Mechanistic Insights into the Very Efficient [ReO3OSiR3]-Catalyzed Isomerization of Allyl Alcohols

Angewandte Chemie (International Edition in English)

Volumn 36, Issue 9, 1997, Pages 976-978

  Bellemin Laponnaz, Stéphane ^a   Gisie, Hervé ^a   Le Ny, Jean Pierre ^a   Osborn, John A ^a  

^a UNIVERSITÉ DE STRASBOURG   (France)

Author keywords

Allyl alcohols; Homogeneous catalysis; Isomerizations; O ligands; Rhenium

Indexed keywords

EID: 0031005577     PISSN: 05700833     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.199709761     Document Type: Article

References (16)

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11. Total equilibrium of the three isomers has not been strictly obtained at this time since the isomeric cis alcohol is still far from equilibrium. However, the ratio of the concentration of the trans isomer to that of hex-1-en-3-ol after 10 mins remains essentially constant at the final equilibrium value.
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