; ALCOHOL DERIVATIVE; AZIDE; REAGENT; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; SYNTHESIS;

EID: 0031006588     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(97)00788-0     Document Type: Article

References (12)

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2. Hughes, D. L.; Organic Reactions, 1992, 42, 335-656.
3. Hughes, D. L.; Organic Preparations and Procedures Int., 1996, 28, 127-164.
4. Tanaka, A.; Oritani, T.; Tetrahedron Lett., 1997, 38, 1955.
5. Choukroun, R.; Gervais, D.; J. Chem. Soc. Dalton Trans., 1980, 1800-1802.
6. Caron, M.; Carlier, P. R.; Sharpless, K. B.; J. Org. Chem., 1988, 53, 5185-5187.
7. Agrell, I.; Acta Chem. Scand., 1970, 24, 1247-1261.
8. Viaud, M. C.; Rollin, P.; Synthesis, 1990, 130-132.
9. 3)}.
10. Compounds 15 and 19 were identical with the samples obtained by submitting 14 and 18 to the Mitsunobu reaction.
11. 2O/pyridine led to the same compound 26 as that obtained by the following transformation. formula presented
12. 2), 228.1388. Found, 228.1381.