"Grignard-Analogous" Rhodium Phosphane Complexes

Angewandte Chemie (International Edition in English)

Volumn 36, Issue 5, 1997, Pages 502-504

  Bogdanović, Borislav ^a   Leitner, Walter ^a   Six, Christian ^a   Wilczok, Ursula ^a   Wittmann, Klaus ^a  

^a MAX PLANCK INSTITUT FÜR KOHLENFORSCHUNG   (Germany)

Author keywords

Carbon dioxide activation; Grignard reactions; Homogeneous catalysis; Phosphane ligands; Rhodium

Indexed keywords

EID: 0031002967     PISSN: 05700833     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.199705021     Document Type: Article

References (40)

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9. nMMgCl], for which X-ray diffraction studies suggest a direct M-Mg bond. For example see a) H. Felkin, G. Swierczewski, Tetrahedron 1975, 31, 2735; b) H. Felkin, P. J. Knowles, B. Meunier, J. Organomet. Chem. 1978, 146, 151; S. G. Davies, M. L. H. Green, J. Chem, Soc. Dalton Trans. 1978, 1510; K. Jonas, G. Koepe, C. Krüger, Angew. Chem. 1986, 95, 901; Angew. Chem. Int. Ed. Engl. 1986, 25, 923. However, many bimetallic transition metal/magnesium complexes containing carbonyl ligands exhibit bridging M(μ-CO)Mg units rather than direct M-Mg interactions; examples: e) G. B. Vicker, Inorg. Chem. 1975, 14, 2087;
10. nMMgCl], for which X-ray diffraction studies suggest a direct M-Mg bond. For example see a) H. Felkin, G. Swierczewski, Tetrahedron 1975, 31, 2735; b) H. Felkin, P. J. Knowles, B. Meunier, J. Organomet. Chem. 1978, 146, 151; S. G. Davies, M. L. H. Green, J. Chem, Soc. Dalton Trans. 1978, 1510; K. Jonas, G. Koepe, C. Krüger, Angew. Chem. 1986, 95, 901; Angew. Chem. Int. Ed. Engl. 1986, 25, 923. However, many bimetallic transition metal/magnesium complexes containing carbonyl ligands exhibit bridging M(μ-CO)Mg units rather than direct M-Mg interactions; examples: e) G. B. Vicker, Inorg. Chem. 1975, 14, 2087;
11. nMMgCl], for which X-ray diffraction studies suggest a direct M-Mg bond. For example see a) H. Felkin, G. Swierczewski, Tetrahedron 1975, 31, 2735; b) H. Felkin, P. J. Knowles, B. Meunier, J. Organomet. Chem. 1978, 146, 151; S. G. Davies, M. L. H. Green, J. Chem, Soc. Dalton Trans. 1978, 1510; K. Jonas, G. Koepe, C. Krüger, Angew. Chem. 1986, 95, 901; Angew. Chem. Int. Ed. Engl. 1986, 25, 923. However, many bimetallic transition metal/magnesium complexes containing carbonyl ligands exhibit bridging M(μ-CO)Mg units rather than direct M-Mg interactions; examples: e) G. B. Vicker, Inorg. Chem. 1975, 14, 2087;
12. nMMgCl], for which X-ray diffraction studies suggest a direct M-Mg bond. For example see a) H. Felkin, G. Swierczewski, Tetrahedron 1975, 31, 2735; b) H. Felkin, P. J. Knowles, B. Meunier, J. Organomet. Chem. 1978, 146, 151; S. G. Davies, M. L. H. Green, J. Chem, Soc. Dalton Trans. 1978, 1510; K. Jonas, G. Koepe, C. Krüger, Angew. Chem. 1986, 95, 901; Angew. Chem. Int. Ed. Engl. 1986, 25, 923. However, many bimetallic transition metal/magnesium complexes containing carbonyl ligands exhibit bridging M(μ-CO)Mg units rather than direct M-Mg interactions; examples: e) G. B. Vicker, Inorg. Chem. 1975, 14, 2087;
13. nMMgCl], for which X-ray diffraction studies suggest a direct M-Mg bond. For example see a) H. Felkin, G. Swierczewski, Tetrahedron 1975, 31, 2735; b) H. Felkin, P. J. Knowles, B. Meunier, J. Organomet. Chem. 1978, 146, 151; S. G. Davies, M. L. H. Green, J. Chem, Soc. Dalton Trans. 1978, 1510; K. Jonas, G. Koepe, C. Krüger, Angew. Chem. 1986, 95, 901; Angew. Chem. Int. Ed. Engl. 1986, 25, 923. However, many bimetallic transition metal/magnesium complexes containing carbonyl ligands exhibit bridging M(μ-CO)Mg units rather than direct M-Mg interactions; examples: e) G. B. Vicker, Inorg. Chem. 1975, 14, 2087;
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