Intercalation of inorganic fullerene-like structures yields photosensitive films and new tips for scanning probe microscopy

Journal of the American Chemical Society

Volumn 119, Issue 11, 1997, Pages 2693-2698

  Homyonfer, M ^a   Alperson, B ^a   Rosenberg, Y ^b   Sapir, L ^a   Cohen, S R ^a   Hodes, G ^a   Tenne, R ^a  

^a WEIZMANN INSTITUTE OF SCIENCE   (Israel)

^b TEL AVIV UNIVERSITY   (Israel)

Author keywords

[No Author keywords available]

Indexed keywords

FULLERENE DERIVATIVE;

ARTICLE; DRUG SYNTHESIS; IN VITRO STUDY; PHOTOCHEMISTRY;

EID: 0030932498     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja963585z     Document Type: Article

References (36)

1. Tenne, R.; Margulis, L.; Genut, M.; Hodes, G. Nature 1992, 360, 444.
2. Feldman, Y.; Wasserman, E.; Srolovitz, D. J.; Tenne, R. Science 1995, 267, 222.
3. Feldman, Y.; Frey, G. L.; Homyonfer, M.; Lyakhovitskaya, V.; Margulis, L.; Cohen, H.; Hodes, G.; Hutchison J. L.; Tenne, R. J. Am. Chem. Soc. 1996, 118, 5362.
4. Stephan, O.; Ajayan, P. M.; Colliex, C.; Redlich, Ph.; Lambert, J. M.; Bernier P.; Lefin, P. Science 1994, 266, 1683.
5. Chopra, N. G.; Luyken, R. J.; Cherrey, K.; Crespi, V. H.; Cohen, M. L.; Louie, S. G.; Zettl, A. Science 1995, 269, 966.
6. José-Yacamán, M.; Lopez, H.; Santiago, P.; Galván, D. H.; Garzón I. L.; Reyes, A. Appl. Phys. Lett. 1996, 69, 1065.
7. Ugarte, D. Nature 1992, 359, 707.
8. Homyonfer, M; Mastai, Y; Hershfinkel, M; Volterra, V; Hutchison, J. L; and Tenne, R J. Am. Chem. Soc. 1996, 118, 7804.
9. Zhou, O.; Fleming, R. M.; Murphy, D. W.; Chen, C. H.; Haddon, R. C.; Ramirez A. P.; Glarum, S. H. Science 1994, 263, 1744.
10. Brec, R.; Rouxel, J. Intercalation in Layered Materials Dresselhaus, M. S., Ed.; NATO ASI Series B: Physics. Plenum Press: New York, 1986; Vol. 148, pp 75-91.
11. Friend, R. H; Yoffe, A. D. Adv. Phys. 1987, 36, 1.
12. Somoano, R. B.; Hadek, V.; Rembaum, A. J. Chem. Phys. 1973, 58, 697.
13. a. Golan Y., Margulis L.; Rubinstein I. Surf. Sci. 1992, 264, 312;
14. b. Alperson, B.; Cohen, S.; Rubinstein, I.; Hodes, G. Phys. Rev. B 1995, 52, R17017.
15. Wells, A. F. Structural Inorganic Chemistry, 3rd ed., Oxford University Press: Oxford, 1962; p 468.
16. 2O (20% v/v). However, no direct evidence for the intercalation of the transition metal atoms into the IF particles has been obtained so far.
17. 2 would form. In the case of the volatile molybdenum oxide, the preliminary sulfidization occurs in the gas phase before the nanoparticles settle on the quartz susceptor. The subsequent conversion of the oxide core into sulfide takes place on the susceptor, and coalescence of the nanoparticles is avoided altogether.
18. Iijima, S.; Ichihashi T.; Ando, Y. Nature 1992, 356, 776.
19. Terrones, H.; Terrones M.; Hsu, W. K. Chem. Soc. Rev. 1995, 341.
20. Dunlap, B. Phys. Rev. B. 1992, 46, 1933.
21. Somoano R. B.; Woollam, J. A., Intercalated Layered Materials; Lévy, F., Ed.; D. Reidel Publishing Company: Dordrecht, 1979; pp 307-319.
22. Jonson, P.; Frindt, R. F.; Morrison, S. R. Mater. Res. Bull. 1986, 21, 457.
23. Frey, G. L. et al., to be published.
24. Dresselhaus M. S.; Dresselhaus, G. Adv. Phys. 1981, 30, 139.
25. Attempts to identify the superlattice of the intercalated atoms by electron diffraction was unsuccessful so far. It is likely that the low concentration of the alkali-metal atoms, and the large repeat unit distance, which entails diffraction spots near the central bright ring of the electron microscope beam prevents such measurements.
26. Lewerenz, H. J.; Heller, A.; DiSalvo, F. J. Am. Chem. Soc. 1980, 102, 1877.
27. Bordas, J. Optical and Electrical Properties, in the series Physics and Chemistry of Materials with Layered Structures; Lee, P. A., Ed.; D. Reidel Publishing Company: Dordrecht, 1976; pp 145-230.
28. Geddes, N. J.; Sambles, J. R.; Parker, W. G.; Couch, N. R.; Jarvis, D. J.; J. Phys. D: Appl. Phys. 1990, 23, 95.
29. Hamers, R. J.; Merkert, K. Phys. Rev. Lett., 1990, 64, 1051.
30. Gerischer, H.; Heller, A. J. Phys. Chem. 1991, 95, 5261.
31. Hodes, G.; Howell I. D.; Peter, L. M. J. Electrochem. Soc. 1992, 139, 3136.
32. Kam, K. K.; Parkinson, B. A. J. Phys. Chem. 1982, 86, 433.
33. Tributsch, H. Struct. Bonding 1982, 49, 127.
34. Ducker, S. A.; Senden, T. J.; Pashley, R. M. Nature 1992, 353, 239.
35. Dai, H.; Hafner, J. H.; Rinzler, A. G.; Colbert, D. T.; Smalley, R. E. Nature 1996, 384, 147.
36. Reisfeld R. et al., to be published.