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Volumn 3, Issue 2, 1997, Pages 237-248

The vinylketene-acylallene rearrangement: Theory and experiment

Author keywords

ab initio calculations; allenes; ketenes; matrix isolation; rearrangements

Indexed keywords


EID: 0030993840     PISSN: 09476539     EISSN: None     Source Type: Journal    
DOI: 10.1002/chem.19970030212     Document Type: Article
Times cited : (32)

References (75)
  • 1
  • 10
    • 0001032956 scopus 로고    scopus 로고
    • b) Cf. also D. M. Birney, J. Org. Chem. 1996, 61, 243-251; R. Koch, M. W. Wong, C. Wentrup, ibid. 1996, 61, 6809-6813.
    • (1996) J. Org. Chem. , vol.61 , pp. 243-251
    • Birney, D.M.1
  • 23
    • 85036445011 scopus 로고    scopus 로고
    • note
    • All molecules having the structures 1 or 2 are defined as s-trans, regardless of the nature of R.
  • 24
    • 85036443763 scopus 로고    scopus 로고
    • note
    • s-cis) obtained at the B 3-LYP/6-31 G* level. It ignores the unknown errors in the calculated ε values;
  • 25
    • 85036440072 scopus 로고    scopus 로고
    • note
    • -1 at 70 K.
  • 31
    • 85036440412 scopus 로고    scopus 로고
    • note
    • All the bands observed were in very good agreement with the literature [12].
  • 40
    • 85036444888 scopus 로고    scopus 로고
    • note
    • -1.
  • 41
    • 85036446014 scopus 로고    scopus 로고
    • note
    • -1 is also observed due to the formation of unsubstituted vinylketene in a retroene reaction, which will be described in a separate paper [21 b].
  • 45
    • 85036446247 scopus 로고    scopus 로고
    • note
    • -1) was formed from 5b at 900°C.
  • 46
    • 85036442222 scopus 로고    scopus 로고
    • note
    • 2 and propyne, respectively, increased drastically.
  • 48
    • 85036444762 scopus 로고    scopus 로고
    • note
    • -1).
  • 53
    • 85036449533 scopus 로고    scopus 로고
    • note
    • -1 above s-cis-4d (G2(MP2,SVP));
  • 54
    • 85036440012 scopus 로고    scopus 로고
    • note
    • -1 below s-cis-4a;
  • 55
    • 85036440795 scopus 로고    scopus 로고
    • note
    • -1 below s-trans-4c and 32 kJ/mol below s-cis-4c.
  • 71
    • 84890755152 scopus 로고
    • C. D. Hurd, Syn. Coll. Vol. 1, 1941, 330-334.
    • (1941) Syn. Coll. , vol.1 , pp. 330-334
    • Hurd, C.D.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.