메뉴 건너뛰기




Volumn 61, Issue 1, 1996, Pages 243-251

Further pseudopericyclic reactions: An ab initio study of the conformations and reactions of 5-oxo-2,4-pentadienal and related molecules

Author keywords

[No Author keywords available]

Indexed keywords


EID: 0001032956     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo951716t     Document Type: Article
Times cited : (119)

References (66)
  • 12
    • 0001740156 scopus 로고
    • L. A. Paquette, Ed.; John Wiley & Sons, Inc.
    • (f) Hyatt, J. A.; Raynolds, P. W. In Organic Reactions; L. A. Paquette, Ed.; John Wiley & Sons, Inc.: 1994; Vol. 45; pp 159-635.
    • (1994) Organic Reactions , vol.45 , pp. 159-635
    • Hyatt, J.A.1    Raynolds, P.W.2
  • 19
    • 85087188170 scopus 로고    scopus 로고
    • note
    • 6 has also suggested that the presence of orthogonal orbitals could make an otherwise forbidden 1,3-sigmatropic shift allowed.
  • 21
    • 85087191858 scopus 로고    scopus 로고
    • note
    • -1.
  • 22
    • 85087193234 scopus 로고    scopus 로고
    • note
    • 2g
  • 34
    • 85087194531 scopus 로고    scopus 로고
    • note
    • 16 However, vinylketenes, lacking lone pairs at both ends, will only undergo pericyclic reactions.
  • 37
    • 5544313287 scopus 로고    scopus 로고
    • Frisch, M. J.; Trucks, G. W.; Head-Gordon, M.; Gill, P. M. W.; Wong, M. W.; Foresman, J. B.; Johnson, B. G.; Schlegel, H. B.; Robb, M. A.; Replogle, E. S.; Gomperts, R.; Andres, J. L.; Raghavachari, K.; Binkley, J. S.; Gonzalez, C.; Martin, R. L.; Fox, D. J.; Defrees, D. J.; Baker, J.; Stewart, J. J. P.; Pople, J. A. Gaussian, Inc. Pittsburgh, PA, 1992
    • Frisch, M. J.; Trucks, G. W.; Head-Gordon, M.; Gill, P. M. W.; Wong, M. W.; Foresman, J. B.; Johnson, B. G.; Schlegel, H. B.; Robb, M. A.; Replogle, E. S.; Gomperts, R.; Andres, J. L.; Raghavachari, K.; Binkley, J. S.; Gonzalez, C.; Martin, R. L.; Fox, D. J.; Defrees, D. J.; Baker, J.; Stewart, J. J. P.; Pople, J. A. Gaussian, Inc. Pittsburgh, PA, 1992.
  • 40
    • 85087193474 scopus 로고    scopus 로고
    • note
    • 22,23
  • 45
    • 85087191772 scopus 로고    scopus 로고
    • note
    • 10a
  • 49
    • 5544304290 scopus 로고    scopus 로고
    • note
    • Two additional transition states, inward and outward, in which the formyl group of the ketenes will be trans, are also expected.
  • 56
    • 85087194089 scopus 로고    scopus 로고
    • note
    • 36 This would also predict a bent geometry.
  • 60
    • 5544259651 scopus 로고    scopus 로고
    • note
    • It may be that 18, although the thermal barrier is significant, isomerizes with a high quantum yield to 2 and so is not observed in the matrix.
  • 65
    • 5544295960 scopus 로고    scopus 로고
    • note
    • Efforts are underway to explore this question in more detail


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.